Search results for "element"
showing 10 items of 13601 documents
Speciation and interactions of plutonium with humic substances and kaolinite in aquifer systems
2007
Abstract The speciation of plutonium (Pu) in contact with humic substances (HS) and kaolinite has been performed in aquifer systems. Mainly the redox behavior, complexation, and sorption of plutonium are discussed here. The redox behavior of Pu(VI) in contact with HS was studied and it was found that Pu(VI) is reduced to Pu(III) and Pu(IV) within a couple of weeks. The complexation constants (log β LC ) of Pu(III) and Pu(IV) with HS have been determined by means of the ultrafiltration method. Furthermore, the sorption of Pu(III) and Pu(IV) onto kaolinite has been investigated as a function of pH by batch experiments under aerobic and anaerobic conditions.
LA-ICP-MS analyses on coral growth increments reveal heavy winter rain in the Eastern Mediterranean at 9 Ma
2009
Abstract Sediment particles incorporated into coral skeletons reflect variation in composition and amount of suspended material in ambient water during coral growth. They can be used to identify periods of enhanced storm frequency and associated freshwater discharge. Tortonian (Late Miocene) Porites corals from Crete (Aegean Sea, Eastern Mediterranean) show pronounced annual density bands in X-ray photographs. δ18O compositional variability reflects the annual banding equivalent with a ~ 7 °C annual sea surface temperature (SST) cycle over a seven-year period. Fine sediment particles are concentrated in layers with skeletal porosity parallel to growth increments. Variations in the chemical …
Multicopter measurements of volcanic gas emissions at Masaya (Nicaragua), Turrialba (Costa Rica) and Stromboli (Italy) volcanoes: Applications for vo…
2017
Abstract. Volcanoes are a natural source of several reactive gases (e.g. sulfur and halogen containing species), as well as non-reactive gases (e.g. carbon dioxide). Besides that, halogen chemistry in volcanic plumes might have important impacts on atmospheric chemistry, carbon to sulfur ratios and sulfur dioxide fluxes are important established parameters to gain information on subsurface processes. In this study we demonstrate the successful deployment of a multirotor UAV (quadcopter) system with custom-made lightweight payloads on board for the compositional analysis and gas flux estimation of volcanic plumes. The various applications and their potential with such new measurement strateg…
A New Web-Based Catalog of Earth Degassing Sites in Italy
2008
Italy is a region characterized by intense and widespread processes of Earth degassing. High-temperature gases are released by crater plumes and fumaroles in volcanic environments throughout Italy. Also prevalent are numerous low-temperature gas emissions rich in carbon dioxide (CO2). These low-temperature emissions are located in a large area, mainly in the western sector of central and southern Italy (Figure 1).
AGU Centennial Grand Challenge: Volcanoes and Deep Carbon Global CO 2 Emissions From Subaerial Volcanism—Recent Progress and Future Challenges
2020
Quantifying the global volcanic CO2 output from subaerial volcanism is key for a better understanding of rates and mechanisms of carbon cycling in and out of our planet and their consequences for the long-term evolution of Earth's climate over geological timescales. Although having been the focus of intense research since the early 1990s, and in spite of recent progress, the global volcanic CO2 output remains inaccurately known. Here we review past developments and recent progress and examine limits and caveats of our current understanding and challenges for future research. We show that CO2 flux measurements are today only available for ~100 volcanoes (cumulative measured flux, 44 Tg CO2/y…
Application and evaluation of biomagnetic and biochemical monitoring of the dispersion and deposition of volcanically-derived particles at Mt. Etna, …
2010
article i nfo Article history: Received 6 August 2009 Accepted 4 January 2010 Available online xxxx Biomagnetic monitoring, using tree leaves as passive surfaces for particle collection, has been shown to be a promising technique for assessing the dispersion and deposition of particles in the context of anthropogenic pollution. By comparing leaves' magnetic properties with trace metal levels measured in the leaves, we here assess the utility of the biomagnetic technique as a sensitive, fast and inexpensive method for assessment of volcanic plume deposition. Samples of sweet chestnut leaves (Castanea sativa) were collected from the area surrounding Mt. Etna volcano in Sicily during the 2008 …
Fluorine speciation in topsoils of three active volcanoes of Sicily (Italy)
2008
Fluorine is one of the many environmental harmful elements released by volcanic activity. The content of total oxalate-extractable and water-extractable fluorine was determined in 96 topsoils of three active volcanic systems of southern Italy (Mt Etna, Stromboli and Vulcano). Total fluorine (F) content (F TOT) ranges from 112 to 7,430 mg kg−1, F extracted with oxalate (F OX) ranges from 16 to 2,320 mg kg−1 (2–93% of F TOT) and F extracted with distilled water ( $$ F_{{{\text{H}}_{{\text{2}}} {\text{O}}}} $$ ) ranges from 1.7 to 159 mg kg−1 (0.2–40 % of F TOT). Fluorine in the sampled topsoils derives both from the weathering of volcanic rocks and ashes and from the enhanced deposition due t…
A christmas gift: Signature of the 24th December 2018 eruption of Mt. Etna on the chemical composition of bulk deposition in eastern sicily
2020
The eruption of Mt. Etna which occurred on December 24th 2018 was characterized by strombolian activity and fire fountains, emitted by the New South-East Crater and along a fissure that propagated towards the SE. The influence of volcanic emissions on atmospheric deposition was clearly detectable at several kilometres from the source. Wet and dry (bulk) deposition samples were collected each month, through a network of eleven collectors, in the areas of Milazzo, and Priolo between June 2018 and June 2019. They were analysed for major ions and trace elements concentrations. The pH values range from 3.9 to 8.3, while the EC values range from 7 to 396 μS cm-1. An extensive neutralization of th…
Magmatic degassing of multicomponent vapors and assessment of magma depth: application to Vulcano Island (Italy)
2001
Degassing of magmatic H2O, CO2 and rare gases plays a major role in understanding large-scale Earth processes and in the assessment of volcanic activity. Here we describe a quantitative model for magmatic degassing of H2O–CO2–noble gas–N2 mixtures. Our modeling takes into account non-ideal behaviors by adopting recently developed approaches for the solubility of H2O–CO2 mixtures in silicate liquids and for noble gas partitioning in H2O–CO2 bearing magmas. This new approach allows quantitative treatment of inert gas fractionation throughout the degassing of any H2O–CO2 bearing natural magma in a wide range of thermo-baric conditions. Magma degassing simulations performed by our model have cl…
Major and trace element geochemistry of neutral and acidic thermal springs at El Chichón volcano, Mexico
2008
Abstract Four groups of thermal springs with temperatures from 50 to 80 °C are located on the S–SW–W slopes of El Chichon volcano, a composite dome-tephra edifice, which exploded in 1982 with a 1 km wide, 160 m deep crater left. Very dynamic thermal activity inside the crater (variations in chemistry and migration of pools and fumaroles, drastic changes in the crater lake volume and chemistry) contrasts with the stable behavior of the flank hot springs during the time of observations (1974–2005). All known groups of hot springs are located on the contact of the basement and volcanic edifice, and only on the W–SW–S slopes of the volcano at almost same elevations 600–650 m asl and less than 3…