Search results for "elemental"
showing 10 items of 131 documents
Universal features of the nuclear matrix elements governing the mass sector of the 0νββ decay
2005
In this work we report on manifest universal features found in the nuclear matrix elements which govern the mass sector of the neutrinoless double beta decay. The results are based on the analysis of the calculated matrix elements corresponding to the decays of 76Ge, 82Se, 100Mo, and 116Cd. The results suggest a dominance of few low-lying nuclear states of few multipoles in these matrix elements. Dedicated charge-exchange reactions could be used to probe these key states to determine experimentally the value of the nuclear matrix element.
An Active X-Ray Spectrometer for the SELENE-2 Rover
2014
The Active X-ray Spectrometer (AXS) for the Japanese SELENE-2 rover has been proposed for elemental analysis on the lunar surface to measure the major elements: Mg, Al, Si, Ca, Ti, and Fe; the minor elements, Na, K, P, S, Cl, Cr, and Mn and the trace element Ni, all depending on their concentrations at a landing site. The elemental data of the AXS allow us to not only classification but also quantification of surface rocks on the Moon. The AXS is a compact low-weight instrument for elemental analysis based on the principle of X-ray fluorescence spectrometry using an X-ray spectrometer and two (four) pyroelectric crystals as X-Ray Generators (XRG). This paper introduces the current status of…
A Unique Collection of Palaeolithic Painted Portable Art: Characterization of Red and Yellow Pigments from the Parpalló Cave (Spain).
2016
In this work we analyze the pigments used in the decoration of red and yellow motifs present in the portable art of the Parpallo Cave (Gandia, Spain), one of the most important Palaeolithic sites in the Spanish Mediterranean region. Energy dispersive X-ray fluorescence spectrometry (EDXRF) and spectrophotometry in the visible region (CIEL*a*b*color coordinates and spectral reflectance curves) were used to perform in situ fast analyses of the red and yellow motifs with portable equipment and to characterize their elemental composition and their colorimetric perception, respectively. According to the elemental composition, the intensity of the fluorescence iron signals in red and yellow motif…
A practical ethylene polymerization for vinyl-polyethylenes: synthesis, characterization and catalytic behavior of α,α’-bisimino-2,3:5,6- bis(pentame…
2016
A series of α,α′-bis(arylimino)-2,3:5,6-bis(pentamethylene)pyridyliron chlorides was synthesized in a one-pot reaction and characterized by FT-IR and elemental analysis as well as X-ray crystallography for one representative iron complex, where the Fe center adopts a distorted square pyramidal geometry with three coordinating nitrogen and two chlorine atoms. The iron precatalysts, upon treatment with either methylaluminoxane (MAO) or modified methylaluminoxane (MMAO), exhibit high activities in the range of 107 g of PE per mol of Fe per h toward ethylene polymerization, yielding highly linear and, more importantly, vinyl-polyethylenes. The correlation between the structural features of iron…
Characterization of the atmospheric muon flux in IceCube
2015
Muons produced in atmospheric cosmic ray showers account for the by far dominant part of the event yield in large-volume underground particle detectors. The IceCube detector, with an instrumented volume of about a cubic kilometer, has the potential to conduct unique investigations on atmospheric muons by exploiting the large collection area and the possibility to track particles over a long distance. Through detailed reconstruction of energy deposition along the tracks, the characteristics of muon bundles can be quantified, and individual particles of exceptionally high energy identified. The data can then be used to constrain the cosmic ray primary flux and the contribution to atmospheric …
Correlation of radioactivity measurements, air kerma rates and geological features of Sicily
2006
Abstract Sicily, the largest Mediterranean island (with an extension of about 25 000 km 2 ), exhibits a very wide variety of lithologies, ranging from sedimentary to metamorphic and volcanic rocks. Principal component analysis (PCA) and hierarchical cluster analysis (HCA) have been applied to air kerma values measured by thermoluminescent dosimetry in several sites and to data of radionuclide concentrations, geochemical and mineralogical features of rocks and soils sampled in 29 sites of Sicily to point out similarities among different lithologies. The study was devoted to find multiple correlations and allow a better classification of Sicilian lithotypes. Samples of rocks and soils have be…
Estuarine sediment quality assessment by Fourier-transform infrared spectroscopy
2010
Partial least squares Fourier-transform infrared (PLS-FTIR) models were developed for the quality assessment of estuarine sediments through the evaluation of several physico-chemical parameters. Models were based on the chemometric treatment of attenuated total reflection (ATR) spectra directly obtained from samples previously lyophilized and sieved through a lower than 63 μm grid. Spectra were scanned from 3997 to 523 cm-1, averaging 36 scans per spectrum with a nominal resolution of 8 cm-1. Models were built using reference data obtained for sediment samples collected from Ria de Arousa estuary. Hierarchical cluster classification of sediment ATR spectra was employed for the establishment…
Concentration of retene and resin acids in sedimenting particles collected from a bleached kraft mill effluent receiving lake
2000
Abstract The concentration of retene, a di-alkyl substituted PAH derived microbially and thermally from dehydroabietic acid, eight resin acids and their derivatives were analysed from sedimenting particles collected from five lake sites receiving pulp and paper mill effluents and from two reference sites. At five of the sites, samples were collected prior and after a conventional aerated lagoon wastewater treatment system of the mill was modernized with an activated sludge plant, and elemental chlorine free bleaching (ECF) had replaced chlorine bleaching. The highest level of retene was 30.0–53.8 μ g/g dry weight (d.w.), observed 3 km downstream from the mill. Nine kilometers downstream fr…
Data on physical and chemical characterization of wood combustion products derived at cogeneration power plants
2021
The data presented in this article are related to the research paper “Granulation of fly ash and biochar with organic lake sediments – A way to sustainable utilization of waste from bioenergy production” [1] in the context of waste material investigation and possible valorization instead of disposal. This article provides a comprehensive chemical and physical characterization of wood combustion products – fly ashes, bottom ashes, mixed ashes and biochar. Multiple analytical techniques and methodology were exploited to investigate the composition of wood combustion products, among them a loss on ignition, potentiometry, colorimetry, X-ray diffractometry, X-ray fluorescence spectrometry, indu…
Beyond the mean: A comparison of trace- and macroelement correlation profiles of two lacustrine populations of the crayfish Procambarus clarkii
2018
In invertebrate biomonitors of chemical pollution, emphasis has been generally given to mean accumulation patterns and how they reflect varying environmental levels of contamination. Intra-population variability, and how it relates with individual phenotypic traits, has received less attention. Here, a set of analytes including trace elements (B, Ba, Cd, Cr, Cu, Fe, Li, Mn, Ni, Pb, Sr, V, and Zn), macroelements (C, Ca, K, Mg, N, Na), and carbon and nitrogen stable isotopes (δ13C and δ15N) was measured in two populations of the crayfish Procambarus clarkii from Lake Trasimeno and Lake Bolsena (Central Italy). The influence of location, sex, body size, and condition factor was assessed; in ad…