Search results for "emulsion"
showing 10 items of 344 documents
Reduction of saturated fat in chocolate by using sunflower oil-hydroxypropyl methylcellulose based oleogels
2021
The suitability of sunflower oil-hydroxypropyl methylcellulose (HPMC) based oleogel obtained by emulsion template approach as partial cocoa butter (CB) replacer in chocolates was investigated. A level of 50% CB replacement was optimum, as higher level of replacement affected the sensory appearance in comparison to the control chocolate (without added oleogel). Four levels of HPMC (0.5, 1, 1.5 and 2%) were considered. Textural and calorimetric properties, as well as sensory properties obtained by Free Choice Profile of the formulated chocolates were investigated. Partial replacement of CB by the sunflower-HPMC based oleogel reduced significantly the chocolate hardness. Higher HPMC concentrat…
Small-angle neutron scattering from lecithin reverse micelles
1996
Abstract We report new results of small-angle neutron scattering from cyclohexane- d 12 /lecithin/water micellar solutions, performed as a function of the water content, w 0 , the temperature, T and the dispersed-phase volume fraction, ф. The data from dilute samples can be interpreted in terms of the existence of giant cylindrical reverse micelles, in good agreement with the current idea of an unlimited micellar growth with ф. In contrast, the appearance of a sharp interference maximum at high concentrations ( ф > 0.15 ) suggests that the current hypothesis of a gel structure interpreted as a random network of entangled micelles can be assumed to be incorrect, and that there must be some c…
Interface and aroma barrier properties of iota-carrageenan emulsion–based films used for encapsulation of active food compounds
2009
Abstract Food quality preservation requires that the initial properties of the food products be maintained by protecting them from the environment and by limiting the gain or loss of external matter. Barrier edible films can preserve food quality by controlling moisture transfer, oxygen uptake or the loss of volatile aroma compounds. Edible films made of iota-carrageenans display interesting advantages: good mechanical properties, stabilization of emulsions and reduction in oxygen transfer. Moreover, lipid globules incorporated as emulsion-based films can be the carriers for the encapsulation of active volatile molecules such as flavor compounds. Such films also enhance the barrier properti…
Funcionalidad de hidrocoloides en la digestibilidad de emulsiones aceite/agua
2019
La presente tesis doctoral se centra en el estudio de las propiedades físicas y la digestibilidad lipídica de emulsiones alimentarias basadas en hidrocoloides, para valorar su aplicación como sustitutos de grasa en la reformulación de un producto final más saludable. La obtención de alimentos más saludables se puede conseguir a través de diferentes vías; o bien disminuyendo la cantidad de grasa presente, o bien disminuyendo la digestibilidad de la grasa, considerándose también un aspecto clave la mejora del perfil lipídico. Teniendo estos aspectos en cuenta, se diseñaron y estudiaron emulsiones formuladas con diferentes tipos de grasa estabilizadas por diferentes tipos de matrices poliméric…
Multifunctional polymer/inorganic hybrid nanoparticles with controlled structure
2019
Hybrids and composite materials offer a synergic combination of polymer and inorganic features. The integration of specific functionalities at the nanoscale leads to the improvement of the characteristics of macroscopic materials. In this context, the attractiveness of multifunctional polymer–inorganic nanoparticles is remarkable. The relative arrangement of the components forming the hybrid nanostructure determines the accessibility of the functionalities, the properties, and the applicability of the material. Colloidal methods have been traditionally used for the preparation of hybrid nanoparticles, but the precise control of their morphology remains still a challenge. The objective of th…
The CdCl2 effects on synthetic DNAs encaged in the nanodomains of a cationic water-in-oil microemulsion
2011
The present work is dedicated to the study of the interactions of CdCl(2) with the synthetic polynucleotides polyAT and polyGC confined in the nanoscopic aqueous compartment of the water-in-oil microemulsion CTAB/pentanol/hexane/water, with the goal to mimic in vitro the situation met by the nucleic acids in vivo. In biological structures, in fact, very long strings of nucleic acids are segregated into very small compartments having a radius exceedingly smaller than the length of the encapsulated macromolecule. For comparison, the behaviour of polyGC was also studied in aqueous solutions of matched composition. The conformational and thermal stabilities of both polynucleotides enclosed in t…
Preparation of Polymeric Nanoparticles by Photo-Crosslinking of an Acryloylated Polyaspartamide in w/o Microemulsion
2004
Biodegradable polymeric nanoparticles have been prepared by UV irradiation of an acryloylated water soluble polymer by an inverse microemulsion. The starting polymer was a α,β‐poly(N‐2‐hydroxyethyl)‐D,L‐aspartamide (PHEA) partially functionalized with glycidyl methacrylate (GMA) in order to introduce reactive vinyl groups in the side chain. The PHEA‐GMA copolymer obtained (PHG) was crosslinked by UV irradiation of the inverse microemulsion prepared by mixing an aqueous solution of PHG with propylene carbonate (PC)/ethyl acetate (EtOAc) in the presence of sorbitan trioleate (SPAN 85) as surfactant. Nanoparticles obtained were characterized by FTIR spectrophotometry, transmission electron mic…
DNA recovery from Droplet Digital™ PCR emulsions using liquid nitrogen
2020
Droplet microfluidics is a technology that enables the production and manipulation of small volumes. In biosciences, the most popular application of this technology is Droplet Digital™ PCR (ddPCR™), where parallel nanoliter-scale PCR assays are used to provide a high sensitivity and specificity for DNA detection. However, the recovery of PCR products for downstream applications such as sequencing can be challenging due to the droplets' stability. Here we compared five methods for disrupting the droplets to recover DNA. We found that rapid freezing in liquid nitrogen results in a clear phase separation and recovery of up to 70% of the DNA content. Liquid nitrogen freezing can thus offer a si…
Direct electricity production from coconut oil - the electrooxidation of coconut oil in an acid electrolyte
2018
Supplying more and more energy is an essential task of today's energy industry. In the last few decades, in addition to traditional methods of energy production, alternative energy sources have been developing at a fast rate. One of the devices that can use these sources is the fuel cell (FC). FCs can be a power source of the future mainly due to their high efficiency, their low impact on the environment and the possibility of powering with different fuels. Most often, FCs are powered by hydrogen. However, issues with its cheap production and storage are the reasons for seeking new fuels for FCs. Yet it must be a fuel that will provide a zero or low emission level. One of these fuels can be…
Possibility of direct electricity production from waste canola oil
2017
Powering high-efficiency devices, such as fuel cells, with waste products will allow for a broader development of renewable energy sources and utilisation of by- products. This publication presents the possibility of electrooxidation of the emulsion of waste rapeseed oil, prepared on the basis of the detergent Syntanol DS-10. The process of electrooxidation was carried out on platinum electrode in alkaline (KOH) and acidic (H 2 SO 4 ) electrolyte, in the temperature range of 293-333 K. In each analysed case the process of electrooxidation took place. The maximum current density obtained was 7 mA cm -2 . Thus, it has been shown that it is possible to generate electricity directly from the em…