Search results for "engineering.material"
showing 10 items of 2352 documents
Long-term stability of alpha particle damage in natural zircon
2005
Abstract We report the first discovery of radiation damage haloes generated by alpha particles in zircon. Proterozoic zircon crystals from a potassium-rich leucogranite from the Adirondack Mountains, New York State, have interior regions that are generally low in actinide elements (UO 2 + ThO 2 ≤ 0.02 wt.%) but show a remarkable pattern of heterogeneous metamictisation. The degree of radiation damage in these regions is not uniformly low, as would be expected if it corresponded to the observed actinide distribution patterns and age of the crystals. Rather, radiation damage is significantly increased in the outermost micro-areas of the low-actinide regions. The additional radiation damage …
Sr/Ca and Mg/Ca ratios of ontogenetically old, long-lived bivalve shells (Arctica islandica) and their function as paleotemperature proxies
2011
International audience; The Sr/Ca and Mg/Ca ratios of many biogenic skeletons provide useful paleotemperature estimates. As yet however, it has remained largely impossible to obtain such information from bivalve shells. In the present study, metal-to-calcium values in the hinge plate (aragonite, outer shell layer) of four ontogenetically old (85 to 374 year-old) specimens of the long-lived bivalve, Arctica islandica, were measured on a LA-ICP-MS. The shells were collected alive in 1868, 1986 and 2003 from three different localities around Iceland. With increasing ontogenetic age and decreasing growth rate, a distinct trend toward increasing Sr/Ca (max. 5.17 mmol/mol) and Mg/Ca values (max. …
Cretaceous ultrapotassic magmatism from the Sava-Vardar Zone of the Balkans
2020
Highlights • Geochemically diverse Late Cretaceous small-volume magmatism in the Sava-Vardar Zone. • Late Cretaceous ultrapotassic lava, equivalent of minette and kersantite. • Magma derivation from a LREE and K enriched, garnet-bearing anciently metasomatized mantle source. • Magmatism occurred either in a fore-arc setting or is associated with transtensional tectonics. Abstract Late Cretaceous global plate reorganization associated with the inception of counterclockwise rotation of Africa relative to Europe initiated in the Balkan region small-volume magmatism of diverse geochemical signature along the enigmatic Sava-Vardar Zone. We study a Late Cretaceous lamprophyric sill in Ripanj vill…
Phlogopite-pargasite coexistence in an oxygen reduced spinel-peridotite ambient
2021
AbstractThe occurrence of phlogopite and amphibole in mantle ultramafic rocks is widely accepted as the modal effect of metasomatism in the upper mantle. However, their simultaneous formation during metasomatic events and the related sub-solidus equilibrium with the peridotite has not been extensively studied. In this work, we discuss the geochemical conditions at which the pargasite-phlogopite assemblage becomes stable, through the investigation of two mantle xenoliths from Mount Leura (Victoria State, Australia) that bear phlogopite and the phlogopite + amphibole (pargasite) pair disseminated in a harzburgite matrix. Combining a mineralogical study and thermodynamic modelling, we predict …
2D Hydro-Mechanical-Chemical Modeling of (De)hydration Reactions in Deforming Heterogeneous Rock: The Periclase-Brucite Model Reaction
2020
Deformation at tectonic plate boundaries involves coupling between rock deformation, fluid flow, and metamorphic reactions, but quantifying this coupling is still elusive. We present a new two-dimensional hydro-mechanical-chemical numerical model and investigate the coupling between heterogeneous rock deformation and metamorphic (de)hydration reactions. We consider linear viscous compressible and power-law viscous shear deformation. Fluid flow follows Darcy's law with a Kozeny-Carman type permeability. We consider a closed isothermal system and the reversible (de)hydration reaction: periclase and water yields brucite. Fluid pressure within a circular or elliptical inclusion is initially bel…
Textural-chemical changes and deformation conditions registered by phyllosilicates in a fault zone (Pic de Port Vieux thrust, Pyrenees)
2017
International audience; Synkinematic phyllosilicates in fault zones can be used to deduce the deformation mechanisms and the conditions of fault activity, as their chemical composition, crystal structure and texture can record the different stages of deformation and fluid-rock interactions. The Pic de Port Vieux, a second-order thrust related to the major Gavarnie thrust in the southern central part of the Pyrenees Axial Zone, juxtaposes Triassic pelites of the hanging wall and Cretaceous limestones of the footwall. In order to investigate the mineralogical and geochemical changes and constrain the deformation conditions of thrusting, characterization of phyllosilicates was performed along …
Simulation of nitrous oxide emissions from wheat-cropped soils using CERES
2005
Estimation of nitrous oxide (N2O) emissions from arable soils, in relation to crop fertilization, is essential to devise strategies to mitigate the impact of agriculture on global warming. This paper presents the development and test of a N2O model resulting from the linkage of a dynamic soil-crop simulation model (CERES) with two sub-models of N2O production and reduction in soils. These sub-models (NOE and NGAS) account for both the nitrification and denitrification pathways. The resulting models (CERES–NOE and CERES–NGAS) were tested against experimental data collected on three contrasting wheat-cropped soils representative of the Beauce agricultural region in France. Although the input …
The Chevroches zodiacal cap and its Burgundy relations
2009
AbstractThe excavation of an unexplored secondary agglomeration in Chevroches (France), from 2001 to 2002 has led to the discovery of a bronze dome of a type unknown in the Ancient world. It is inscribed with three lines in Greek transcribing Egyptian and Roman months, and the twelve signs of the Zodiac. This paper presents the first observations and some other finds from similar objects in Burgundy.
Phase equilibrium constraints on pre-eruptive conditions of recent felsic explosive volcanism at Pantelleria Island, Italy.
2010
International audience; We present experimental phase equilibria carried out on a pantelleritic bulk-rock composition with a peralkalinity index [PI = molar (Na2O + K2O)/Al2O3] = 1*4, which is representative of the most energetic pumice fall eruption of the resurgent post-caldera volcanism on Pantelleria island. For the explored conditions (P = 25-150 MPa; T = 680-800°C; H2Omelt up to 6 wt %; fO2 ≤ NNO, where NNO is nickel-nickel oxide buffer) clinopyroxene is the liquidus phase followed by alkali feldspar and then quartz. The crystallization of amphibole is limited to temperatures below 700°C. Aenigmatite crystallizes near the liquidus for P ≥ 100 MPa. When clinopyroxene is the sole liquid…
Impact of Coseismic Frictional Melting on Particle Size, Shape Distribution and Chemistry of Experimentally-Generated Pseudotachylite
2020
In natural friction melts, or pseudotachylites, clast textures and glass compositions can influence the frictional behavior of faults hosting pseudotachylites, and are, in turn, sensitive to the processes involved in pseudotachylite formation. Quantification of these parameters in situations where the host rock composition and formation conditions are well-constrained, such as analogue experiments, may yield calibrations that can be employed in analysis of natural pseudotachylites. In this paper, we experimentally-generated pseudotachylites in granitoid rocks (tonalite and Westerly granite) at Pconf= 40 MPa and slip rates of ∼0.1 m s−1, comparable to the conditions under which natural pseud…