Search results for "engineering.material"
showing 10 items of 2352 documents
Effect of sodium borohydride and hydrogen peroxide pretreatments on soda pulping of sugar maple (Acer saccharum)
2021
For recovering value-added wood-based organic material prior to delignification, sodium borohydride (NaBH4) and hydrogen peroxide (H2O2) pretreatments under alkaline conditions were performed before soda pulping of sugar maple (Acer saccharum) chips with sodium hydroxide (NaOH). In this investigation, it was determined whether the pulp yield could be increased by partly stabilizing the hemicelluloses by these pretreatments, and simultaneously obtains lower pulp kappa numbers. The results indicated that when aiming to the same kappa numbers (i.e., kappa numbers 14.3-20.5), roughly 3% higher pulp yield could be achieved if the chips were pretreated with alkaline 0.5% NaBH4 solutions, compared…
Formaldehyde: Catalytic Oxidation as a Promising Soft Way of Elimination
2013
International audience; Compared to other molecules such as benzene, toluene, xylene, and chlorinated compounds, the catalytic oxidation of formaldehyde has been studied rarely. However, standards for the emission level of this pollutant will become more restrictive because of its extreme toxicity even at very low concentrations in air. As a consequence, the development of a highly efficient process for its selective elimination is needed. Complete catalytic oxidation of formaldehyde into CO2 and H2O using noble-metal-based catalysts is a promising method to convert this pollutant at room temperature, making this process energetically attractive from an industrial point of view. However, th…
Boosting Protein Encapsulation through Lewis-Acid-Mediated Metal–Organic Framework Mineralization: Toward Effective Intracellular Delivery
2022
Encapsulation of biomolecules using metal–organic frameworks (MOFs) to form stable biocomposites has been demonstrated to be a valuable strategy for their preservation and controlled release, which has been however restricted to specific electrostatic surface conditions. We present a Lewis-acid-mediated general in situ strategy that promotes the spontaneous MOF growth on a broad variety of proteins, for the first time, regardless of their surface nature. We demonstrate that MOFs based on cations exhibiting considerable inherent acidity such as MIL-100(Fe) enable efficient biomolecule encapsulation, including elusive alkaline proteins previously inaccessible by the well-developed in situ azo…
Synthesis and host properties of tetragonal Li2Mn2O4 and Li2Co0.4Mn1.6O4
2000
Abstract This paper presents synthesis and electrochemical properties of tetragonal lithium manganese dioxide, Li2Mn2O4 and its cobalt doped analogue Li2Co0.4Mn1.6O4. The materials are compared as host materials for lithium insertion and the behavior during the initial lithium extraction as well as on repeated cycling is presented. These materials show an initial lithium extraction capacity between 200 and 270 mAh/g. On repeated cycling, they are converted into spinel-like lattices with reversible capacities in the range 82–90 mAh/g. As they are chemically compatible with the manganese spinel, they will be well suited as additives compensating for the capacity loss during the initial formin…
Imaging the local charge environment of nitrogen-vacancy centers in diamond
2018
Characterizing the local internal environment surrounding solid-state spin defects is crucial to harnessing them as nanoscale sensors of external fields. This is especially germane to the case of defect ensembles which can exhibit a complex interplay between interactions, internal fields and lattice strain. Working with the nitrogen-vacancy (NV) center in diamond, we demonstrate that local electric fields dominate the magnetic resonance behavior of NV ensembles at low magnetic field. We introduce a simple microscopic model that quantitatively captures the observed spectra for samples with NV concentrations spanning over two orders of magnitude. Motivated by this understanding, we propose an…
Anatectic amphibole and restitic garnet in Variscan migmatite from NE Sardinia, Italy: insights into partial melting from mineral trace elements
2014
We report results of a laser-ICP-MS investigation of trace element contents in the main constituent minerals of an amphibole-bearing migmatite from the Variscan orogen in northeastern Sardinia. The migmatite is associated with migmatised orthogneiss and Al-silicate-bearing pelitic migmatites. The protolith of the amphibole-bearing migmatite was a mid-Ordovician igneous rock of intermediate composition characterised by a biotite + plagioclase + quartz assemblage. The migmatite consists of mesosomes and tonalitic (or, less frequently, granodioritic) leucosomes, characterised by amphibole crystals (potassian ferropargasite) up to 2 cm in size. The tonalitic leucosomes are made up of quartz, pl…
Evolution of the Mayo Kebbi region as revealed by zircon dating: An early (ca. 740Ma) Pan-African magmatic arc in southwestern Chad
2006
Abstract The Mayo Kebbi region in SW Chad is part of the NNE-SSW trending Neoproterozoic Central African Fold Belt (CAFB) and is made up of three calc-alkaline granitoid suites emplaced into a metavolcanic–metasedimentary sequence. The first suite is represented by mafic to intermediate rocks (gabbro-diorite and metadiorite) emplaced between 737 and 723 Ma during early Pan-African convergence. The second consists of the Mayo Kebbi batholith and includes tonalites, trondhjemites and granodiorites, emplaced during several magmatic pulses between 665 and 640 Ma. The third suite includes porphyritic granodiorite and hypersthene monzodiorite dated at ca. 570 Ma. The Mayo Kebbi domain extends sou…
Occurrence and Genesis of Palygorskite and Associated Clay Minerals in a Pleistocene Calcrete Complex, Sde Boqer, Negev Desert, Israel
1996
AbstractPalygorskite and associated clay minerals have been studied in a Pleistocene calcrete complex from the Negev desert (Sde Boqer, Israel). This complex is divided into five main parts: the chalky and marly bedrock overlain by its weathered product, a brecciated calcrete hardpan; the laminar crust; loess pockets trapped in the calcrete; and the overlying soft surficial soil. The distribution of clay minerals is directly dependent on the position of the sample in the calcrete complex. Smectite is inherited from the bedrock in the calcrete with an aeolian enrichment in loess pockets and upper soft soil. The source of kaolinite is mainly detrital, related to desert dust. Illite is partly …
Der meteorit von Breitscheid—III petrographische untersuchung
1959
Abstract The meteorite of Breitscheid is a grey-veined bronzite-olivine-chondrite containing nickel-iron and troilite. It has a remarkably high volume of pores of about 10 per cent. The density of the solid is 3·7, of the stone as a whole 3.3. The chondrules take about 20 per cent of the volume of the stone. The ore minerals are: nickel-iron (kamacite and taenite), troilite, chromite, ilmenite and besides, in the melting crust, magnetite. Especially ilmenite—until recently doubtful as a constituent of meteorites—could be proved in a convincing manner. The silicate constituents are: olivine, bronzite, clinopyroxene, plagioclase (?), glass and a few minerals which could not be identified. The…
PIANCALDOLI METEORITE: CHEMISTRY, MINERALOGY AND PETROLOGY
1976
The fall occurred near Piancaldoli, Florence, Italy, at 19.14 U.T. on the 10th August 1968. The fireball broke up in the atmosphere producing a cloud like a balloon. The trajectory and the terminal point were calculated, leading to the recovery of three small meteoritic fragments, found on the roof of a house. Chemical analysis gave the following results: SiO2 40.80; TiO2 0.15; Al2O3 2. 70; Cr2O3 0.47; FeO 17.20; MnO 0.07; MgO 25.18; CaO 1.95; Na2O 0.64; K2O 0.07; P2O5 0.20; NiS 0.93; FeS 6.24; Fe° 2.40; Ni° 0.40; Co 0.05; sum 99.45. In the lithic portion of the meteorite the following minerals were found: both clino and orthopyroxenes (En = 76 to 98%), olivines (Fo = 66 to 98%), troilite, …