Search results for "equipment and supplies"
showing 10 items of 483 documents
Structural and magnetic characterization of Pd nanoparticles encapsulated in apoferritin
2010
Pd nanoparticles exhibiting permanent magnetism at room temperature have been prepared within the apoferritin cavity. Pd nanoparticles in air and under an inert atmosphere were synthesized to study the influence of the aerobic and anaerobic conditions in the final magnetic properties. The surface of nanoparticles as well as the type of crystalline phase could determine the magnetic properties. X-ray powder diffraction, including Debye-function analysis, transmission electronic microscopy, and magnetization measurements have been used for characterizing the nanoparticles.
Dispersion of magnetic susceptibility in a suspension of flexible ferromagnetic rods
2020
Abstract The properties of suspensions of magnetosomes extracted from magnetotactic bacteria are investigated. By using dynamic light scattering and measuring the dispersion of magnetic susceptibility it is shown that sonicated samples with broken magnetosome chains have qualitatively different behavior in comparison with native samples. This is explained by the presence of flexible chains of magnetosomes in non-sonicated samples which have the qualitative features of magnetic susceptibility predicted by the model of flexible magnetic rods.
Corrosion protection of Nd–Fe–B type permanent magnets by zinc phosphate surface conversion coatings
2001
Abstract The use of protective zinc phosphate top coatings to protect Nd–Fe–B type permanent magnets against corrosion is discussed. The progress of the phosphatisation process has been tested by simultaneous measurement of pH near surface, corrosion potential, substrate mass loss and phosphate coating mass gain. The corrosion behaviour of the magnet in phosphate solution was analyzed by the anodic polarization technique and the general resistance of the magnet to corrosion was evaluated by the Akimov drop test. It is shown that immersion of the magnet in the acidified (pH=2) phosphating solution containing Zn(II), nitrate and fluoride ions resulted in the formation of well adhered, thin an…
Early-stage detection of surface stress corrosion cracking at the subgranular level
2014
The strain field at the interface between an alloy and its oxide layer has been mapped using nanopatterned gauges resistant to the environment of the primary nuclear medium. It was found that oxidation has decreased the alloy ductility, thereby enabling some grain boundary opening to be detectable from 1.8 % strain. It is shown that statistics of extreme rare events of hotspots quantify the occurrence of the local opening of intergranular cracks, and thereby the ageing process.
Characterization of microscopic ferromagnetic defects in thin films using magnetic microscope based on Nitrogen-Vacancy centres
2020
In this work we present results acquired by applying magnetic field imaging technique based on Nitrogen-Vacancy centres in diamond crystal for characterization of magnetic thin films defects. We used the constructed wide-field magnetic microscope for measurements of two kinds of magnetic defects in thin films. One family of defects under study was a result of non-optimal thin film growth conditions. The magnetic field maps of several regions of the thin films created under very similar conditions to previously published research revealed microscopic impurity islands of ferromagnetic defects, that potentially could disturb the magnetic properties of the surface. The second part of the measur…
Tailoring the microstructure and mechanical properties of Ti–Al alloy using a novel electromagnetic stirring method
2006
The effect of melt convection during the solidification of Ti45Al55 alloys was investigated in terms of microstructure evolution and the resulting mechanical properties. The samples were subjected to conventional induction melting as well as enhanced melt stirring by an external magnetic field using a specially designed floating zone arrangement. The stirred samples showed a significant improvement of plastic deformability. A strong change in the morphology from dendritic to spherical and an increased properitectic phase fraction were observed after stirring.
Electrochemical behaviour of copper-nickel alloys as immobilisation matrices for the storage of fission products in CO2-enriched synthetic groundwater
2013
International audience; The surface properties of nickel and copper alloys exposed to simulated French Callovo-Oxfordien ground-water (aerated and CO2-saturated solutions) have been evaluated from electrochemical impedance spectroscopy in conjunction with X-ray photoelectron spectroscopy. The kinetic reactions and physical properties of the layers grown on the alloy's surfaces, change versus the Ni content in the alloys and the presence of CO2 in the solution. Nickel alloys retain favourable passive properties in such environments, whereas oxide products on copper alloys are insufficiently protective when formed in the absence of dissolved oxygen in the electrolyte. A maximum addition of 30…
Multi-spectral Reflection Photoplethysmography: Potential for Skin Microcirculation Assessment
2006
Technique for simultaneous recording of reflection photoplethysmography signals in broad spectral band (violet to NIR) has been developed, and its potential for assessment of blood microcirculation at various depths from the skin surface is discussed.
Characterization of the ESR response of alanine dosimeters to low-energy Cu-target X-tube photons
2017
Abstract This article describes Electron Spin Resonance (ESR) response measurements of Kodak BioMax alanine films exposed to low-energy X-rays from a Cu-target tube operating at 20 kV. Commercial alanine detectors were used to ensure maximum reproducibility of the results, while the choice of a film was due the low penetration of the soft X-rays. X-ray energy spectra and fluences were determined with an innovative digital semiconductor detector system. These data were used to quantify the irradiation of the alanine films in terms of absorbed dose to water. The alanine films were found to present a stable response, highly linear with dose. To our knowledge, these data have not been previousl…
Core-shell PLA/Kef hybrid scaffolds for skin tissue engineering applications prepared by direct kefiran coating on PLA electrospun fibers optimized v…
2021
Abstract Over the recent years, there is a growing interest in electrospun hybrid scaffolds composed of synthetic and natural polymers that can support cell attachment and proliferation. In this work, the physical and biological properties of polylactic acid (PLA) electrospun mats coated with kefiran (Kef) were evaluated. Gravimetric, spectroscopic (FTIR-ATR) and morphological investigations via scanning electron microscopy confirmed the effective formation of a thin kefiran layer wrapped on the PLA fibers with an easy-tunable thickness. Air plasma pre-treatment carried out on PLA (P-PLA) affected both the morphology and the crystallinity of Kef coating as confirmed by differential scanning…