Search results for "ether"

2020

Epoxy resin plays a key role in composite matrices and DGEBA is the major precursor used. With the aim of favouring the use of bio resources, epoxy resins can be prepared from lignin. In particular, diglycidyl ether of isoeugenol derivatives are good candidates for the replacement of DGEBA. This article presents an effective and eco-friendly way to prepare epoxy resin derived from isoeugenol (BioIgenox), making its upscale possible. BioIgenox has been totally characterized by NMR, FTIR, MS and elemental analyses. Curing of BioIgenox and camphoric anhydride with varying epoxide function/anhydride molar ratios has allowed determining an optimum ratio near 1/0.9 based on DMA and DSC analyses a…

Lagrangians, Hamiltonians and Noether’s Theorem

2015

This chapter is intended to remind the basic notions of the Lagrangian and Hamiltonian formalisms as well as Noether’s theorem. We shall first start with a discrete system with N degrees of freedom, state and prove Noether’s theorem. Afterwards we shall generalize all the previously introduced notions to continuous systems and prove the generic formulation of Noether’s Theorem. Finally we will reproduce a few well known results in Quantum Field Theory.

Unequal Attainments: Ethnic educational inequalities in ten Western countries

2014

Western countries have become increasingly diverse in recent decades and these demographic trends are certain to continue. The resulting ethnic diversity is a major challenge to policy-makers, who need to tackle issues of social justice and social integration. Education plays a pivotal role since it is the major stepping stone for the children of immigrants to successful economic integration and also plays a major role in social and political integration more generally since education gives access to the skills, resources and contacts which enable individuals to participate fully in the life of their society. Our central research questions are: Do the descendants of migrants experience equa…

The electromagnetic and Proca fields revisited: A unified quantization

1997

Quantizing the electromagnetic field with a group formalism faces the difficulty of how to turn the traditional gauge transformation of the vector potential, Aμ(x) → Aμ(x) + ∂μφ(x), into a group law. In this paper, it is shown that the problem can be solved by looking at gauge transformations in a slightly different manner which, in addition, does not require introducing any BRST-like parameter. This gauge transformation does not appear explicitly in the group law of the symmetry but rather as the trajectories associated with generalized equations of motion generated by vector fields with null Noether invariants. In the new approach the parameters of the local group, U(1)(x, t), acquire dyn…

The occurrence of Dechlorane Plus and related norbornene-based flame retardants in Baltic wild salmon (Salmo salar)

2015

Twenty five Baltic wild salmon (Salmo salar) specimens were analysed for the content of Dechlorane-related compounds (DRCs). Out of the ten analysed DRCs, seven compounds were detected in the muscle tissues of salmon, including Dechlorane (Dec) 602, Dec 603, syn- and anti-stereoisomers of Dechlorane Plus (DP), Dechlorane Plus monoadduct (1,3-DPMA), hexachlorocyclopentadienyl-dibromocyclooctane (DBHCTD), and Mirex. The concentrations of Dec 604 and two DP dechlorinated compounds - decachloropentacyclooctadecadiene (Cl10DP) and undecachloropentacyclooctadecadiene (Cl11DP) - were below the limit of detection in all samples. The aggregated concentrations of DRCs (ΣDRC) were in the range of 551-…

Occurrence of polybrominated diphenyl ethers, perfluorinated compounds, and nonsteroidal anti-inflammatory drugs in freshwater mussels from Latvia.

2018

Abstract The occurrence of polybrominated diphenyl ethers (PBDE), perfluorinated compounds (PFC), and nonsteroidal anti-inflammatory drugs (NSAID) in Latvian freshwater ecosystems was evaluated by using filter-feeding mussels as bioindicators. Twenty four samples of mussels were collected from freshwater bodies throughout the territory of Latvia during the summer of 2017. PBDE contamination was ubiquitous, reaching the highest total concentration of 193.2 pg g−1 w.w. BDE-209 was the most abundant compound, followed by penta-BDE components BDE-49, -100, −99, −153, −154, and −47 in decreasing order. The levels of PFCs in Latvian mussels were generally lower than those reported from other regi…

The use of blue tit eggs as a biomonitoring tool for organohalogenated pollutants in the European environment

2010

In the present study, large scale geographical variation in the occurrence of organohalogenated pollutants (OHPs) was investigated throughout Europe using eggs of a terrestrial resident passerine species, the blue tit (Cyanistes caeruleus). Blue tit eggs from 10 sampling locations, involving suburban, rural and remote areas, in 7 European countries were collected and analysed. Sum polychlorinated biphenyl (PCB) levels ranged from 150 ng/g lipid weight (lw) to 2003 ng/g lw. Sum polybrominated diphenyl ethers (PBDEs) ranged from 3.95 ng/g lw to 114 ng/g lw. As expected, PCB and PBDE concentrations were significantly higher in the sampled suburban locations compared to the rural and remote loc…

Hydrogen sulfide and odor removal by field-scale biotrickling filters: Influence of seasonal variations of load and temperature

2012

Two biotrickling filters were set up at two wastewater treatment plants (WWTP) in The Netherlands to investigate their effectiveness for treatment of odorous waste gases from different sources. One biotrickling filter was installed at Nieuwe Waterweg WWTP in Hook of Holland to study the hydrogen sulfide removal from headworks waste air. The other reactor was installed at Harnaschpolder WWTP (treating wastewater of the city of The Hague) to remove mercaptans and other organic compounds (odor) coming from the emissions of the anaerobic tanks of the biological nutrient removal (BNR) activated sludge. The performance of both units showed a stable and highly efficient operation under seasonal va…

The preparation and evaluation of core-shell magnetic dummy-template molecularly imprinted polymers for preliminary recognition of the low-mass polyb…

2020

Abstract The design, preparation process, binding abilities, morphological characteristic and prospective field of application of dummy-template magnetic molecularly imprinted polymer (DMMIP) for preliminary recognition of the selected low-mass polybrominated diphenyl ethers (PBDE-47 and PBDE-99) from aquatic environment were investigated. The surface of iron oxide (Fe3O4) nanopowder (50–100 nm particles size) was modified with tetraethoxysilane and next prepared Fe3O4@SiO2 particles were dispersed in anhydrous toluene functionalized by (3-aminopropyl)triethoxysilane. Finally, MIPs' thin film layer on the surface of Fe3O4@SiO2@NH2 was formed in acetonitrile as a solvent solution, using ethy…

PCDEs, PCBs, PCDDs AND PCDFs in black guillemots and white-tailed sea eagles from the Baltic Sea

1995

Abstract Concentrations and patterns of several chloro compounds including polychlorinated dibenzo p-dioxins (PCDD), dibenzofurans (PCDF), biphenyls (PCB) and diphenyl ethers (PCDE) were determined in black guillemots ( Cepphus grylle L.) and white-tailed sea-eagles ( Hallaeetus albicilla L.) from the Baltic Sea environment. Three breast muscles of eagles were analyzed and had different concentrations and patterns of the studied compounds, whereas the three guillemot eggs were found to have more similar levels and patterns. The concentrations of individual PCDE congeners varied from