Search results for "etica"
showing 10 items of 14083 documents
A DFT Study of Linear Gold–Thiolate Superclusters Absorbing in the Therapeutic NIR Window
2015
A series of linear clusters up to an aspect ratio of 1:6, formed as multimers of smaller clusters with an icosahedral Au13(5+) core having an eight-electron superatom configuration, are computationally predicted to have a greatly enhanced size-dependent absorption in the near-infrared (NIR) region extending to the biologically important NIR window. A novel structural model is presented for the previously isolated thiol-stabilized Au54(SR)30 cluster, where the metal core is formed as a heterodimer of the cores of the known Au25(SR)18(-/0) and Au38(SR)24 clusters.
The Role of the Anchor Atom in the Ligand of the Monolayer-Protected Au25(XR)18– Nanocluster
2015
We present a density functional theory (DFT) investigation on the role of the anchor atom and ligand on the structural, electronic, and optical properties of the anionic Au25(XR)18– nanocluster (X = S, Se, Te; R = H, CH3, and (CH2)2Ph). Substituting the anchor atom with other group 16 elements induces subtle changes in the Au–Au and Au–X bond lengths and polarization of the covalent bond. The changes in the electronic structure based on substituting both the anchor and R groups are presented through careful analysis of the density of states and theoretical determined optical spectra. We give a detailed side-by-side comparison into the structural, electronic, and optical properties of Au25(X…
The electronic structure of Ge9[Si(SiMe3)3]3-: a superantiatom complex.
2012
We report on the electronic structure of Ge(9)[Si(SiMe(3))(3)](3)(-). Systematic density functional theory analysis of the electronic shell structure of the cluster and its derivatives reveals that the Ge(9)[Si(SiMe(3))(3)](3)(-) and its neutral counterpart have electronic shells that can be explained using the superatom model. The ligand-core interaction of these complexes is distinctly different from previously identified gold, gallium, and aluminium superatom complexes, indicating an electron-donating rather than electron-withdrawing ligand. We modify the electron-counting rule for this case and introduce a simple picture for superatom and superantiatom complexes. Discussions comparing s…
JIMWLK and beyond: From concepts to observables
2016
Volume: 112 Host publication title: 6th International Conference on Physics Opportunities at an Electron-Ion Collider The Color Glass Condensate and its associated evolution equation, the JIMWLK equation have applications to many observables far beyond totally inclusive observables. The phenomenology is so rich that little has been done to explore beyond scaling behavior of correlators. We show first examples that exemplify the considerations necessary to access additional information both experimentally and theoretically and demonstrate that the Wilson line correlators appearing throughout make it imperative to consistently take into account that one is dealing with correlators of group el…
Adsorption and Activation of Water on Cuboctahedral Rhodium and Platinum Nanoparticles
2017
Rh and Pt are widely used as the components in heterogeneous catalysts for multiple industrial applications. Because the metals are typically in the form of nanoparticles in real catalysts, it is important to carefully select models for the computational prediction of the catalytic properties. Here we report a first-principles study on the water activation, an important step in numerous catalytic reactions, using the finite-size Rh and Pt nanoparticle models and compare them to the extended surface models. We show that regardless of the model, adsorption and activation of water is practically identical for both metals, whereas the dissociation is energetically more favorable on Rh. The expe…
Prometeo genetista. Profitti delle tecniche e metafore della scienza
2016
Il saggio di Claude Calame affronta una tematica di grande rilievo scientifico, ossia il confronto tra il valore epistemologico e sociale dell'uso delle arti tecniche nell'antica Grecia e il valore epistemologico del linguaggio della scienza moderna in particolare applicato all'ambito della genetica e delle moderne biotecnologie e scienze di laboratorio. Lo spunto del confronto è offerto dall'analisi storico-culturale e antropologica del mito di Prometeo, come è stato diversamente declinato dai vari autori dell'antichità classica, a partire da Esiodo sino a Platone, passando per l'autore del dramma "Prometeo incatenato". In una prospettiva di indagine antropopoietica, le arti tecniche perme…
Video art between aesthetic maturity and medium immersion: Patterns of change and generational shift in moving image technology
2018
This chapter addresses how technological change in the field of moving images affected the visual arts by means of various waves depending on the subsequent generations of artists, who employed the new medium according to their awareness and nativity towards the video.
L'intersezione di filosofia e teologia nel "Discorso sul Dio in cui credo" di Francesco Conigliaro
2017
Una discussione dei nodi filosofici contenuti nel recente ampio libro di F. Conigliaro sul tema della Trinità cristiana, e dei filosofi coinvolti nella trattazione di Conigliaro.