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Control of Morphology and Corona Composition in Aggregates of Mixtures of PS-b-PAA and PS-b-P4VP Diblock Copolymers: Effects of Solvent, Water Conten…
2014
The morphologies and corona compositions in aggregates of mixtures of PS-b-PAA and PS-b-P4VP diblock copolymers are influenced by controllable assembly parameters such as water content, block copolymer molar ratios, and solvent effects as well as the hydrophilic block lengths and block length ratios. All these factors can affect the morphology of the aggregates as well as their corona composition, the latter especially in vesicles, where two interfaces are involved. The morphologies and corona compositions of the aggregates were investigated by transmission electron microscopy and electrophoretic mobility, respectively. They depend, to a large extent, on the solubility of P4VP and PAA in th…
Control of Corona Composition and Morphology in Aggregates of Mixtures of PS-b-PAA and PS-b-P4VP Diblock Copolymers: Effects of pH and Block Length
2014
The corona compositions and morphologies in aggregates of mixtures of amphiphilic polystyrene-block-poly(acrylic acid) (PS-b-PAA) and polystyrene-block-poly(4-vinylpyridine) (PS-b-P4VP) diblock copolymers are influenced by controllable assembly parameters such as the hydrophilic block length and solution pH. The morphologies and corona compositions of the aggregates were investigated by transmission electron microscopy and electrophoretic mobility, respectively. When mineral acids or bases are present during aggregate formation, they can exert a strong influence on the corona composition. Morphology changes were also seen with changing pH, as well as changes in corona composition, specifica…
Effect of bisphenol A on ameloblasts and tooth enamel mineralization
2011
Effect of bisphenol A on ameloblasts and tooth enamel mineralization. Journées de l’école doctorale
Idiosyncratic responses to simulated herbivory by root fungal symbionts in a subarctic meadow
2021
Plant-associated fungi have elementary roles in ecosystem productivity. There is little information on the interactions between arbuscular mycorrhizal (AM) fungal symbiosis, fine endophytic (FE) and dark septate endophytic (DSE) fungi, and their host plants in cold climate systems. In particular, the environmental filters potentially driving the relative abundance of these root symbionts remain unknown. We investigated the interlinkage of plant and belowground fungal responses to simulated herbivory (clipping, fertilization, and trampling) in a subarctic meadow system. AM and FE frequency in the two target plant roots, Potentilla crantzii and Saussurea alpina, was unaffected by simulated he…
Forensic tools for the diagnosis of electrocution death: Case study and literature review
2018
Diagnosis of death by electrocution may be difficult when electric marking is not visible or unclear. Accordingly, the body of a man who appeared to have died from accidental electrocution was carefully forensically analysed. Macroscopic and microscopic analysis of the current mark was carried out using a variable-pressure scanning electron microscope equipped with energy dispersive X-ray microanalyser to highlight skin metallisation, indicating the presence of iron and zinc. The histological findings of electrocution myocardial damage were supported by the results of biochemical analysis which demonstrated the creatine kinase-MB and cardiac troponin I elevation. The effects of electric cu…
Water dissociation and water-gas shift energetics on MgO, MgO/Ag and Au/MgO/Ag surfaces
2011
Water dissociation and the energetics of the WGS reaction on a bulk MgO, an Ag supported MgO thin film and Au/MgO/Ag surfaces is studied based on the density functional theory. The literature results for water splitting on MgO and MgO/Ag surfaces with a step type defect are repeated and further analysis on the origin of the energetically favored dissociative water adsorption are made. The reactivity towards water dissociation on the stepped MgO and MgO/Ag surfaces is attributed to four contributing factors: 1. The change in the interlayer distance of the surface in dissociative adsorption is diminished on the stepped surfaces compared to the flat surfaces. On the flat surfaces the dissociat…
Wykorzystanie energii wiatru występującego w warstwie przygruntowej oraz architektonicznej
2016
W pracy przedstawiono wyniki analiz możliwości wykorzystania energii wiatru za pomocą mikro turbin wiatrowych. Przeanalizowano możliwość wykorzystania energii wiatru występującego w warstwie przygruntowej oraz architektonicznej. Zaproponowano zastosowanie układu mikroelektrowni wiatrowej o mocy 2 kW na potrzeby pojedynczego gospodarstwa domowego.Określono opłacalność zastosowania tego typu mikroelektrowni w warunkach wietrzności panujących w Opolu.
Topological surface wave metamaterials for robust vibration attenuation and energy harvesting
2021
International audience; We propose topological metamaterials working in Hertz frequency range, constituted of concrete pillars on the soil ground in a honeycomb lattice. Based on the analog of the quantum valley Hall effect, a non-trivial bandgap is formed by breaking the inversion symmetry of the unit cell. A topological interface is created between two different crystal phases whose robustness against various defects and disorders is quantitatively analyzed. Finally, we take advantage of the robust and compact topological edge state for designing a harvesting energy device. The results demonstrate the functionality of the proposed structure for both robust surface vibration reduction and …
Through space singlet-singlet and triplet-triplet energy transfers in cofacial bisporphyrins held by the carbazoyl spacer
2007
The through space singlet-singlet and triplet-triplet energy transfers in cofacial bis(etio-porphyrins) rigidly held by the carbazoyl spacer were investigated. The studies on singlet-singlet transfer, which operates via a Förster mechanism, were performed using the zinc porphyrin and free base chromophores as energy donor and acceptor, respectively, while the investigation on triplet-triplet processes was performed using the palladium porphyrin, and the zinc porphyrin and free base chromophores as donor and acceptors, respectively. The rate for singlet-singlet transfer ( k ET ( singlet )) is unexpectedly slower than that reported for other similar, rigidly held bisporphyrins such as H 2( D…
Factores predictores del engagement positivo y negativo de la marca país España en Facebook
2020
En todo contexto de comunicación, intervienen tres factores (el mensaje, el contexto, y la audiencia). Considerando al engagement como parte del proceso de comunicación de las marcas con los consumidores, la presente tesis desea conocer los predictores del engagement positivo y del engagement negativo relacionados con el mensaje, el contexto y la audiencia. En general, la revisión de la literatura reveló que son necesarios nuevos estudios en torno a estas variables. Por ello, la presente investigación persigue 3 objetivos: (i) identificar cuáles son las variables clave de diseño de un mensaje en una red social (concretamente Facebook) que un anunciante puede utilizar para aumentar el engage…