Search results for "feature"
showing 10 items of 4091 documents
Analysis of the presence of perfluoroalkyl substances in water, sediment and biota of the Jucar River (E Spain). Sources, partitioning and relationsh…
2016
The presence, sources and partitioning of 21 perfluoroalkyl substances (PFASs: C4–C14, C16, C18 carboxylate, C4, C6–C10 sulfonates and C8 sulfonamide) were assessed in water, sediment, and biota of the Jucar River basin (E Spain). Considering the three matrices, perfluoropentanoate (PFPeA) and perfluorooctane sulfonate (PFOS) were the most frequent compounds, being remarkable the high occurrence of short-chain PFASs (C≤8), which are intended to replace the long-chain ones in several industrial and commercial applications. In general, all samples were contaminated with at least one PFAS, with the exception of three fish samples. Mean concentrations detected in sediments (0.22–11.5 ng g−1) an…
Mercury levels in sediments of central Mediterranean Sea: a 150+ year record from box-cores recovered in the Strait of Sicily.
2006
To evaluate the degree of anthropogenic mercury pollution, Hg contents have been measured for box-core sediments sampled along three nearshore-offshore transects in the Strait of Sicily and well constrained for their mineralogy, bulk geochemistry and TOC%. Hg values are generally low (from 15 to 70 microg kg(-1)); however, depth profiles clearly display upcore rising concentrations (up to 202 microg kg(-1) near the SE Sicily coast) that are attributed to anthropogenic load. Based on (210)Pb chronology, these trends are more dramatic across the last 20-30 years. Geogenic influence is thought to explain some anomalies related to volcanic emission and geothermal activity. Combined effects due …
Perfluoroalkyl substance contamination of the Llobregat River ecosystem (Mediterranean area, NE Spain).
2014
The occurrence and sources of 21 perfluoroalkyl substances (PFASs: C4-C14, C16, C18 carboxylate, C4, C6-C8 and C10 sulfonates and C8 sulfonamide) were determined in water, sediment, and biota of the Llobregat River basin (NE Spain). Analytes were extracted by solid phase extraction (SPE) and determined by liquid chromatography triple quadrupole mass spectrometer (LC-QqQ-MS). All samples were contaminated with at least one PFAS, being the most frequently found perfluorobutanoate (PFBA), perfluorooctanoate (PFOA) and perfluorooctane sulfonate (L-PFOS). In general, mean PFAS concentrations measured in sediments (0.01-3.67 ng g(-1)) and biota (0.79-431 μg kg(-1)) samples were higher than those …
Geochemical characterization of surface waters and groundwater resources in the Managua area (Nicaragua, Central America)
2008
This paper reports new geochemical data on dissolved major and minor constituents in surface waters and ground waters collected in the Managua region (Nicaragua), and provides a preliminary characterization of the hydrogeochemical processes governing the natural water evolution in this area. The peculiar geological features of the study site, an active tectonic region (Nicaragua Depression) characterized by active volcanism and thermalism, combined with significant anthropogenic pressure, contribute to a complex evolution of water chemistry, which results from the simultaneous action of several geochemical processes such as evaporation, rock leaching, mixing with saline brines of natural or…
Sensitivity Analysis Of Multi-Electrode Arrays For Characterizing The Non-Saturated Zone In Groundwater Vulnerability Assessment
2009
The near-surface environment acts as a filter and buffer for contaminants introduced from the surface by anthropogenic activities. For this reason there is a great need to improve our understanding of the shallow subsurface taking into account the increasing demand for vulnerability maps which illustrates the exposure of aquifers against pollution. These maps are designed to show areas of greatest potential for groundwater contamination on the basis of local subsurface conditions. A shallow, unconfined sand-and-gravel aquifer is highly vulnerable to pollutants because rapid recharge gives little time to contaminants to degrade naturally or be adsorbed before reaching the aquifer. Conversely…
Ecological and human health risks appraisal of metal(loid)s in agricultural soils: a review
2019
Agriculture is one of the major human activities that changed the landforms, water resources and the biogeochemical cycles. Pollution of agricultural soilsby metal(loid)s is a serious and global hazard but worldwide studies related to metal(loid)s pollution in agricultural soils are very limited. To fulfil this gap, metal(loid)s content in agricultural soils from 2001 to 2019 all over the world was reviewed. Multivariate statistical techniques, contamination indices and human health risk assessment were determined for the metal(loid)s. Among the analysed metal(loid)s, the average contents of Zn, Cu, Pb, Cr, Cd, As and Ni exceeded the Canadian, and China soil guidelines limits. The results o…
Hydrogen sulfide measurements in air by passive/diffusive samplers and high-frequency analyzer: A critical comparison
2016
In this study, hydrogen sulfide (H2S) measurements in air carried out using (a) passive/diffusive samplers (Radiello® traps) and (b) a high-frequency (60 s) real-time analyzer (Thermo® 450i) were compared in order to evaluate advantages and limitations of the two techniques. Four different sites in urban environments (Florence, Italy) and two volcanic areas characterized by intense degassing of H2S-rich fluids (Campi Flegrei and Vulcano Island, Italy) were selected for such measurements. The concentrations of H2S generally varied over 5 orders of magnitude (from 101e103 mg/m3), the H2S values measured with the Radiello® traps (H2SR) being significantly higher than the average values measure…
Gas chromatography-mass spectrometry study of polycyclic aromatic hydrocarbons in grass and milk from urban and rural farms
2000
Polycyclic aromatic hydrocarbon (PAH) levels were studied in grass and milk sampled at two farms, one located in a non-contaminated, rural area, and another located in a urban area close to PAH sources such as highways, busy roads, fuel-powered trains and a steel plant. PAH concentration were measured by gas chromatography coupled to mass spectrometry (GC-MS) using internal deuterated standards. In grasses, unexpectedly, although the sum of PAH concentrations was only slightly higher at the urban farm (83.1 ± 16.1 ng g−1) than the rural farm (51.8 ± 10.6 ng g−1), this difference was not observed for all PAH members. This absence of a striking difference of PAH levels between urban and rura…
Major and trace element distribution in the peat from ombrotrophic bogs in Latvia.
2011
This study was undertaken to analyse major and trace elements and the nature of their accumulation in peat, with a particular emphasis on peat properties and the impact of local and regional pollution sources on the character of element accumulation in ombrotrophic bogs in Latvia. The element concentration values in peat from Latvia reflect the local processes that affect element concentrations in the peat mass, indicating accumulation of trace elements – apparently of anthropogenic origin (Pb, Cd, Co, Ni and others) – in the upper layers of the peat profiles. In addition, they indicate accumulation of several elements (for example, As, Cr and others) in deeper layers of bog, possibly due t…
The Impact of the Changing Climate on the Supply and Recycling of Nitrate
2009
A high proportion of the nitrogen found in lakes and rivers is present in the form of nitrate. The concentration of nitrate in many surface waters has increased over the last forty years (OECD, 1982; Roberts and Marsh, 1987; Johnes and Burt, 1993). The main source of nitrate is diffuse drainage from agricultural land (Vinten and Smith, 1993) but point sources can be important in populated areas (Jarvey et al., 1998). In 1991, the European Union introduced the Nitrates Directive (91.676) to protect waters from pollution by nitrate leached from agricultural land.