Search results for "femtosecond"

Controlling ground-state rotational dynamics of molecules by shaped femtosecond laser pulses

2004

We report controlled excitation of ground-state rotational wave packet by pulse-shaping technique. The experiment is conducted in nitrogen $({\mathrm{N}}_{2})$ at room temperature and atmospheric pressure. A femtosecond laser pulse produces rotational coherences in the vibronic ground state of ${\mathrm{N}}_{2}$ through an impulsive Raman process. The laser pulse is tailored using a spatial light modulator producing spectral phase modulation. Periodic phase steps are applied in order to control the excitation of specific rotational Raman transitions. The outcome is the modification of the relative excitation between odd and even rotational states which allows the control of the symmetry and…

Rotational coherence imaging and control for CN molecules through time-frequency resolved coherent anti-Stokes Raman scattering

2011

Numerical wave packet simulations are performed for studying coherent anti-Stokes Raman scattering (CARS) for CN radicals. Electronic coherence is created by femtosecond laser pulses between the X²Σ and B²Σ states. Due to the large energy separation of vibrational states, the wave packets are superpositions of rotational states only. This allows for a specially detailed inspection of the second- and third-order coherences by a two-dimensional imaging approach. We present the time-frequency domain images to illustrate the intra- and intermolecular interferences, and discuss the procedure to rationally control and experimentally detect the interferograms in solid Xe environment. peerReviewed

Broadband telecom to mid-infrared supercontinuum generation in a dispersion-engineered silicon germanium waveguide.

2015

We demonstrate broadband supercontinuum generation (SCG) in a dispersion-engineered silicon-germanium waveguide. The 3 cm long waveguide is pumped by femtosecond pulses at 2.4 μm, and the generated supercontinuum extends from 1.45 to 2.79 μm (at the −30  dB point). The broadening is mainly driven by the generation of a dispersive wave in the 1.5–1.8 μm region and soliton fission. The SCG was modeled numerically, and excellent agreement with the experimental results was obtained.

<title>Second harmonic generation in selenium thin films</title>

2008

Results of second harmonic (SH) generation in amorphous and crystalline selenium films induced by titanium-sapphire femtosecond laser (wavelength λ - 800-1000 nm) are presented. It is found that the highest intensity of SH is provided by fundamental wave at wavelength 1000 nm and it reaches maximum in approximately 100 sec. The intensity of transmitted SH depends on film thickness while that of reflected does not.

<title>Second harmonic generation in selenium-metal structures</title>

2008

The article examines the processes of second harmonic generation (SHG) when selenium-metal (Cu) film structures are illuminated by femtosecond radiation (180 fs, 80 MHz) at wavelength 800 - 1000 nm. Selenium-copper structures were obtained by successive thermal evaporation of selenium and copper onto the glass substrate in vacuum. Microanalysis of the film composition was performed to determine amount of copper in thin films. The as-evaporated selenium-copper structures were crystallised by annealing in inert atmosphere at temperature 85°C. Just evaporated as well as annealed thin films were explored. The experiment was performed by confocal microscope [1] where the femtosecond radiation fr…

Author response: The primary structural photoresponse of phytochrome proteins captured by a femtosecond X-ray laser

2020

Acoustic vibrations of metal nanoparticles: high order radial mode detection

2004

The vibrational radial modes of silver nanospheres embedded in a glass matrix are investigated using a high sensitivity femtosecond pump-probe technique. The results yield evidence for coherent launching of the fundamental and higher order radial modes in agreement with a sphere dilation mediated excitation model. The results are consistent with low-frequency Raman scattering experiments.

Observation of laser-induced field-free permanent planar alignment of molecules

2011

International audience; Permanent planar alignment of gas-phase linear molecules is achieved by a pair of delayed perpendicularly polarized short laser pulses. The experiment is performed in a supersonic jet, ensuring a relatively high number density of molecules with moderately low rotational temperature. The effect is optically probed on a femtosecond time scale by the use of a third short pulse, enabling a time-resolved birefringence detection performed successively in two perpendicular planes of the laboratory frame. The technique allows for an unambiguous estimation of the molecular planar delocalization produced within the polarization plane of the pulse pair after the turn-off of the…

Ultrafast stimulated Raman parallel adiabatic passage by shaped pulses

2009

We present a general and versatile technique of population transfer based on {\it parallel adiabatic passage} by femtosecond shaped pulses. Their amplitude and phase are specifically designed to optimize the adiabatic passage corresponding to parallel eigenvalues at all times. We show that this technique allows the robust adiabatic population transfer in a Raman system with the total pulse area as low as 3 $\pi$, corresponding to a fluence of one order of magnitude below the conventional stimulated Raman adiabatic passage process. This process of short duration, typically pico- and subpicosecond, is easily implementable with the modern pulse shaper technology and opens the possibility of ul…

Alignement moléculaire sous impulsions laser ultracourtes

2006

Talk given by O. Faucher; National audience