Search results for "fluori"

showing 10 items of 687 documents

New Fluorinated Peptidomimetics through Tandem Aza-Michael Addition to α-Trifluoromethyl Acrylamide Acceptors: Synthesis and Conformational Study in …

2009

A range of partially modified retro (PMR) psi[NHCH(2)] peptide mimetics containing a hydrolytically stable CH(2)CH(CF(3))CO unit have been synthesized. The first kind of peptidomimetics is obtained from the highly efficient aza-Michael addition of different amines to alpha-trifluoromethyl acrylamide acceptors. Subsequent deprotection of the amino group furnishes the key common intermediate for the synthesis of other families of peptidomimetics: dipeptides, tripeptides, peptidomimetics containing a urea moiety, and structures containing two units of alpha-trifluoromethyl-beta(2)-alanine. Finally, a conformational study of several of the newly synthesized peptidomimetics, performed with the a…

AcrylamidesAza CompoundsAlanineMagnetic Resonance SpectroscopyDipeptideTrifluoromethylChemistryTrifluoromethylationStereochemistryFluorine CompoundsOrganic ChemistryMolecular ConformationTripeptideCrystallography X-RayChemical synthesisSolutionschemistry.chemical_compoundCascade reactionpeptidomimeticsMichael reactionMoietyPeptidesThe Journal of Organic Chemistry
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Preparation and Promotion of Fruit Growth in Kiwifruit of Fluorinated N-Phenyl-N‘-1,2,3-thiadiazol-5-yl Ureas

2004

Seventeen phenyl-fluorinated analogues of thidiazuron [N-phenyl-N'-(1,2,3-thiadiazol-5-yl)urea, TDZ] have been prepared and characterized. The effects of each fluorinated urea on growth and quality of kiwifruits (Actinidia deliciosa) were evaluated by comparison with untreated (control) and TDZ-treated fruits. The results obtained showed a clear dependence of the growth-promoting activity of these fluorinated ureas on the pattern and degree of fluorine substitution in the phenyl ring. The most effective for promoting fruit growth was N-(2,3,5,6-tetrafluorophenyl)-N'-(1',2',3'-thiadiazol-5'-yl)urea at 25 ppm (at harvest, treated fruits were 58% heavier than untreated ones) followed by N-(3,5…

Actinidia deliciosaGrowth promotingbiologyChemistryPhenylurea CompoundsActinidiaFluorine CompoundsQuantitative Structure-Activity RelationshipTitratable acidGeneral Chemistrybiology.organism_classificationchemistry.chemical_compoundSoluble solidsFruitThidiazuronThiadiazolesBotanyUreaDry matterGeneral Agricultural and Biological SciencesNuclear chemistryJournal of Agricultural and Food Chemistry
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Efficacy of an amine fluoride-triclosan mouthrinse as compared to the individual active ingredients

2003

Background: The purpose of the clinical study was to examine the antibacterial and plaque-reducing properties of mouthrinses containing triclosan (TRI), amine fluoride (AmF), and the combination of both (AFT) on 4-day plaque regrowth. A placebo solution (PLA) and a 0.2% chlorhexidine solution (CHX) served as negative and positive controls, respectively. Materials & Methods: After a professional tooth cleaning (day 0), 15 volunteers refrained from all mechanical oral hygiene measures for the next 96 h and rinsed instead twice daily for 1 min with 10 ml of one of the five randomly assigned solutions. Plaque index (PlI), which was assessed after 24 and 96 h (PlI1, PlI2), and plaque area of the…

Active ingredientbusiness.industryChemistryChlorhexidineAmine fluorideBiofilmDentistryPlaceboOral hygieneTriclosanchemistry.chemical_compoundStatistical significancemedicinePeriodonticsbusinessmedicine.drugJournal of Clinical Periodontology
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Comparison of combined application treatment with one-visit varnish treatments in an orthodontic population

2013

Objective: To evaluate the effect of chlorhexidine-thymol varnish alone, its combination with chlorhexidine-fluo - ride containing dentifrice and fluoride varnish on oral hygiene and caries prevention in orthodontic patients. Study design: Sixty patients, aged 12-18, with orthodontic fixed appliances were randomly assigned into three groups as follows: Group 1 (n=20): 1% chlorhexidine and 1% thymol varnish (Cervitec ® Plus); Group 2 (n=20): Cervitec ® Plus+ 0.2% chlorhexidine and 0.2% sodium fluoride (900 ppm fluoride) (Cervitec ® Gel)); and Group 3 (n=20): 0.1% fluoride varnish (Fluor Protector ® ). Mutans streptococci (MS), lactobacilli (LB) levels, buffering capacity (BC), visible plaque…

AdolescentOffice VisitsPopulationDentistryOrthodonticsOdontologíaDental CariesOral hygieneOrthodontics Correctivechemistry.chemical_compoundGingivitisFluoridesSodium fluorideDentifricemedicineHumansFluorides TopicalSingle-Blind MethodProspective StudieseducationChildGeneral DentistryOrthodonticseducation.field_of_studybusiness.industryChlorhexidineFluoride varnishChlorhexidine:CIENCIAS MÉDICAS [UNESCO]Ciencias de la saludThymolDrug CombinationsOtorhinolaryngologychemistryUNESCO::CIENCIAS MÉDICASAnti-Infective Agents LocalSurgeryResearch-Articlemedicine.symptombusinessFluorideToothpastesmedicine.drug
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PET Studies of Net Blood—Brain Clearance of FDOPA to Human Brain: Age-Dependent Decline of [18F]Fluorodopamine Storage Capacity

2005

Conventional methods for the graphical analysis of 6-[18F]fluorodopa (FDOPA)/positron emission tomography (PET) recordings ( Kappin) may be prone to negative bias because of oversubtraction of the precursor pool in the region of interest, and because of diffusion of decarboxylated FDOPA metabolites from the brain. These effects may reduce the sensitivity of FDOPA/PET for the detection of age-related changes in dopamine innervations. To test for these biasing effects, we have used a constrained compartmental analysis to calculate the brain concentrations of the plasma metabolite 3- O-methyl-FDOPA (OMFD) during 120 mins of FDOPA circulation in healthy young, healthy elderly, and Parkinson's …

AdultAgingFluorine Radioisotopesmedicine.medical_specialtyMetaboliteDiffusionCentral nervous system diseasechemistry.chemical_compoundDopamineInternal medicinemedicineHumans18F-fluorodopamineFluorodopamedicine.diagnostic_testbusiness.industryPutamenBrainHuman brainMiddle Agedmedicine.diseaseDihydroxyphenylalanineEndocrinologymedicine.anatomical_structureNeurologychemistryPositron emission tomographyPositron-Emission TomographyNeurology (clinical)Cardiology and Cardiovascular MedicineNuclear medicinebusinessmedicine.drugJournal of Cerebral Blood Flow & Metabolism
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Potential clinical value of quantitative fluorine-18-fluorodeoxyglucose-PET/computed tomography using a graph-based method analysis in evaluation of …

2019

Objectives To identify the clinical relevance of incidentally detected lesions (IDLs) in the gastrointestinal tract (GIT) with 18F-FDG PET/CT and to assess the potential benefit of using semiquantitative PET measures to discern malignant from benign lesions. Methods Forty-one patients who underwent F-FDG PET/CT scans during the oncologic follow-up, revealing abnormal incidental 18F-FDG accumulations in the GIT were included in this retrospective analysis. Incidental PET/CT findings were correlated with endoscopic and histological findings. Semiquantitative PET values (SUVmax, SUVmean, SULpeak, and TLG) were evaluated by using a new graph-based method. Two sample t-test analysis has been per…

AdultMale-Endoscopy Gastrointestinal030218 nuclear medicine & medical imagingCorrelation03 medical and health sciences0302 clinical medicineFluorodeoxyglucose F18Positron Emission Tomography Computed TomographyBiopsymedicineImage Processing Computer-AssistedHumansRadiology Nuclear Medicine and imagingClinical significanceGastrointestinal NeoplasmsRetrospective StudiesGastrointestinal tractIncidental FindingsFluorine-18-fluorodeoxyglucosemedicine.diagnostic_testbusiness.industryRetrospective cohort studyGeneral Medicinemedicine.diseaseEndoscopyTumor BurdenDysplasia030220 oncology & carcinogenesisFemalebusinessNuclear medicineGlycolysisNuclear medicine communications
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Dopamine in amygdala gates limbic processing of aversive stimuli in humans

2008

Dopamine is known to contribute to the amygdala-mediated aversive response, where increased dopamine release can augment amygdala function. Combining fMRI and PET imaging techniques, Kienast et al. present findings that suggest a functional link between anxiety temperament, dopamine storage capacity and emotional processing in the amygdala. Dopamine is released under stress and modulates processing of aversive stimuli. We found that dopamine storage capacity in human amygdala, measured with 6-[18F]fluoro-L-DOPA positron emission tomography, was positively correlated with functional magnetic resonance imaging blood oxygen level–dependent signal changes in amygdala and dorsal anterior cingula…

AdultMaleFluorine RadioisotopesDopamineBrain mappingAmygdalaGyrus CinguliDopaminemedicineImage Processing Computer-AssistedLimbic SystemPsychophysicsHumansAnterior cingulate cortexSystems neuroscienceBrain Mappingmedicine.diagnostic_testGeneral NeuroscienceMiddle AgedAmygdalaMagnetic Resonance ImagingDihydroxyphenylalanineFunctional imagingOxygenAffectmedicine.anatomical_structurenervous systemPositron-Emission TomographyAversive StimulusFunctional magnetic resonance imagingPsychologyNeurosciencepsychological phenomena and processesmedicine.drug
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No evidence for attenuated stress-induced extrastriatal dopamine signaling in psychotic disorder

2015

AbstractStress is an important risk factor in the etiology of psychotic disorder. Preclinical work has shown that stress primarily increases dopamine (DA) transmission in the frontal cortex. Given that DA-mediated hypofrontality is hypothesized to be a cardinal feature of psychotic disorder, stress-related extrastriatal DA release may be altered in psychotic disorder. Here we quantified for the first time stress-induced extrastriatal DA release and the spatial extent of extrastriatal DA release in individuals with non-affective psychotic disorder (NAPD). Twelve healthy volunteers (HV) and 12 matched drug-free NAPD patients underwent a single infusion [18F]fallypride positron emission tomogr…

AdultMaleFluorine RadioisotopesDopaminePrefrontal CortexHypofrontalityStressSynaptic TransmissionTemporal lobeCellular and Molecular Neuroscienceddc:150DopamineRadioligandmedicineHumansPrefrontal cortexBiological PsychiatryTemporal cortexPositive and Negative Syndrome ScaleBrainMiddle AgedTemporal Lobe3. Good healthNeostriatumPsychiatry and Mental healthFallypridePsychotic DisordersCase-Control StudiesPositron-Emission TomographyBenzamidesPsychologicalFemaleOriginal ArticlePsychologyNeuroscienceStress Psychologicalmedicine.drug
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Net influx of plasma 6-[18F]fluoro-L-DOPA (FDOPA) to the ventral striatum correlates with prefrontal processing of affective stimuli.

2006

Dopaminergic neurotransmission in the ventral and dorsal striatum interact with central processing of rewarding and reward-indicating stimuli, and may affect frontocortical-striatal-thalamic circuits regulating goal-directed behaviour. Thirteen healthy male volunteers were investigated with multimodal imaging, using the radioligand 6-[ 18 F]fluoro-L-DOPA (FDOPA) for positron emission tomography (PET) measurements of dopamine synthesis capacity, and also functional magnetic resonance imaging (fMRI) in a cognitive activation paradigm. We calculated the correlation between FDOPA net blood-brain influx (K app in ; ml/g/min) in the ventral and associative dorsal striatum and BOLD signal changes …

AdultMaleFluorine RadioisotopesDopaminePrefrontal CortexStriatumNucleus accumbensSynaptic TransmissionReward systemmedicineHumansOperculum (brain)Anterior cingulate cortexmedicine.diagnostic_testGeneral NeuroscienceVentral striatumPutamenMiddle AgedMagnetic Resonance ImagingCorpus StriatumDihydroxyphenylalanineDorsolateral prefrontal cortexAffectmedicine.anatomical_structurenervous systemPositron-Emission TomographyCaudate NucleusRadiopharmaceuticalsFunctional magnetic resonance imagingPsychologyNeurosciencepsychological phenomena and processesPhotic StimulationThe European journal of neuroscience
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Echogenicity of the substantia nigra in relatives of patients with sporadic Parkinson’s disease

2003

Increased echogenicity of the substantia nigra (SN) on ultrasound is a typical sonographic finding in Parkinson's disease (PD). Sonographic signal intensity of the SN is related to tissue iron content with higher iron level being associated with increased echogenicity. Recent findings indicate that hyperechogenicity of the SN represents an important susceptibility factor for nigrostriatal degeneration. In this study we determined the prevalence of a characteristic ultrasound sign of Parkinson's disease in first-degree relatives of PD patients. Fourteen patients with sporadic PD and 58 of their relatives underwent neurological, neuropsychological, and ultrasound examination. In addition, fou…

AdultMaleFluorine RadioisotopesPathologymedicine.medical_specialtyParkinson's diseaseUltrasonography Doppler TranscranialCognitive NeuroscienceSubstantia nigraNeuropsychological TestsHypokinesiamedicineHumansGenetic Predisposition to DiseaseGenetic TestingDominance CerebralProblem SolvingDominance (genetics)business.industryPutamenUltrasoundEchogenicityParkinson DiseaseMiddle Agedmedicine.diseaseDihydroxyphenylalanineTranscranial DopplerSubstantia NigraNeurologyNerve DegenerationFemalemedicine.symptomPsychologybusinessTomography Emission-ComputedNeuroImage
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