Search results for "fluoroquinolones"

showing 4 items of 44 documents

Synthesis, structure, and nuclease properties of several binary and ternary complexes of copper(II) with norfloxacin and 1,10 phenantroline

2007

Three new binary Cu(II) complexes of norfloxacin have been synthesized and characterized. We also report the synthesis, characterization and X-ray crystallographic structures of a new binary compound, [Cu(HNor)(2)]Cl(2).2H(2)O (2) and two new ternary complexes norfloxacin-copper(II)-phen, [Cu(Nor)(phen)(H(2)O)](NO(3)).3H(2)O (4), and [Cu(HNor)(phen)(NO(3))](NO(3)).3H(2)O (5). The structure of 2 consists of two crystallographically independent cationic monomeric units of [Cu(HNor)(2)](2+), chloride anions, and uncoordinated water molecules. The Cu(II) ion is placed at a center of symmetry and is coordinated to two norfloxacin ligands which are related through the inversion center. The struct…

StereochemistryRadicalBinary compoundCrystallography X-RayBiochemistryInorganic ChemistryMetalchemistry.chemical_compoundTandem Mass SpectrometrySpectroscopy Fourier Transform InfraredOrganometallic CompoundsMoleculeDeoxyribonucleasesMolecular StructureCationic polymerizationSquare pyramidal molecular geometryCrystallographyMonomerchemistryvisual_artvisual_art.visual_art_mediumSpectrophotometry UltravioletTernary operationCopperFluoroquinolonesNorfloxacinPhenanthrolinesJournal of Inorganic Biochemistry
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Fluoroquinolone–metal complexes: A route to counteract bacterial resistance?

2014

Abstract Microbial resistance to antibiotics is one of the biggest public health threats of the modern world. Antibiotic resistance is an area of much clinical relevance and therefore research that has the potential to identify agents that may circumvent it or treat resistant infections is paramount. Solution behavior of various fluoroquinolone (FQ) complexes with copper(II) in the presence and absence of 1,10-phenanthroline (phen) was studied in aqueous solution, by potentiometry and/or spectrophotometry, and are herein described. The results obtained showed that under physiological conditions (micromolar concentration range and pH 7.4) only copper(II):FQ:phen ternary complexes are stable.…

Stereochemistrychemistry.chemical_elementInfrared spectroscopyMicrobial Sensitivity TestsCrystallography X-RayBiochemistryInorganic ChemistryMetalMinimum inhibitory concentrationCoordination ComplexesSpectrophotometryDrug Resistance BacterialEscherichia colimedicineMoleculeAqueous solutionmedicine.diagnostic_testChemistryCombinatorial chemistryCoppervisual_artvisual_art.visual_art_mediumTernary operationCopperFluoroquinolonesPhenanthrolinesJournal of Inorganic Biochemistry
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Multiple Resistance to Betalactam Antibiotics, Azithromycin or Moxifloxacin in Implant Associated Bacteria

2013

Background Antibiotics are more and more frequently prescribed in dentistry for prevention and treatment of oral diseases. Bacterial resistance to these agents is clearly increasing, including even previously susceptible micro-organisms and true pathogens. The aim of the present investigation was to examine resistant bacterial strains with respect to possible multiple antibiotic resistance. Methods In a previous investigation, implant-associated bacteria were tested first as mixed cultures and again as pure isolates (n = 138) for resistance to one of five antibiotics (ampicillin/AM, ampicillin + sulbactam/AB, azithromycin/AZ, penicillin/PG, moxifloxacin/MX) using the Etest. The resistance o…

medicine.drug_classMoxifloxacinAntibioticsMicrobial Sensitivity TestsDrug resistanceAzithromycinbeta-LactamsGeneral Biochemistry Genetics and Molecular BiologyMicrobiologyAntibiotic resistanceMoxifloxacinAmpicillinmedicineHumansEtestDental ImplantsAza CompoundsBacteriabusiness.industryDrug Resistance MicrobialSulbactamDrug Resistance MultiplePenicillinQuinolinesbusinessFluoroquinolonesmedicine.drugClinical Laboratory
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Anti- Toxoplasma Activities of 24 Quinolones and Fluoroquinolones In Vitro: Prediction of Activity by Molecular Topology and Virtual Computational Te…

2000

ABSTRACT The apicoplast, a plastid-like organelle of Toxoplasma gondii , is thought to be a unique drug target for quinolones. In this study, we assessed the in vitro activity of quinolones against T. gondii and developed new quantitative structure-activity relationship models able to predict this activity. The anti- Toxoplasma activities of 24 quinolones were examined by means of linear discriminant analysis (LDA) using topological indices as structural descriptors. In parallel, in vitro 50% inhibitory concentrations (IC 50 s) were determined in tissue culture. A multilinear regression (MLR) analysis was then performed to establish a model capable of classifying quinolones by in vitro acti…

medicine.drug_classStereochemistryMolecular ConformationBiologyModels BiologicalStructure-Activity RelationshipAnti-Infective AgentsPredictive Value of TestsMoxifloxacinparasitic diseasesmedicineAnimalsStructure–activity relationshipComputer SimulationPharmacology (medical)Mechanisms of Action: Physiological EffectsAntibacterial agentPharmacology4-QuinolonesBiological activityQuinoloneGatifloxacinGrepafloxacinTrovafloxacinInfectious DiseasesRegression AnalysisToxoplasmaFluoroquinolonesmedicine.drugAntimicrobial Agents and Chemotherapy
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