Search results for "force"
showing 10 items of 3423 documents
Vivir como cristianos y pagar como moros: genealogía medieval de la servidumbre morisca en el reino de Valencia
2009
La conversión forzosa de los musulmanes del reino de Valencia, decretada en 1526, no implicó una igualación social entre cristianos «viejos» y «nuevos», ya que se mantuvo la diferencia de estatus que había existido anteriormente. El artículo examina los tres aspectos fundamentales del contenido de dicha diferencia: la intensidad de las rentas soportadas, la imposición de servicios obligatorios y las trabas a la migración interior y exterior; establece sus orígenes en las condiciones de dominación impuestas a la población infiel inmediatamente después de la conquista del siglo XIII, y traza los grandes rasgos de su evolución a lo largo de la Baja Edad Media. Se arguye que esta población estu…
New force field for GCMC simulations of D 2 /H 2 quantum sieving in pure silica zeolites
2020
International audience; We report a study on adsorption and coadsorption of H2 and D2 in FAU, MFI and CHA pure silica zeolites having different pore sizes and shapes. Adsorption capacities, selectivities, enthalpies and entropies are determined by combining experiments and GCMC simulations. We show that the force fields available in the literature cannot predict the adsorption equilibria below 77 K with sufficient accuracy. Here we propose a new force field adjusted by using our experimental data obtained for the pure silica MFI zeolite at 65 K and 77 K. With this new force field, it is possible to predict the adsorption and coadsorption equilibria on the three zeolite structures in a tempe…
Polystyrene Sulfonate–Porphyrin Assemblies: Influence of Polyelectrolyte and Porphyrin Structure
2011
In this study, electrostatic self-assembly of different polystyrene sulfonates and a set of tetravalent cationic porphyrins is investigated. It is shown that association of linear polystyrene sulfonates of different molar masses yields finite size nanoscale assemblies that are stable in aqueous solution. Aggregates are compared to the ones of cylindrical brushes, revealing that both form assemblies in the 100 nm range with the charge ratio (molar ratio of porphyrin charges to polyelectrolyte charges) being determining, while the morphology of the resulting network-like assemblies is different for both polyelectrolyte architectures. For the smallest 8k polystyrene sulfonate, in addition, sto…
Faktori, kas ietekmē Latvijas piena nozares konkurētspēju Baltijas valstīs
2019
This study presents competitiveness analysis and factors influencing on the competitiveness in Latvian dairy sector among the Baltic states. Gross domestic product, the number of population, demographics, trade balance, labour cost indicators of each country and numbers of manufacturers, the revenue of the sector and its growth rate, volume sold of goods and its growth rate, average volume sold per capita of products, an average price of milk and cream, an average price of yoghurt and curdled milk, an average price of cream cheese and cheese in the dairy sector of every Baltic state are compared between among them and has been commented by three experts: Inga Orlova ( representative of Mini…
Zadania sądu egzekucyjnego w postępowaniu cywilnym - właściwość funkcjonalna
2021
Właściwość funkcjonalna w postępowaniu egzekucyjnym wyznacza zakres kompetencji pełnionych przez sąd egzekucyjny, referendarza oraz komornika. Czynności egzekucyjne są wykonywane przez komorników z wyjątkiem czynności zastrzeżonych dla sądów. W ostatnim czasie dochodzi do przekazywania kompetencji sądu egzekucyjnego na rzecz referendarza sądowego. Opracowanie prezentuje zakres uprawnień sądu i referendarza w postępowaniu egzekucyjnym
Rovibrational structure of the Ar–CO complex based on a novel three-dimensional ab initio potential
2002
The first three-dimensional ab initio intermolecular potential energy surface of the Ar–CO van der Waals complex is calculated using the coupled cluster singles and doubles including connected triples model and the augmented correlation-consistent polarized valence quadruple zeta (aug-cc-pVQZ) basis set extended with a (3s3p2d1f1g) set of midbond functions. The three-dimensional surface is averaged over the three lowest vibrational states of CO. Rovibrational energies are calculated up to 50 cm−1 above the ground state, thus enabling comprehensive comparison between theory and available experimental data as well as providing detailed guidance for future spectroscopic investigations of highe…
Study of the benzene⋅N2 intermolecular potential-energy surface
2003
The intermolecular potential-energy surface pertaining to the interaction between benzene and N2 is investigated theoretically and experimentally. Accurate intermolecular interaction energies are evaluated for the benzene–N2 van der Waals complex using the coupled cluster singles and doubles including connected triples [CCSD(T)] method and the aug-cc-pVDZ basis set extended with a set of 3s3p2d1f1g midbond functions. After fitting the energies to an analytic function, the intermolecular Schrödinger equation is solved to yield energies, rotational constants, and Raman-scattering coefficients for the lowest intermolecular levels of several benzene–N2 isotopomers. Experimentally, intermolecula…
Computational and experimental investigation of intermolecular states and forces in the benzene-helium van der Waals complex
2003
A study of the intermolecular potential-energy surface (IPS) and the intermolecular states of the perprotonated and perdeuterated benzene–He complex is reported. From a fit to ab initio data computed within the coupled cluster singles and doubles including connected triples model for 280 interaction geometries, an analytic IPS including two- to four-body atom–atom terms is obtained. This IPS, and two other Lennard-Jones atom–atom surfaces from the literature, are each employed in dynamically exact (within the rigid-monomer approximation) calculations of J = 0 intermolecular states of the isotopomers. Rotational constants and Raman-scattering coefficients for intermolecular vibrational trans…
À l’ombre des épées. Les seigneurs de la guerre, gardiens de la Constitution et pouvoirs régulateurs dans l’imaginaire constitutionnel haïtien
2022
Due to a militarised society between 1804 and 1915, the weight of the warlords was heavy in the foundation and maintenance of the Haitian constitutional order. Their mission as guardians is apparent since the Constitution of 1801, and the military was not content to monopolise the supreme magistracy until the US occupation in 1915. Institutional practice, however, leaves much to be desired. The military Senate was defined by President Jean-Pierre Boyer as the moderating power of the institutions between 1839 and 1842, a short-lived attempt to normalise the institutions in the hands of generals at rest. Unfortunately, the political and social climate accompanying the disintegration of the st…
The implicit in "In search of lost ime" : study on an aspect of proustien speech
2013
The implicit is defined as content present in speech without being formally expressed. Presupposition and implied content are the two fundamental elements of this concept. They act as information implied in speech whose essence the speaker can grasp or decrypt using the theories of pragmatics and enunciative linguistics. Proustian speech constitutes a remarkable example of the use of the implicit and its concepts. The present work is entirely devoted to the search for the implicit in Proust’s In Search of Lost Time. In our work, the development of this concept emerges especially in the verbal interaction between Proust's characters, also, through the speech of the narrator who opts for a ne…