Search results for "force"
showing 10 items of 3423 documents
Synthetic studies on the preparation of oxygenated spongiane diterpenes from carvone
2003
Abstract The paper describes a new diastereoselective approach to oxygenated spongiane diterpenes functionally related to natural dorisenones. The strategy followed for the preparation of the spongiane framework, a B→AB→ABC→ABCD approach, is based on the preparation of epoxydecalone 11 (AB rings) from R-(−)-carvone, followed by an intramolecular Diels–Alder reaction for the construction of the C ring (compound 26 ). Further manipulation of the Diels–Alder adduct functionality allows the completion of the spongiane framework and the elaboration of several oxygenated spongiane-type compounds. The structures of two compounds 27 and 31 , has been established by single-crystal X-ray crystallogra…
ChemInform Abstract: Synthesis of Elemane Bis-lactones from Santonin - Synthesis of the Reported Structure of seco-Isoerivanin Pseudo Acid and Formal…
2001
The synthesis of the reported structure for seco-isoerivanin pseudo acid (1) and of an elemane bis-lactone 5 from santonin (4) through a common vinylic precursor 12 is described. Compound 5 is a known intermediate in a previous synthesis of the antitumor compound (+)-8-deoxyvernolepin (3). The vinyl group of 12 underwent a regio- and diastereoselective anti addition of an external electrophile and an intramolecular condensation to yield either the selenolactone 13 or the hydroxylactone 17. The lactones 13 and 17 served as key intermediates in the total synthesis of 1 and 5 respectively. A revision of the structure of seco-isoerivanin pseudo acid to the C-10 epimer is suggested on the basis …
A normative ‘due process’ in the creation of States through secession
2006
The choice and/or the balancing between effectivess and legality in the creation of States is, today, one of the most hotly debated issues in the international legal scholarship. Should a state-like entity formed in breach of the peremptory norm prohibiting the use of force or of the principle of self-determination (not) be considered as a State for the purposes of international law? The answer differs according to what theoretical premises are adopted. For those who believe that the State is a social person, and its creation basically a historical occurrence, the law cannot cancel its very existence. On the other hand, if State-creation is also a matter of law, one might agree that “[a]n a…
4-Chloro-N-methyl-N-nitroaniline
1998
The molecular structure of (p-ClC 6 H 4 )(CH 3 )NNO 2 (or C 7 H 7 ClN 2 O 2 ) contains a planar NNO 2 nitroamino group which is twisted about the N-C phenyl bond by ca 68° from the plane of the aromatic ring. The structural data are in agreement with the spectral results and indicate that there is no conjugation between the aromatic sextet and the nitroamino group. There are no specific intermolecular interactions.
A novel correction method for a low cost sensorless control system of IPMSM electrical drives
2008
In this paper a novel correction method for sensorless Field Oriented Control System of Brushless internal Permanent Magnet Electrical Drives is introduced discussed and experimentally validated. The novelty of this control system is the estimation of rotor speed and angular position is based on the back electromotive force space vector determination, without the aid of voltage probes. Actual voltage signals needed for estimation are replaced with the reference ones given by the current controller. This choice obviously introduces an error that have been vanished by means of a new compensating function or with the aid of data coming from experimental tests. Experimental verifications of the…
El viaje desde los cuestionarios Likert a los cuestionarios de elección forzosa: evidencia de la invarianza de los parámetros de los ítems
2019
ABSTRACT Multidimensional forced-choice questionnaires are widely regarded in the personnel selection literature for their ability to control response biases. Recently developed IRT models usually rely on the assumption that item parameters remain invariant when they are paired in forced-choice blocks, without giving it much consideration. This study aims to test this assumption empirically on the MUPP-2PL model, comparing the parameter estimates of the forced-choice format to their graded-scale equivalent on a Big Five personality instrument. The assumption was found to hold reasonably well, especially for the discrimination parameters. In the cases in which it was violated, we briefly dis…
On the use of ionic liquids as mobile phase additives in high-performance liquid chromatography. A review.
2015
The popularity of ionic liquids (ILs) has grown during the last decades in several analytical separation techniques. Consequently, the number of reports devoted to the applications of ILs is still increasing. This review is focused on the use of ILs (mainly imidazolium-based associated to chloride and tetrafluoroborate) as mobile phase additives in high-performance liquid chromatography (HPLC). In this approach, ILs just function as salts, but keep several kinds of intermolecular interactions, which are useful for chromatographic separations. Both cation and anion can be adsorbed on the stationary phase, creating a bilayer. This gives rise to hydrophobic, electrostatic and other specific in…
Novel method for functionalising and patterning textile composites:Liquid resin print
2016
Abstract The paper reports a novel method of integrating resin into continuous textile reinforcement. The method presents a print of liquid reactive resin into textile preforms. A series of targeted injections forms a patch which upon consolidation and curing transforms into a stiff region continuously spanning through preform thickness. Enhancing the injected resin with conductive phase allows creating a pattern of patches with controlled dimensions and added functionalities. Patterned composites reveal features which are not typical for conventional composites such as fibre bridged interfaces, regular thickness variation, and gradient matrix properties. The presented study explores the ro…
Experimental Studies Regarding Mechanical Behaviour of Textile Reinforcements Laminated Composite Materials
2013
The aim of this paper is to determine the mechanical properties of textile reinforcements laminated composite material and to establish the influence of thickness about these properties. The composite material used for this is a laminated sheet of HGW 2082. In order to study the mechanical behaviour of these kinds of materials we select two experimental tests: uniaxial test and bending test. For the uniaxial test we have measured the maximum load, the maximum extension, the maximum tensile stress and the maximum tensile strain. Also, using an optical extensometer we measured the major and the minor strains. For the bending test we measured the maximum load and the maximum bending deflection…
Real Bando, en que se pone tasa a las ropas de lana, y otras de que pueden vsar los cabos, oficiales, y soldados en la Reseña General, que se dispon…
1681
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