Search results for "force"
showing 10 items of 3423 documents
Contratti a valle rimedi civilistici e disciplina della concorrenza
2008
L'entrata in vigore del c.d. regolamento di modernizzazione dell'antitrust europeo (Reg. 1/2003) ha determinato il delinearsi di un sistema misto di enforcement del diritto europeo della concorrenza, ove al tradizionale meccanismo pubblicistico se ne affianca anche uno privatistico. Il volume mette in evidenza le criticità che siffatto impianto di enforcement presenta, tanto dal punto di vista della coerenza complessiva del modello europeo di diritto della concorrenza, quanto dal punto di vista della versatilità dei rimedi del diritto privato ad assolvere ad una qualche funzione di contrasto delle violazioni concorrenziali. Particolare attenzione, entro questa cornice, è dedicata al tema de…
Conformational investigation of α,β‐dehydropeptides Part VI. Molecular and crystal structure of benzyloxycarbonylglycyl‐(Z )‐dehydrophenylalanine
1994
The structure of a peptide containing C-terminal dehydrophenylalanine, Z-Gly-(Z)-delta Phe (C19H18N2O5, MW = 354) was determined from single-crystal X-ray diffraction data. Needle-shaped crystals were grown from a 1:1 mixture of methanol-acetone in the monoclinic space group P2(1) with a = 14.717(4), b = 4.941(2), c = 12.073(4) A, beta = 103.72(4) degrees; V = 852.86(8) A3, Z = 2 and Dc = 1.32 g cm-3. The structure was solved by direct methods using SHELXS-86 and refined to a final R-index of 0.032 for 1714 observed reflections. The peptide adopts a conformation folded at the glycine residue, and principal torsion angles are omega 0 = -167.6(2) degrees, phi 1 = -71.8(3) degrees, psi 1 = -31…
tutela della concorrenza e professione forense
2015
lo studio approfondisce le problematiche sollevate dall'esercizio del professione forense nel mercato della concorrenza.
Cupole in cemento armato in Sicilia occidentale nella prima metà del Novecento
2014
The paper intends to examine through three case studies the change introduced by the technology of reinforced concrete in the construction of domes. After a brief description of the geometric and architectural characteristics of reinforced concrete domes, the study focuses on three interventions, for which a considerable archival documentation was collected. Chronologically the first intervention is related to the construction of the dome of the mother-church of Bisacquino (1923-25), built on the basis of the architectural project and under the direction of the engineer Pietro Scibilia. The second concerns the reconstruction of the dome of Sant’Ignazio martire all'Olivella church in Palermo…
Reactivity of bis(cyclohexylammonium) 4-nitrophenylphosphate with SnMe3 Cl. X-ray structure of 4-NO2 C6 H4 PO4(SnMe3)2·H2 O
2014
The reaction of bis(cyclohexylammonium) 4-nitrophenylphosphate with Me3 SnCl (1:2) under reflux in ethanol yielded the title compound 4-NO2 C6 H4 PO4(SnMe3)2H2 O (1). The X-ray crystallographic analysis achieved on single crystals obtained by slow evaporation at room temperature revealed the formation of an unexpected supramolecular coordination network. The elementary building block can be viewed as two Me3 Sn moieties linked by a bridging 4-nitrophenylphosphate ligand. The two tin atoms are five-coordinated and describe a trans-Me3 SnO2 geometry in a trigonal bipyramidal arrangement. However, the Sn atoms are distinct, exhibiting two different environments. Thus, one is linked to two axia…
Assessment and strengthening of reinforced concrete bridges with half-joint deterioration
2022
Existing Niagara-type concrete cantilever bridges, which in Italy are called Gerber bridges, suffer from degradation due to reinforcement corrosion and a consequent reduced load-bearing capacity. The assessment of these structures is therefore an important part of the procedures for analyzing the state of existing bridges and any interventions required for their retrofitting. In particular, safety against failure of the half-joint must be evaluated with respect to the behavior of the entire bridge and its state of conservation, determining what the conditions are that lead to failure, in terms of loads, state of stress, and possibly cracking state. This evaluation has to be carried out cons…
3,5-Dimethoxyphenyl 4-methylbenzenesulfonate
2017
Molecules of the title compound, C15H16O5S, are composed of a 3,5-dimethoxyphenyl moiety substituted with a toluene-4-sulfonate group. The dihedral angle between two aromatic rings is 57.23 (4)°. In the crystal, molecules are connected by weak C—H...O hydrogen bonds and S...O van der Waals interactions.
Crystal structure of 1-(2-fluorobenzoyl)-2,7-dimethoxynaphthalene
2014
The asymmetric unit of the compound contains two independent conformers. Each conformer is stacked along the a axis to form columns through van der Waals interactions only.
Influences of Chemical Functionalities on Crystal Structures and Electrochemical Properties of Dihydro-benzoxazine Dimer Derivatives
2021
Dihydro-1,3,2H-benzoxazine dimer derivatives or dihydro-benzoxazine dimers are a class of compounds typically prepared by ring-opening reactions between dihydro-benzoxazines and phenols. Dihydro-benzoxazine dimers act as chelating agents for several transition and rare-earth cations. To better understand the chelating properties, it is necessary to examine their structural features and electrochemical characteristics thoroughly. However, the electrochemical properties of dihydro-benzoxazine dimers have not been tremendously examined. Herein, eight derivatives of dihydro-benzoxazine dimers possessing different substituents on the benzene ring and the tertiary-amine nitrogen were synthesized …
Bis(4,6-di-tert-butyl-2-{N-[4-(diethylamino)phenyl]carboximidoyl}phenolato)cobalt(II)
2017
In the title complex, [Co(C25H35N2O)2], the cobalt(II) atom has a distorted tetrahedral geometry provided by pairs of O and N atoms. The dihedral angles between the benzene rings of the same ligand are 52.39 (9) and 34.96 (9)°. The molecular structure is stabilized by weak intramolecular C—H...O hydrogen bonds. The crystal packing is stabilized mainly by van der Waals forces. The structure contains a solvent-accessible void of 276 Å3which was treated using the SQUEEZE routine fromPLATON[Spek (2015).Acta Cryst.C71, 9–18]. The methyl C atoms of thetert-butyl groups are rotationally disordered, with site occupancies of 0.802 (3) and 0.548 (9) for the major components and 0.198 (3) and 0.452 (9…