Search results for "fuel"

Origin of the Enhanced Photoluminescence Quantum Yield in MAPbBr 3 Perovskite with Reduced Crystal Size

2018

Methylammonium lead bromide perovskite (MAPbBr3) has been widely investigated for applications in visible perovskite light-emitting diodes (LEDs). Fine-tuning of the morphology and of the crystal size, from the microscale down to the quantum confinement regime, has been used to increase the photoluminescence quantum yield (PLQY). However, the physical processes underlying the PL emission of this perovskite remain unclear. Here, we elucidate the origin of the PL emission of polycrystalline MAPbBr3 thin films by different spectroscopic techniques. We estimate the exciton binding energy, the reduced exciton effective mass, and the trap density. Moreover, we confirm the coexistence of free carr…

Controlling the Phase Segregation in Mixed Halide Perovskites through Nanocrystal Size

2019

Mixed halide perovskites are one of the promising candidates in developing solar cells and light-emitting diodes (LEDs), among other applications, because of their tunable optical properties. Nonetheless, photoinduced phase segregation, by formation of segregated Br-rich and I-rich domains, limits the overall applicability. We tracked the phase segregation with increasing crystalline size of CsPbBr3–xIx and their photoluminescence under continuous-wave laser irradiation (405 nm, 10 mW cm–2) and observed the occurrence of the phase segregation from the threshold size of 46 ± 7 nm. These results have an outstanding agreement with the diffusion length (45.8 nm) calculated also experimentally f…

Shedding light on biogas: Phototrophic biofilms in anaerobic digesters hold potential for improved biogas production

2019

Conventional anaerobic digesters intended for the production of biogas usually operate in complete darkness. Therefore, little is known about the effect of light on their microbial communities. In the present work, 16S rRNA gene amplicon Nanopore sequencing and shotgun metagenomic sequencing were used to study the taxonomic and functional structure of the microbial community forming a biofilm on the inner wall of a laboratory-scale transparent anaerobic biodigester illuminated with natural sunlight. The biofilm was composed of microorganisms involved in the four metabolic processes needed for biogas production, and it was surprisingly rich in Rhodopseudomonas faecalis, a versatile bacterium…

Radiative neutron capture on Pu242 in the resonance region at the CERN n_TOF-EAR1 facility

2018

The spent fuel of current nuclear reactors contains fissile plutonium isotopes that can be combined with uranium to make mixed oxide (MOX) fuel. In this way the Pu from spent fuel is used in a new reactor cycle, contributing to the long-term sustainability of nuclear energy. However, an extensive use of MOX fuels, in particular in fast reactors, requires more accurate capture and fission cross sections for some Pu isotopes. In the case of Pu242 there are sizable discrepancies among the existing capture cross-section measurements included in the evaluations (all from the 1970s) resulting in an uncertainty as high as 35% in the fast energy region. Moreover, postirradiation experiments evaluat…

Design of a neutron converter for fission studies at the IGISOL facility

2012

The upgraded IGISOL facility with JYFLTRAP, at the accelerator laboratory of the University of Jyvaskyla, has been supplied with a new cyclotron which will provide proton or deuteron beams of the order of 100 μA with up to 30 MeV energy. This makes it an ideal place for measurements of neutron-induced fission fragments from various actinides, in view of proposed future nuclear fuel cycles. In the present paper, some considerations for the design of a neutron converter, based on simulations with the Monte Carlo codes MCNPX and FLUKA, are described.

Inappropriate evaluation of methodology and biases by P. Morfeld and T.C. Erren.

2020

Identification of indigoid compounds present in archaeological Maya blue by pyrolysis-silylation-gas chromatography–mass spectrometry

2014

Abstract A study based on the use of pyrolysis-silylation-gas chromatograpy–mass spectrometry (Py-GC–MS), which aimed to identify indigoid compounds and to clarify the multicomponent composition of Maya blue (MB) pigment, has been carried out. A series of reference compounds and synthetic MB specimens prepared in the laboratory have been analysed by this technique. An analysis of archaeological MB samples from 14 Maya archaeological sites from Mexico and Guatemala has also been performed. The obtained results demonstrate that, in addition to indigo, oxidised species such as dehydroindigo, which is formed as a result of redox processes taking place while preparing the pigment, are present in…

The structure of western Sicily, central Mediterranean

2002

Western Sicily is part of the Sicilian chain, a sector of the SE-verging Alpine orogenic belt in the central Mediterranean. Interpretation of seismic reflection profiles, boreholes and recent inland geological data, have enabled us to assess the deep structural grain. A wedge of flat-lying Mesozoic–Miocene carbonate and terrigenous rocks (pre-Panormide nappes) is superimposed on NW-trending, 7–8 km thick, Mesozoic–Paleogene carbonate thrust ramps (Trapanese units), arranged in two structural levels extending from the Tyrrhenian coast to western offshore Sicily. Upper Miocene to Pleistocene terrigenous strata, often deformed, fill syntectonic basins above the thrust pile. The main tectonic t…

Microalgal oil production for use in rice farms in Albufera (València) region

2013

In the Albufera (Valencia) region of Spain, rice has been farmed for nearly 500 years. Post-harvest flooding of rice fields has become an integral element of wetland refuge for migratory birds. The steady rise in the cost of purchased inputs is causing considerable economic stress to the viability of rice farming in this region. In 2011, it has been estimated the cost of purchased diesel accounted for about 15% of the gross revenue from grain sales. Setting aside about 1.6% of the 14,350-hectare paddy fields for the dedicated yearround cultivation of oleaginous microalgae appears to be sufficient for the entire annual need of diesel fuel. The isolated crude microalgal oil could be used dire…

Removal of ethyl acetate, n-hexane and toluene from waste air in a membrane bioreactor under continuous and intermittent feeding conditions

2012

BACKGROUND: European Union environmental policy has focused on abatement of volatile organic compounds (VOCs) from industrial emissions, and new European VOC emission limits have been established. This study analyzes the performance of a composite membrane bioreactor treating air stream contaminated with ethyl acetate, n-hexane and toluene under continuous and intermittent feeding conditions. RESULTS: The system was operated under continuous feeding conditions: removal efficiencies (REs) higher than 99% were obtained for inlet loads up to 200 g m−3 h−1 and empty bed residence times (EBRTs) as short as 15 s for ethyl acetate. A maximum elimination capacity of 75 g m−3 h−1 (RE ∼66%) at an EBR…