Search results for "fuel"
showing 10 items of 986 documents
Insights into the catalytic production of hydrogen from propane in the presence of oxygen: Cooperative presence of vanadium and gold catalysts
2015
7 figures.-- © 2015. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
Performance of Sulfonated Poly(Vinyl Alcohol)/Graphene Oxide Polyelectrolytes for Direct Methanol Fuel Cells
2020
The use of nanotechnology along with the consideration of a functionalization and stabilization approach to poly(vinyl alcohol) (PVA) is considered useful for the preparation of cost-effective polyelectrolyte membranes. A set of nanocomposite and crosslinked membranes based on PVA/sulfosuccinic acid (SSA)/graphene oxide (GO) are prepared and analyzed as polyelectrolytes in direct methanol fuel cells (DMFCs). The crosslinking and sulfonation by the use of SSA enhances the stability and increase the proton-conducting sites in the PVA structure. The presence of GO augments the stability, remarkably decreases the methanol crossover, and enhances power density curves. An optimum value for proton…
Crosslinked chitosan/poly(vinyl alcohol)-based polyelectrolytes for proton exchange membranes
2019
[EN] The preparation polyelectrolytes based on crosslinked poly(vinyl alcohol) (PVA) and chitosan (CS) was considered as a feasible alternative to develop highly functionalised, cost-effective and eco-friendly membranes for proton exchange fuel cell technologies. CS/PVA-based membranes were combined with sulfosuccinic acid (SSA) as crosslinking and sulfonating agent, and glycerol (GL) to promote flexibility and favour their manageability. The chemical structure, the thermo-oxidative behaviour, the ethanol uptake, the electric, the proton conductivity, and the performance in direct ethanol fuel cell (DEFC) were assessed. In general, all the CS/PVA-based polyelectrolytes showed a synergetic i…
Functionalised poly (vinyl alcohol)/graphene oxide as polymer composite electrolyte membranes
2019
[EN] Crosslinked poly(vinyl alcohol) (PVA) based composite films were prepared as polyelectrolyte membranes for low temperature direct ethanol fuel cells (DEFC). The membranes were functionalised by means of the addition of graphene oxide (GO) and sulfonated graphene oxide (SGO) and crosslinked with sulfosuccinic acid (SSA). The chemical structure was corroborated and suitable thermal properties were found. Although the addition of GO and SGO slightly decreased the proton conductivity of the membranes, a significant reduction of the ethanol solution swelling and crossover was encountered, more relevant for those functionalised with SGO. In general, the composite membranes were stable under …
Trace compounds affecting biogas energy utilisation – A review
2011
Abstract This paper investigates the trace compounds affecting energy utilisation in biogas that come from different production sites. With biogas being more widely used in different energy applications more interest has arisen for the specific composition of biogas. In traditional energy applications, methane and hydrogen sulphide contents have had the most influence when energy utilisation application has been considered. With more advanced processes also the quantity and quality of trace compounds is more important. In regards to trace compounds, it was found that the concentrations and the variations of volatile organic compounds (VOCs) can be high in different landfills, especially, wi…
Emerging techniques in bioethanol production: from distillation to waste valorization
2019
Ethanol production from biomass, especially waste biomass, and the use of such ethanol as fuel can reduce fossil fuel consumption and ameliorate the hidden costs of burning fossil fuels such as its environmental impact. However, bioethanol production suffers from several limitations such as being energy-intensive and generating a sizeable amount of waste. This review briefly describes the aspects related to bioethanol production and focuses on both theoretical and practical approaches for process improvements. Several green emerging distillation techniques, such as ohmic-assisted hydrodistillation, membrane-assisted distillation, and heat integrated techniques, are shown to be energy-saving…
Performance and combustion analysis of a supercharged double-fuel spark ignition engine
2019
In order to increase fuel economy and reduce pollutant emissions in the last decades light duty spark ignition (SI) engines have become smaller, supercharged and equipped with direct injection. A suitable alternative to oil derived fuel is represented by gaseous fuels, such as Natural Gas (NG) and Liquefied Petroleum Gas (LPG), whose higher knock resistance and better mixing capabilities substantially improve vehicle fuel economy and pollutant emissions. The simultaneous combustion of gasoline and gaseous fuel (Double-Fuel operation, DF) in a naturally aspirated SI engine has already been investigated in the past also by the same authors, proving remarkable results in terms of engine effici…
Calibration of a knock prediction model for the combustion of a gasoline-natural gas mixture
2009
Gaseous fuels, such as Liquefied Petroleum Gas (LPG) and Natural Gas (NG), thank to their good mixing capabilities, allow complete and cleaner combustion than normal gasoline, resulting in lower pollutant emissions and particulate matter. Moreover natural gas, which is mainly constituted by methane, whose molecule has the highest hydrogen/carbon ratio, leads also to lower ozone depleting emissions. The authors in a previous work (1) experienced the simultaneous combustion of gasoline and natural gas in a bi-fuel S.I. engine, exploiting so the high knock resistance of methane to run the engine with an ‘overall stoichiometric’ mixture (thus lowering fuel consumption and emissions) and better …
Measurement methodology for greenhouse gas emissions from storage of forest chips–A review
2015
Abstract Research on greenhouse gas emission related to solid biofuels has focused mainly on the emissions from end use and the production chain. GHG emissions from the storage of forest chips have not received much attention in recent literature. In order for EU emission reduction targets to be fully understood, emissions from solid biofuel storage needs to be better described. Usually emissions from chip piles have been modelled using studies from organic waste composting but these two materials can differ appreciably; for example the C/N-ratio and moisture content. Herein, previous studies on greenhouse gas emissions from forest chips piles during storage are reviewed. The objective is t…
Full-scale biotrickling filtration of volatile organic compounds from air emission in wood-coating activities
2012
BACKGROUND: Biotrickling filtration could be considered as a suitable and viable technology for controlling the industrial emissions of volatile organic compounds (VOCs) in waste gases. In this study, the performance of a full-scale biotrickling system, including a passively activated carbon-smoothing prefilter was investigated for the treatment of exhaust gases from two different paint spray sources at a furniture facility. RESULTS: The VOC profiles were uneven for both sources, but the second source was more irregular, with highly variable VOC loads. The plant was operated at empty bed residence times (EBRTs) between 20 and 100 s. The system was able to control the VOC emissions, so air t…