Search results for "functional"
showing 10 items of 4822 documents
Substituent effects in nitro derivatives of carbazoles investigated by comparison of low-temperature crystallographic studies with density functional…
2014
The crystal structure of 9H-carbazole, C12H9N, (I), has been redetermined at low temperature for use as a reference structure in a comparative study with the structures of 1-nitro-9H-carbazole, C12H8N2O2, (II), and 9-nitrocarbazole, C12H8N2O2, (III). The molecule of (I) has crystallographically imposed mirror symmetry (Z′ = 0.5). All three solid-state structures are slightly nonplanar, the dihedral angles between the planes of the arene and pyrrole rings ranging from 0.40 (7)° in (III) to 1.82 (18)° in (II). Nevertheless, a density functional theory (DFT) study predicts completely planar conformations for the isolated molecules. To estimate the influence of nitro-group substitution on aroma…
A new approach for clustering of effects in quantile regression
2017
In this paper we aim at nding similarities among the coefficients from a multivariate regression. Using a quantile regression coefficients modeling, the effect of each covariate, given a response (also multivariate) is a curve in the multidimensional space of the percentiles. Collecting all the curves, describing the effects of each covariate on each response variable, we could be able to assess if only one or more covariates have same effects on different responses.
SUGGESTIONS OF SCENARIOS FOR RESTORING LONGITUDINAL CONNECTIVITY TO SUSTAIN FISH FAUNA MIGRATION UPSTREAM AND DOWNSTREAM OF APAHIDA BOTTOM SILL
2016
Rivers and their corridors form complex ecosystems that include adjacent land, flora and fauna and the actual courses of water. Given the ecological criteria for prioritizing the rehabilitation of longitudinal continuity of watercourses recommended by the International Commission for Protection of the Danube River (ICPDR) (Appendix 1) and starting from the analysis of the Management Plan to ensure longitudinal continuity of watercourses in Some?-Tisa River Area (Annex 9.17.a in BMP – Basin Management Plan) there have been proposed several scenarios in order to facilitate fish species migration above the bottom sill from Apahida. The selected case study is focused on the mentioned discharge …
DEFAULT MODE NETWORK AND WORKING MEMORY NETWORK DURING AN FMRI WORKING MEMORY TASK: DIFFERENCES AND CORRELATIONS WITH BEHAVIORAL PERFORMANCE
2013
INTRODUCTION Previous neuroimaging studies have shown that working memory load has marked effects on regional neural activation[1-5]. However, the mechanism through which working memory load modulates brain connectivity is still unclear. During a working memory task, two of the most involved networks are the default mode network (DMN) and the working memory network (WMN)[6-7]: the selective focus on these networks can be useful in better understanding the load effects. Spatial independent component analysis (ICA)[8] has becomes a reliable technique to investigate the networks involved during an fMRI task, as it extracts spatiotemporal patterns of neural activity maximizing spatial independe…
Synthesis and self-assembly of a PEGylated-graphene aerogel
2016
Abstract In the frame of this work, we present, for the first time, the synthesis and self-assembly of an aerogel built by graphene oxide-polyethylene glycol. The synthetic route involves at first the coupling of GO with an amino-terminated polyethylene glycol sample by carbodiimide in aqueous environment, and the subsequent conversion of the hydrogel achieved into an aerogel via freeze-drying. The 3D PEGylated graphene-based aerogel, characterized by spectroscopic, morphological, structural and mechanical analyses, displays an ultralight and highly porous (99.7%) network and possesses high mechanical properties together with a good biocompatibility.
Robust delay-dependent H∞ control of uncertain time-delay systems with mixed neutral, discrete, and distributed time-delays and Markovian switching p…
2011
Author's version of an article published in the journal: IEEE Transactions on Circuits and Systems I: Regular Papers. Also available from the publisher at: http://dx.doi.org/10.1109/tcsi.2011.2106090 The problem of robust mode-dependent delayed state feedback H ∞ control is investigated for a class of uncertain time-delay systems with Markovian switching parameters and mixed discrete, neutral, and distributed delays. Based on the LyapunovKrasovskii functional theory, new required sufficient conditions are established in terms of delay-dependent linear matrix inequalities for the stochastic stability and stabilization of the considered system using some free matrices. The desired control is …
Progettare interventi di sostegno didattico tra profilo di funzionamento e dimensioni di sviluppo
2023
Il contributo presenta le caratteristiche d’uso dell’International Classification of Functioning, Disability and Health (ICF, 2001) per strutturare a scuola percorsi differenziati per gli alunni in situazione di disabilità. L’insegnante ha il compito di creare un ambiente di apprendimento inclusivo, di organizzare attività coerenti con gli obiettivi, di usare strategie adeguate ai bisogni educativi. Per progettare interventi efficaci di sostegno didattico egli osserva le difficoltà e le capacità potenziali dell’alunno, si propone lo sviluppo e il miglioramento di performance significative nel contesto, pensa come insegnare per favorire la partecipazione, personalizza le verifiche e valuta c…
B‐DNA structure and stability: the role of nucleotide composition and order
2022
Abstract We have quantum chemically analyzed the influence of nucleotide composition and sequence (that is, order) on the stability of double‐stranded B‐DNA triplets in aqueous solution. To this end, we have investigated the structure and bonding of all 32 possible DNA duplexes with Watson–Crick base pairing, using dispersion‐corrected DFT at the BLYP‐D3(BJ)/TZ2P level and COSMO for simulating aqueous solvation. We find enhanced stabilities for duplexes possessing a higher GC base pair content. Our activation strain analyses unexpectedly identify the loss of stacking interactions within individual strands as a destabilizing factor in the duplex formation, in addition to the better‐known eff…
Testing the Sobolev property with a single test plan
2020
We prove that in a vast class of metric measure spaces (namely, those whose associated Sobolev space is separable) the following property holds: a single test plan can be used to recover the minimal weak upper gradient of any Sobolev function. This means that, in order to identify which are the exceptional curves in the weak upper gradient inequality, it suffices to consider the negligible sets of a suitable Borel measure on curves, rather than the ones of the $p$-modulus. Moreover, on $\sf RCD$ spaces we can improve our result, showing that the test plan can be also chosen to be concentrated on an equi-Lipschitz family of curves.
Recent Advances on the Halo- and Cyano-Trifluoromethylation of Alkenes and Alkynes
2021
Incorporation of fluorine into organic molecules is a well-established strategy in the design of advanced materials, agrochemicals, and pharmaceuticals. Among numerous modern synthetic approaches, functionalization of unsaturated bonds with simultaneous addition of trifluoromethyl group along with other substituents is currently one of the most attractive methods undergoing wide-ranging development. In this review article, we discuss the most significant contributions made in this area during the last decade (2012−2021). The reactions reviewed in this work include chloro-, bromo-, iodo-, fluoro- and cyano-trifluoromethylation of alkenes and alkynes.