Search results for "gate"

Ultracold quantum gases in optical lattices

2005

Artificial crystals of light, consisting of hundreds of thousands of optical microtraps, are routinely created by interfering optical laser beams. These so-called optical lattices act as versatile potential landscapes to trap ultracold quantum gases of bosons and fermions. They form powerful model systems of quantum many-body systems in periodic potentials for probing nonlinear wave dynamics and strongly correlated quantum phases, building fundamental quantum gates or observing Fermi surfaces in periodic potentials. Optical lattices represent a fast-paced modern and interdisciplinary field of research.

Direct measurement of forces between particles and bubbles

1999

One of the elementary stages of the flotation process is the formation of an aggregate between the particle and a bubble. This aggregate formation is governed by hydrodynamic, capillary and interparticle forces. During the last four years, techniques have been developed to measure directly the force between a colloidal particle and a bubble. These techniques are closely related to the development of atomic force microscopy. Advantages and possibilities, as well as limits and drawbacks are described.

Effects of water dielectric saturation on the space–charge junction of a fixed-charge bipolar membrane

2000

Abstract The dielectric saturation at the space–charge junction of a fixed-charge bipolar membrane is studied using the theoretical approach by Booth for the water dielectric constant and the Poisson equation for the electrical double layer at the junction. The numerical solution gives the electric field and dielectric constant profiles through the junction as well as the junction thickness as a function of the voltage drop. The water dielectric constant decreases substantially for the large electric fields that may occur at the narrow bipolar junction.

¿Conjugated? Copolymers from a Pechmann Dye Derivative

2016

Tailored conjugated polymer Langmuir-Schafer thin films in sensing transistors

2004

Organic Thin Film Transistors (OTFTs) have been fabricated, in a standard bottom gate configuration, with Langmuir-Schäfer (LS) or cast thin films of regioregular poly[1,4-(2,5-dioctyloxyphenylene)-2,5-thiophene], synthesized via an organometallic protocol, as active layers. The transistors electrical characterization has evidenced that LS based devices exhibit better performance level than cast film ones. Appealing perspectives for newly substituted conjugated polymers in OTFT sensing devices are discussed.

Polymer-based symmetric electrochromic devices

1999

Abstract The fact that conjugated polymers repeatedly undergo electrochemical doping/undoping processes, which are accompained by color changes, makes these materials very attractive, and much effort has been devoted to their use in advanced devices. There is renewed interest in electroactive polymers that reversibly undergo both p- and n-doping because of their potential application in symmetric electrochemical devices. We employed fused molecules, dithienothiophenes, as monomers to obtain polymers with a narrow band gap suitable for n- and p-doping. The performance results of two symmetric electrochromic devices having as electrodes both poly(dithieno[3,4-b:3',4'-d]thiophene) (pDTT1) and …

Physicochemical and functional characterization of the polymerization process of the Geodia cydonium lectin

1985

The extracellularly localized, galactose-specific lectin from the sponge Geodia cydonium binds at one class of sites, 40 mol Ca2+/mol lectin with an association constant (Ka) of 0.3 X 10(6)M-1. Stoichiometric calculations reveal that in the extracellular milieu 22 mol Ca2+ (maximum) are complexed per mol lectin. Binding of Ca2+ to the lectin increases its apparent Mr from 44000 to 56000 (electrophoretic determination) or from 36500 to 53500 (high-pressure liquid gel chromatographical determination); the s20, w increases from 4.3 S to 4.5 S if Ca2+ is added to the lectin. In the presence of Ca2+ the lectin undergoes a conformational change perhaps by expanding the carbohydrate side chains wh…

A Computational Approach to Conjugate Heat Transfer between Two Fluids in Plate Heat Exchangers of Arbitrary Geometry

2002

Chebyshev’s Method on Projective Fluids

2020

We demonstrate the acceleration potential of the Chebyshev semi-iterative approach for fluid simulations in Projective Dynamics. The Chebyshev approach has been successfully tested for deformable bodies, where the dynamical system behaves relatively linearly, even though Projective Dynamics, in general, is fundamentally nonlinear. The results for more complex constraints, like fluids, with a particular nonlinear dynamical system, remained unknown so far. We follow a method describing particle-based fluids in Projective Dynamics while replacing the Conjugate Gradient solver with Chebyshev’s method. Our results show that Chebyshev’s method can be successfully applied to fluids and potentially…

Reactivity of Nickel(II) Porphyrins in oCVD Processes—Polymerisation, Intramolecular Cyclisation and Chlorination

2019

Abstract Oxidative chemical vapour deposition of (5,15‐diphenylporphyrinato)nickel(II) (NiDPP) with iron(III) chloride as oxidant yielded a conjugated poly(metalloporphyrin) as a highly coloured thin film, which is potentially useful for optoelectronic applications. This study clarified the reactive sites of the porphyrin monomer NiDPP by HRMS, UV/Vis/NIR spectroscopy, cyclic voltammetry and EPR spectroscopy in combination with quantum chemical calculations. Unsubstituted meso positions are essential for successful polymerisation, as demonstrated by varying the porphyrin meso substituent pattern from di‐ to tri‐ and tetraphenyl substitution. DFT calculations support the proposed radical oxi…