Search results for "geochemistry."
showing 10 items of 2961 documents
Rapid oxidation of mercury (Hg) at volcanic vents: Insights from high temperature thermodynamic models of Mt Etna's emissions
2011
A major uncertainty regarding the environmental impacts of volcanic Hg is the extent to which Hg is deposited locally or transported globally. An important control on dispersion and deposition is the oxidation state of Hg compounds: Hg(0) is an inert, insoluble gas, while Hg(II) occurs as reactive gases or in particles, which deposit rapidly and proximally, near the volcanic vent. Using a new high temperature thermodynamic model, we show that although Hg in Etna's magmatic gases is almost entirely Hg(0) (i.e., gaseous elemental mercury), significant quantities of Hg(II) are likely formed at Etna's vents as gaseous HgCl2, when magmatic gases are cooled and oxidised by atmospheric gases. Thes…
Volcanic SiO2-cristobalite: A natural product of chemical vapor deposition
2020
Abstract Cristobalite is a low-pressure, high-temperature SiO2 polymorph that occurs as a metastable phase in many geologic settings, including as crystals deposited from vapor within the pores of volcanic rocks. Such vapor-phase cristobalite (VPC) has been inferred to result from silica redistribution by acidic volcanic gases but a precise mechanism for its formation has not been established. We address this by investigating the composition and structure of VPC deposited on plagioclase substrates within a rhyolite lava flow, at the micrometer to nanometer scale. The VPC contains impurities of the form [AlO4/Na+]0—coupled substitution of Al3+ charge-balanced by interstitial Na+—which are ty…
Minor and trace elements in olivines as probes into early igneous and mantle melting processes
2013
Abstract The trace element composition of olivine is a rapidly growing research area that has several applications of great potential. Mantle olivines can be distinguished from volcanic olivines by lower concentrations of Ca (
Variation of olivine composition in the volcanic rocks in the Songliao basin, NE China: lithosphere control on the origin of the K-rich intraplate ma…
2016
Abstract Lithospheric thickness and the heterogeneity of the mantle lithosphere are two major parameters that play a role in determining the final composition of the mafic melts and their minerals. The Songliao basin in northeast China represents an ideal natural laboratory to study the effect of these two parameters on early Pliocene to Holocene K-rich mafic lavas (K2O > 4 wt.%; K2O/Na2O > 1). A series of Cenozoic volcanic edifices (Erkeshan, Wudalianchi, Keluo and Xiaogulihe) are tentatively divided into three groups (Group 1 — thin, Group 2 — middle, and Group 3 — thick) according to the lithosphere thickness. They are located in the northern region of the Songliao basin extending in a n…
Does second phase content control the evolution of olivine CPO type and deformation mechanisms? A case study of paired harzburgite and dunite bands i…
2021
Abstract We have examined the microstructures and crystallographic preferred orientations (CPOs) of six “paired” harzburgite and dunite samples from a small (~ 1 km2) area in the Ellis Stream Complex, Red Hills Massif, Dun Mountain ophiolite belt in New Zealand. Here, banded peridotites with isoclinal folds, E-W striking vertical foliations and vertical lineations are inferred to result from shear on vertical planes that overprint previous mantle structures. The samples contain five different olivine CPOs: typically known as A, C, D, E and AG-types. The co-located harzburgite and dunite of each pair show different CPOs (e.g., A vs E type). In each pair, dunite generally has larger grain siz…
Lamproites as indicators of accretion and/or shallow subduction in the assembly of south-western Anatolia, Turkey
2010
IntroductionThe Western Anatolian region of Tur-key is tectonically one of the mostcomplex parts of the Alpine–Himala-yan orogenic belt (Fig. 1) because ofits long accretional palaeotectonicevolution. One of the major tectonicfeatures shaping the structure ofwestern Anatolia is the Menderesmetamorphic massif, which consistsof several assembled and imbricatedterranes exhumed during the exten-sion that affected the entire Aegeanprovince during the Late Miocene(Yilmaz et al., 2000; Okay, 2002).The Menderes Massif is usually inter-preted as a core complex delineated bylow-angle detachment faults (Bozkurtand Park, 1994; Hetzel et al., 1995;Ring et al., 2003). An alternativeexplanation associates …
The olivine macrocryst problem: New insights from minor and trace element compositions of olivine from Lac de Gras kimberlites, Canada
2015
This study presents detailed petrographical and geochemical investigations on remarkably fresh olivines in kimberlites from the EKATI Diamond Mine™ located in the Tertiary/Cretaceous Lac de Gras kimberlite field within the Slave craton of Canada. Olivine, constituting about 42 vol.% of the analyzed samples, can be divided into two textural groups: (i) macrocrystic olivines, > 100 μm sub-rounded crystals and (ii) groundmass olivines, < 100 μm subhedral crystals. Olivines from both populations define two distinct chemical trends; a “mantle trend” with angular cores, showing low Ca (< 0.1 wt.% CaO) and high Ni (0.3–0.4 wt.% NiO) at varying Mg# (0.86–0.93), contrasts with a “melt trend” typifie…
Zircon ages and Hf isotopic compositions of Ordovician and Carboniferous granitoids from central Inner Mongolia and their significance for early and …
2016
Abstract We present zircon ages and Hf-in-zircon isotopic data for plutonic rocks and review the evolution of central Inner Mongolia, China, in the early and late Paleozoic. Zircons of a granodiorite yielded a 206 Pb/ 238 U age of 472 ± 3 Ma that reflects the time of early Paleozoic magmatism. Zircon ages were also obtained for a tonalite (329 ± 3 Ma), quartz-diorite (320 ± 3 Ma), and granite vein (297 ± 2 Ma). Our results, in combination with published zircon ages and geochemical data, document distinct magmatic episodes in central Inner Mongolia. The dated samples are mostly granodiorite, tonalite and quartz-diorite in composition with intermediate to high-silica, high Na 2 O (3.08–4.26 w…
Serbo-Macedonian revisited: A Silurian basement terrane from northern Gondwana in the Internal Hellenides, Greece
2009
Abstract New geochronological and geochemical data on basement orthogneisses from the Vertiskos Unit of the Serbo-Macedonian Massif (SMM), Internal Hellenides, northern Greece, are used in order to constrain the pre-Alpine tectonic history of the basement units in the metamorphic hinterland of the Hellenides. The prevailing rock types in the Vertiskos crystalline basement are coarse-grained biotite augengneisses with subordinate leucocratic muscovite gneisses and two-mica gneisses. Zircon Pb–Pb and U–Pb ages on 20 samples range from 425.9 ± 4.2 Ma to 443.4 ± 5.5 Ma with a mean of 432.2 ± 3.2 Ma and are interpreted as primary crystallisation ages of the basement granites on the basis of the …
A fault-related coalification anomaly in the Blanzy-Montceau Coal Basin (Massif Central, France)
1997
Abstract The Stephanian intramontane Blanzy-Montceau Coal Basin is situated along a Variscan fault complex bordering the Upper Paleozoic Blanzy-Le Creusot-Bert graben. The deposition of coal-bearing strata was controlled by a complex of early faults known as the “Faille de Bordure” (FB, Border Fault). Another complex of Permian faults known as the “Faille de l'Est” (FE, Eastern Fault) is situated along the more central part of the coal basin. Coalification in the basin follows three main trends: (1) Increasing rank from upper to lower coal seams in accordance with a general vertical trend (Hilt, 1873). The gradient of volatile matter is higher than normal, ranging from 3% to I I% Vdaf per 1…