Search results for "geochemistry"
showing 10 items of 2967 documents
Light hydrocarbons as a proxy to identify the origin of the gas manifestations in Greece
2017
The geologic emissions of greenhouse gases (CO2 and CH4) have an important natural contribution in the global carbon budget. Tectonics, through faults in geothermal and oil producing areas, play a significant role in the release of C-gases in many non-volcanic regions of the Earth. Methane, the most abundant organic compound in Earth’s atmosphere, has a potential global warming that is 28 times higher than that of CO2 on a 100-year time horizon. In this study, δ13C-CH4, δ2H-CH4 and light hydrocarbon (alkane: CH4, C2H6, C3H8, C3H6, i-C4H10, n-C4H10; alkene C3H6, iC4H8; and aromatic C6H6) gas concentration data of 119 gas samples (103 unpublished data and 16 literature data) from volcanic-hyd…
Mineralogy of the soils altered by fumarolic activity at Nisyros volcano, Greece
2017
Nisyros is the easternmost island of the South Aegean Active Volcanic arc in Greece. It is an active stratovolcano known for its intense hydrothermal activity. In this study we present the results of the mineralogical analyses of 20 soil samples collected in the caldera area. Samples were analysed through X-ray diffraction and the results allow us to divide them in two groups: Lakki Plain and Stefanos Crater. In their majority the soils of Lakki Plain have a main mineralogical assemblage that consists of quartz, feldspar and gismondine (Ca2Al4Si4O16·9H2O). Gismondine as well as stellerite (CaAl2Si7O18·7H2O), which is appearing in some samples, derive from hydrothermal alteration, whilst wol…
Insights on Hydrothermal‐Magmatic Interactions and Eruptive Processes at Poás Volcano (Costa Rica) From High‐Frequency Gas Monitoring and Drone Measu…
2019
Texto completo del documento Identification of unambiguous signals of volcanic unrest is crucial in hazard assessment. Processes leading to phreatic and phreatomagmatic eruptions remain poorly understood, inhibiting effective eruption forecasting. Our 5‐year gas record from Poás volcano, combined with geophysical data, reveals systematic behavior associated with hydrothermal‐magmatic eruptions. Three eruptive episodes are covered, each with distinct geochemical and geophysical characteristics. Periods with larger eruptions tend to be associated with stronger excursions in monitoring data, particularly in SO2/CO2 and SO2 flux. The explosive 2017 phreatomagmatic eruption was the largest erupt…
Authigenic phases and biomass contents drive Zr, Hf and REE distributions in anoxic lake sediments.
2013
Abstract. REE, Zr and Hf distributions in seafloor sediments collected from the hypersaline, anoxic Thetis, Kryos, Medee and Tyro deep-sea basins from the Eastern Mediterranean were determined in light of their mineralogical composition, and biomass contents. Mineralogical investigations demonstrate that all the studied sediments show a similar mineralogy. Detritic assemblages mainly consist of quartz, gypsum and calcite with Mg contents ranging from 0 to about 7%, often of a bioclastic nature. On the contrary, authigenic parageneses are formed by halite, bischofite, dolomite and calcite, with Mg contents up to 22%. Textural evidences of biological activity were also identified. In sediment…
The history of Ludovico Sicardi and the birth of geochemical
2022
Ludovico Sicardi was a chemist and a pharmacist, and a passionate researcher, enthusiastic about phenomena related to volcanic activity. Due to a field survey within a project of mining research committed by a private company, he has the opportunity to visit the island of Vulcano (Eolie - Sicily), from December 1921 to June 1922. He was completely fascinated by the wild island of Vulcano and its gas manifestations. During several successive field trips in Vulcano, he observed and described the fumarolic field on a systematic basis, measuring the temperatures and recording their variations over time. He was one of the first to perform chemical analysis of fluids emitted by fumaroles in Vulca…
The behavior of Rare-Earth Elements, Zr and Hf during biologically-mediated deposition of silica-stromatolites and carbonate-rich microbial mats
2015
Abstract Venere Lake, in the Pantelleria Island thermal system (Central Mediterranean Sea) consists of a mix of seawater and hydrothermal volcanic fluids containing high levels of dissolved SiO 2 . Close to the lake's thermal springs, siliceous stromatolites are deposed under high bacterial activity conditions whereas roughly interlaminated Ca-carbonates and microbial mats are widely scattered in the lake. The dissolved REE speciation in lake waters is dominated by [REE(CO 3 ) 2 ] − , [REE(CO 3 )] + and [REE(H 3 SiO 4 )] 2 + complexes. On the contrary the most abundant Zr and Hf species are hydroxyl- and fluoride-complexes. The behavior of REE Zr and Hf in the Venere lake waters is controll…
Geochemistry of the thermomineral waters in Greece
2020
Many geothermal areas of Greece are located in regions affected by Miocene or Quaternary volcanism and in continental basins characterized by elevated heat flow. Moreover, the majority of them is found along the coast as well as in islands of the Aegean Sea and thus thermal water is often brackish to saline due to marine intrusion into coastal aquifer. In the present study, almost 300 thermal and cold mineral water samples were collected along the Hellenic territory with their physicochemical parameters (temperature, pH, electrical conductivity and Eh) and the amount of bicarbonates (titration with 0.1N HCl) being determined in situ. Additionally, gases, found either in free or dissolved ph…
On the formation of laminated sediments on the continental margin off Pakistan: the effects of sediment provenance and sediment redistribution
2001
Abstract The sedimentary processes and sediment sources contributing to the formation of laminated sediments along the upper slope off Pakistan are unravelled using inorganic bulk sediment geochemistry of 43 surface cores from the Pakistani continental margin and additional geochemical and Pb and Nd-isotope data for different types of layers. An important process everywhere along the margin is redeposition of fluvial-derived detritus from the shelf onto the slope. This process is of considerably higher intensity along the Makran margin than on the Indus margin. Trace element enrichment related to early diagenesis or surface productivity, which is commonly detectable in bulk sediment composi…
Climate signatures on decadal to interdecadal time scales as obtained from mollusk shells (Arctica islandica) from Iceland
2013
Abstract Pronounced decadal climate oscillations are detected in a multi-centennial record based on shell growth rates of the marine bivalve mollusk, Arctica islandica, from Iceland. The corresponding analysis of patterns in sea level pressure and temperature exhibit large-scale teleconnections with North Atlantic climate quantities. We find that the record projects onto blocking situations in the northern North Atlantic. The associated circulation shows a low-pressure signature over Greenland and the Labrador Sea and a high-pressure system over Western Europe associated with northeasterly flow towards Iceland and weakening in the westerly zonal flow over Europe. It can be speculated that s…