Search results for "green chemistry"

showing 10 items of 159 documents

Protocol for development of various plants leaves extract in single-pot synthesis of metal nanoparticles

2012

This article is aimed to extend a simple protocol for preparation of various plant leaves extract and their application to green synthesis of the metallic nanoparticles. Five plant leaves extract showed mild reduction and stabilization ability for silver and gold nanoparticles (AgNPs and AuNPs) at room temperature. The particle size range varied from 25 to 42 nm and 21 to 47 nm for AgNPs and AuNPs, respectively. Plant leaves extract-mediated nanoparticles were characterized to confirm the shape, size, crystallinity, and content using different spectroscopic investigations. Differences in stability of nanoparticles at different pH were also measured by zeta potential.

SilverPlant ExtractsChemistryPotentiometric titrationAnalytical chemistryMetal NanoparticlesNanoparticleGreen Chemistry TechnologyOxidation reductionAtomic and Molecular Physics and OpticsAnalytical ChemistryPlant LeavesCrystallinityX-Ray DiffractionColloidal goldZeta potentialGoldParticle sizeParticle SizeMetal nanoparticlesOxidation-ReductionInstrumentationta116SpectroscopyNuclear chemistrySpectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
researchProduct

Enseñanza de las ciencias : revista de investigación y experiencias didácticas

2021

Este trabajo se plantea estudiar el papel de la Química Verde en la educación científica para contribuir, desde ese campo, a la Ciencia de la Sostenibilidad y, por tanto, a la transición hacia sociedades sostenibles. Se mostrarán unos primeros resultados de una investigación llevada a cabo sobre la atención que la enseñanza secundaria y la propia investigación en el campo de la didáctica de las ciencias están prestando a las aportaciones de la Química Verde, y la posibilidad de su incorporación en la formación de la ciudadanía y la adopción de medidas necesarias para contribuir a la construcción de un futuro sostenible. Se pretende así responder a los numerosos llamamientos para que la educ…

Sostenibilitatenseñanza secundariaquímicagreen chemistry; sustainability; science education; sustainability science; STSE relationshipsresponsabilidadInteraccions ctsaStse relationshipsEducationecologíaSustainability scienceScience educationprotección del medio ambienteinvestigación educativaQuímicaCiència de la sostenibilitatprograma de estudiosquímica verde; sostenibilidad; educación científica; ciencia de la sostenibilidad; interacciones CTSASostenibilidadInteracciones ctsaQuímica verdequímica verda; sostenibilitat; educació científica; ciència de la sostenibilitat; interaccions CTSAeducación científicacontenido de la educaciónGreen chemistrySustainabilityQuímica verdaEducació secundàriaEducació científicaCiencia de la sostenibilidad
researchProduct

Sustainable soy protein microsponges for efficient removal of lead (II) from aqueous environments

2023

Protein-based materials recently emerged as good candidates for water cleaning applications, due to the large availability of the constituent material, their biocompatibility and the ease of preparation. In this work, new adsorbent biomaterials were created from Soy Protein Isolate (SPI) in aqueous solution using a simple environmentally friendly procedure. Protein microsponge-like structures were produced and characterized by means of spectroscopy and fluorescence microscopy methods. The efficiency of these structures in removing Pb2+ ions from aqueous solutions was evaluated by investigating the adsorption mechanisms. The molecular structure and, consequently, the physico-chemical propert…

SoyLeadGreen chemistryStructural BiologyGeneral MedicineAdsorptionMolecular BiologyBiochemistryAmyloid superstructuresWater contaminationSettore FIS/07 - Fisica Applicata(Beni Culturali Ambientali Biol.e Medicin)
researchProduct

Hydroxypropylcellulose as a novel green reservoir for the synthesis, stabilization, and storage of silver nanoparticles

2015

Muhammad Ajaz Hussain,1 Abdullah Shah,1 Ibrahim Jantan,2 Muhammad Raza Shah,3 Muhammad Nawaz Tahir,4 Riaz Ahmad,5 Syed Nasir Abbas Bukhari2 1Department of Chemistry, University of Sargodha, Sargodha, Pakistan; 2Drug and Herbal Research Centre, Faculty of Pharmacy, Universiti Kebangsaan Malaysia, Jalan Raja Muda Abdul Aziz, Kuala Lumpur, Malaysia; 3International Center for Chemical and Biological Sciences, University of Karachi, Karachi, Pakistan; 4Institute of Inorganic and Analytical Chemistry, Johannes Guttenberg University, Duesbergweg, Mainz, Germany; 5Centre for Advanced Studies in Physics (CASP), GC University, Lahore, Pakistan Abstract: Polysaccharides are attracting the vigil eye of…

Staphylococcus aureusSilverMaterials scienceScanning electron microscopeDrug StorageBiophysicsMetal NanoparticlesPharmaceutical ScienceBioengineeringNanotechnologyNanoreactorMicroscopy Atomic Forcenanobiotechnologyantimicrobial assaySilver nanoparticlestorageBiomaterialsAnti-Infective AgentsMicroscopy Electron TransmissionX-Ray DiffractionInternational Journal of NanomedicinePhase (matter)Spectroscopy Fourier Transform InfraredDrug DiscoveryEscherichia coliStaphylococcus epidermidisThin filmCelluloseOriginal ResearchAqueous solutiongreen synthesisOrganic Chemistrytechnology industry and agricultureGreen Chemistry TechnologyGeneral MedicinestabilityTransmission electron microscopyPseudomonas aeruginosaMicroscopy Electron ScanningSunlightAspergillus nigernanoreactorAbsorption (chemistry)Bacillus subtilisNuclear chemistryInternational Journal of Nanomedicine
researchProduct

Current and New Insights in the Sustainable and Green Recovery of Nutritionally Valuable Compounds from Stevia rebaudiana Bertoni.

2015

International audience; The South American plant Stevia rebaudiana Bertoni is a great source of noncaloric sweeteners (steviol glycosides), mainly concentrated in its leaves, but also has important antioxidant compounds (vitamin C, polyphenols, chlorophylls, and carotenoids) and other important macro- and micronutrients such as folic acid and all of the essential amino acids except tryptophan. Traditionally, conventional methods have been used to recover nutritionally valuable compounds from plant food matrices. However, nowadays, the need for obtaining greener, sustainable, and viable processes has led both food industries and food scientists to develop new processes in full correspondence…

Stevia rebaudiana; food additives; nutraceuticals; conventional extraction; pulsed electric technologies; acoustic technologies; sub- and supercritical fluid extraction; microwave assisted extraction[SDV.BIO]Life Sciences [q-bio]/Biotechnologyfood.ingredient[SDV]Life Sciences [q-bio]microwave assisted extractionSteviolBiologyPlant foodschemistry.chemical_compoundpulsed electric technologiesfoodNutraceuticalStevia[SPI.GPROC]Engineering Sciences [physics]/Chemical and Process Engineeringacoustic technologiesnutraceuticals2. Zero hungerbusiness.industryPlant ExtractsFood additivefood and beveragesGreen Chemistry TechnologyGeneral Chemistrysub- and supercritical fluid extractionBiotechnologyfood additivesPlant LeavesStevia rebaudianachemistryFolic acidPolyphenolSouth americanGeneral Agricultural and Biological Sciencesbusinessconventional extraction[SDV.AEN]Life Sciences [q-bio]/Food and NutritionNutritive ValueStevia rebaudianaJournal of agricultural and food chemistry
researchProduct

Green determination of the presence of volatile organic compounds in vehicle repair shops through passive sampling.

2012

A simple, fast and green direct analytical methodology has been developed to evaluate the concentration level of volatile organic compounds (VOCs) in indoor areas of vehicle repair shops using membrane devices as passive samplers. VOCs retained in the samplers were directly determined without any sample pre-treatment and avoiding the use of solvents by head space (HS) coupled to gas chromatography-mass spectrometry (GC-MS) in only 20 min. Benzene, toluene, tetrachloroethene, m,p-xylene and o-xylene were found at concentration levels from 0.1 to 11.2 mg m(-3).

TetrachloroethyleneVolatile Organic CompoundsBenzeneGreen Chemistry TechnologyAir Pollutants OccupationalXylenesMass spectrometryTolueneAnalytical Chemistrychemistry.chemical_compoundchemistryAir pollutantsEnvironmental chemistryIn vehicleHumansBenzenePassive samplingTolueneTalanta
researchProduct

Straightforward preparation of highly loaded MWCNT-polyamine hybrids and their application in catalysis

2020

Multiwalled carbon nanotubes (MWCNTs) were easily and efficiently functionalised with highly cross-linked polyamines. The radical polymerisation of two bis-vinylimidazolium salts in the presence of pristine MWCNTs and azobisisobutyronitrile (AIBN) as a radical initiator led to the formation of materials with a high functionalisation degree. The subsequent treatment with sodium borohydride gave rise to the reduction of imidazolium moieties with the concomitant formation of secondary and tertiary amino groups. The obtained materials were characterised by thermogravimetric analysis (TGA), elemental analysis, solid state 13C-NMR, Fourier-transform infrared spectroscopy (FT-IR), transmission ele…

Thermogravimetric analysisNitroaldol reactionPotentiometric titrationHeterogeneous Catalysis Carbon nanotubes Ionic Liquids Green Chemistry AminesBioengineering02 engineering and technology010402 general chemistry01 natural sciencesCatalysischemistry.chemical_compoundSodium borohydridePolymer chemistryGeneral Materials ScienceGeneral EngineeringAzobisisobutyronitrileGeneral ChemistrySettore CHIM/06 - Chimica OrganicaMWCNT-polyamine hybrids021001 nanoscience & nanotechnologyAtomic and Molecular Physics and Optics0104 chemical scienceschemistryddc:540Radical initiatorKnoevenagel condensation0210 nano-technologyddc:546
researchProduct

Synthesis of vanillin in water by TiO2 photocatalysis

2012

Abstract The photoproduction of vanillin is studied in aqueous medium starting from trans-ferulic acid, isoeugenol, eugenol or vanillyl alcohol by using both commercial and home prepared TiO2 samples as photocatalysts and batch Pyrex photoreactors. The photo-oxidation at room temperature of these compounds produces vanillin with a selectivity ranging from 1.4 to 21 mol% with respect to the converted substrate. An investigation on the intermediates was performed in the case of trans-ferulic acid; for this substrate the most important intermediates were homovanillic acid, vanillyl mandelic acid, trans-caffeic acid, formic acid, acetic acid, and oxalic acid. The carbon mass balance, including …

Titanium dioxide Photocatalysis Vanillin Partial oxidationSettore ING-IND/24 - Principi Di Ingegneria ChimicaChemistryFormic acidSettore ING-IND/25 - Impianti ChimiciTITANIUM DIOXIDEProcess Chemistry and TechnologyVanillinOxalic acidSubstrate (chemistry)Catalysischemistry.chemical_compoundVanillyl alcoholIsoeugenolAcetic acidSUSTAINABLE CHEMISTRYOrganic chemistryVANILLINSettore CHIM/07 - Fondamenti Chimici Delle TecnologiePHOTOCATALYSISSelectivityTiO2 Selective oxidation VanillinGREEN CHEMISTRYGeneral Environmental ScienceApplied Catalysis B: Environmental
researchProduct

Omega-3 Extraction from Anchovy Fillet Leftovers with Limonene: Chemical, Economic, and Technical Aspects

2019

International audience; We investigate selected chemical, technical, and economic aspects of the production of fish oil rich in polyunsaturated omega-3 fatty acids from anchovy filleting leftovers using d-limonene as the extraction solvent at ambient temperature and pressure. Entirely derived from the orange peel prior to orange squeezing for juice production, the bio-based solvent is easily recovered, affording a circular economy process with significant potential for practical applications.

avantage comparatifqualité techniqueGeneral Chemical Engineering[SDV]Life Sciences [q-bio]Orange (colour)010402 general chemistrynutraceutics01 natural sciencesfish oilArticlechemistry.chemical_compoundAnchovy[SDV.IDA]Life Sciences [q-bio]/Food engineering[SPI.GPROC]Engineering Sciences [physics]/Chemical and Process EngineeringFillet (mechanics)QD1-999bioeconomyLimoneneaspect économiquebiology010405 organic chemistryChemistrygreen chemistrylimonèneGeneral Chemistryextraction d'huileacide gras oméga 3Fish oilbiology.organism_classificationPulp and paper industry0104 chemical scienceshexaneSolventChemistryTemperature and pressurequalité chimiquelimonenehuile de poisson
researchProduct

Iron-Catalyzed C(sp2)-C(sp3) Cross-Coupling of Alkyl Grignard Reagents with Polyaromatic Tosylates

2017

chemistry.chemical_classificationGreen chemistry010405 organic chemistryIron catalyzedOrganic ChemistryHomogeneous catalysis010402 general chemistry01 natural sciences0104 chemical sciencesCoupling (electronics)chemistryReagentPolymer chemistryPhysical and Theoretical ChemistryAlkylEuropean Journal of Organic Chemistry
researchProduct