Search results for "ground"
showing 10 items of 2432 documents
Nonequilibrium Green's function approach to strongly correlated few-electron quantum dots
2009
The effect of electron-electron scattering on the equilibrium properties of few-electron quantum dots is investigated by means of nonequilibrium Green's function theory. The ground and equilibrium states are self-consistently computed from the Matsubara (imaginary time) Green's function for the spatially inhomogeneous quantum dot system whose constituent charge carriers are treated as spin-polarized. To include correlations, the Dyson equation is solved, starting from a Hartree-Fock reference state, within a conserving (second-order) self-energy approximation where direct and exchange contributions to the electron-electron interaction are included on the same footing. We present results for…
Socio-technical innovation in community-based tourism organizations: A proposal for local development
2021
Abstract Socio-technical innovation is based on new patterns of interaction involving a set of new behaviors that have been legitimized in a given context. The approach of socio-technical innovation complements a purely technological innovation focus. However, studies of how to address social and environmental challenges under this approach are scarce. The aim of this paper is to identify the technical and social structures that underpin the socio-technical innovation system of community-based tourism organizations (CBTOs). This paper offers an in-depth case study of a specific type of collective property known as an “ejido”. Through this case study, the paper highlights the aspects that ha…
Retrieval of Forest Water Potential from L-Band Vegetation Optical Depth
2021
A retrieval methodology for forest water potential from ground-based L-band radiometry is proposed. It contains the estimation of the gravimetric and the relative water content of a forest stand and tests in situ- and model-based functions to transform these estimates into forest water potential. The retrieval is based on vegetation optical depth data from a tower-based experiment of the SMAPVEX 19–21 campaign for the period from April to October 2019 at Harvard Forest, MA, USA. In addition, comparison and validation with in situ measurements on leaf and xylem water potential as well as on leaf wetness and complex permittivity are foreseen to understand limitations and potentials of the pro…
Low-energy Neutrino Astronomy in LENA
2015
LENA (Low Energy Neutrino Astronomy) is a proposed next-generation neutrino detector based on 50 kilotons of liquid scintillator. The low detection threshold, good energy resolution and excellent background rejection inherent to the liquid-scintillator detectors make LENA a versatile observatory for low-energy neutrinos from astrophysical and terrestrial sources. In the framework of the European LAGUNA-LBNO design study, LENA is also considered as far detector for a very-long baseline neutrino beam from CERN to Pyhasalmi ¨ (Finland). The present contribution gives an overview LENA’s broad research program, highlighting the unique capabilities of liquid scintillator for the detection of low-…
An experimental and constitutive investigation on the chemo-mechanical behaviour of a clay
2013
Engineering issues for which the understanding of the chemo-mechanical behaviour of soils is relevant include wellbore stability problems, the salinification of groundwater, and nuclear waste storage. However, despite the vast number of situations in which couplings between chemistry and mechanics occur, the available constitutive models rely on limited experimental evidence. This paper presents the results of an experimental programme on the chemo-mechanical behaviour of a non-swelling illite. The osmotic suction is controlled through the ion concentration of sodium chloride in the pore water. Stress paths include mechanical loading at a constant osmotic suction, and an increasing osmotic …
Experimental investigations of the hypernucleus $_Λ^4$H
2015
International audience; Negatively charged pions from two-body decays of stopped _Lambda^4H hypernuclei were studied in 2012 at the Mainz Microtron MAMI, Germany. The momenta of the decay-pions were measured with unprecedented precision by using high-resolution magnetic spectrometers. A challenge of the experiment was the tagging of kaons from associated K^+∧ production off a Be target at very forward angles. In the year 2014, this experiment was continued with a better control of the systematic uncertainties, with better suppression of coincident and random background, improved particle identification, and with higher luminosities. Another key point of the progress was the improvemen…
Succinate-bonded pullulan: An efficient and reusable super-sorbent for cadmium-uptake from spiked high-hardness groundwater.
2015
Abstract Chemically modified pullulan was evaluated for its sorption efficiency and selectivity to remove cadmium (Cd) from spiked high-hardness groundwater (GW). Pullulan esterified with succinic anhydride using dimethylaminopyridine showed a fairly high degree of substitution value as confirmed by 1 H NMR spectroscopy. Pullulan succinate (Pull-Suc) was converted into the sodium salt (Pull-Suc-Na). The effect of contact time (5–200 min) and pH (2–8) on Cd-uptake by the sorbent (Pull-Suc-Na) was investigated. The sorbent showed more than 90% Cd-removal in first 15 min from distilled water (DW) and GW solution, respectively. Comparison of Pull-Suc-Na with other polysaccharidal sorbents sugge…
Europium(III), Terbium(III), and Gadolinium(III) Oxamato-Based Coordination Polymers: Visible Luminescence and Slow Magnetic Relaxation
2021
The reaction of aqueous solutions of EuIII, TbIII, and GdIII ions with Na2Hpcpa [H3pcpa = N-(4-carboxyphenyl)oxamic acid] afforded three new isostructural oxamate-containing lanthanide(III) coordination polymers of general formula {LnIII2(Hpcpa)3(H2O)5·H2O}n [Ln = Eu (1),Tb (2), and Gd(3)]. Their structure is made up of neutral zigzag chains running parallel to the [101] direction where double syn-syn carboxylate(oxamate)-bridged dilanthanide(III) pairs (Ln1 and Ln2) are linked by three Hpcpa2- ligands, one of them with the μ-κ2O,O':κO″ coordination mode and the other two with the μ3-κ2O,O':κO″:κO'''. Additionally, two of those chains are interlinked through hydrogen bonding and π-π type in…
Coexistence of long-range antiferromagnetic order and slow relaxation of the magnetization in the first lanthanide complex of a 1,2,4-benzotriazinyl …
2017
The first lanthanide complex of a 1,2,4-benzotriazinyl radical (1), Dy(1)(tbacac)3 (2, tbacac = 2,2,6,6-tetramethyl-3,5-heptane-dionato), was synthesised and found to have an antiferromagnetically ordered ground state with a metamagnetic phase diagram and a critical field of 0.91 T at 1.85 K. The application of a small dc field revealed the single-molecule magnet behaviour of 2, illustrating the coexistence of long-range antiferromagnetic order and slow relaxation of the magnetization. peerReviewed
Two C3-symmetric Dy3 III complexes with triple di-μ-methoxo-μ-phenoxo bridges, magnetic ground state, and single-molecule magnetic behavior
2014
Two series of isostructural C3-symmetric Ln3 complexes Ln3·[BPh4] and Ln3·0. 33[Ln(NO3)6] (in which LnIII=Gd and Dy) have been prepared from an amino-bis(phenol) ligand. X-ray studies reveal that LnIII ions are connected by one μ2-phenoxo and two μ3-methoxo bridges, thus leading to a hexagonal bipyramidal Ln3O5 bridging core in which LnIII ions exhibit a biaugmented trigonal-prismatic geometry. Magnetic susceptibility studies and ab initio complete active space self-consistent field (CASSCF) calculations indicate that the magnetic coupling between the DyIII ions, which possess a high axial anisotropy in the ground state, is very weakly antiferromagnetic and mainly dipolar in nature. To redu…