Search results for "hard-sphere"
showing 2 items of 2 documents
Hiding in plain view: Colloidal self-assembly from polydisperse populations.
2016
We report small-angle x-ray scattering (SAXS) experiments on aqueous dispersions of colloidal silica with a broad monomodal size distribution (polydispersity 18%, size 8 nm). Over a range of volume fractions the silica particles segregate to build first one, then two distinct sets of colloidal crystals. These dispersions thus demonstrate fractional crystallization and multiple-phase (bcc, Laves AB$_2$, liquid) coexistence. Their remarkable ability to build complex crystal structures from a polydisperse population originates from the intermediate-range nature of interparticle forces, and suggests routes for designing self-assembling colloidal crystals from the bottom-up.
Hard-Core Thinnings of Germ‒Grain Models with Power-Law Grain Sizes
2013
Random sets with long-range dependence can be generated using a Boolean model with power-law grain sizes. We study thinnings of such Boolean models which have the hard-core property that no grains overlap in the resulting germ‒grain model. A fundamental question is whether long-range dependence is preserved under such thinnings. To answer this question, we study four natural thinnings of a Poisson germ‒grain model where the grains are spheres with a regularly varying size distribution. We show that a thinning which favors large grains preserves the slow correlation decay of the original model, whereas a thinning which favors small grains does not. Our most interesting finding concerns the c…