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Recovery of aliphatic low-molecular-mass carboxylic acids from hardwood kraft black liquor

2015

Abstract During alkaline pulping of wood, substantial amounts of carbohydrates-derived aliphatic carboxylic acids (formic and acetic acids together with various hydroxy acids) are formed and dissolved into the cooking liquor (“black liquor”). These acids with low heating values are considered to be potential feedstocks for the chemical industry but, due to many factors, their straightforward recovery as free acids from black liquor (pH 13–14) is difficult. In this paper, we outlined the partial recovery of volatile formic and acetic acids from the acidified birch ( Betula pendula ) kraft black liquor (pH approximately 2.5) by distillation, and the partial recovery of significant low-molecul…

distillationesterificationalkalinitymolecular massFiltration and SeparationhardwoodsAnalytical Chemistrylaw.inventionCatalysisrecoveryResidue (chemistry)esterslawHardwoodOrganic chemistrychemical industryta215DistillationIon exchangeMolecular massChemistryfood and beveragespulp cookingacetic acidkraft procession exchangersmedical problemsBlack liquorKraft paperSeparation and Purification Technology
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