Search results for "hematite"

Comment on "Enthalpy of Uranium Adsorption onto Hematite".

2021

Technogenic Magnetic Particles in Alkaline Dusts from Power and Cement Plants

2012

During this study, we investigated the mineralogical characterization of technogenic magnetic particles (TMPs) contained in alkaline industrial dust and fly ash emitted by coal burning power plants and cement plants. The reaction of tested dust samples varied between values of pH 8 and pH 12. Their magnetic properties were characterized by measurement of magnetic susceptibility (χ), frequency dependence of magnetic susceptibility (χ(fd)), and temperature dependence of magnetic susceptibility. Mineralogical and geochemical analyses included scanning electron microscopy with energy dispersive spectroscopy, microprobe analysis and X-ray diffraction. The TMPs in fly ash from hard coal combustio…

The colours of Segesta. Searching for the traces of the lost pigments

2023

Many monuments and objects of the ancient civilizations were painted, but unfortunately the pigments are not still present and sometimes only small traces are evident. The analysis of the traces requires a multianalytical approach through the use of non-invasive techniques and only if necessary of a microsampling. Here, the study of the traces of colours found in some architectural elements and findings belonging to the Archeological Park of Segesta (Trapani, Italy) is reported. The traces are identified and characterised via several techniques such as Optical Microscopy, UV-Fluorescence Imaging, Fiber Optical Reflectance Spectroscopy (FORS), X-ray Fluorescence (XRF) and FT-IR Spectroscopy.…

CHARACTERIZATION OF IRON COMPOUNDS FROM URBAN AND RURAL AEROSOL SOURCES

2000

Abstract Iron plays an important role in the chemistry and physics (by varying the hygroscopicity) of the atmosphere. Bulk samples were taken from an air-conditioning device, from the electrofilter of a gas–oil power station of the Technical University of and from rural sites near Darmstadt, situated between medium-altitude mountains and with a climate dominated by air masses from the west. Samples were collected in urban and rural (meadow) air, from different waste incineration power stations, from the exhausts of a gasoline and from a diesel motor car, and from a private gas fired heating system. The samples were characterized for elemental composition by total reflection X-ray fluorescen…

Mineralogy at Gusev Crater from the Mössbauer spectrometer on the Spirit Rover.

2004

Mössbauer spectra measured on Mars by the Spirit rover during the primary mission are characterized by two ferrous iron doublets (olivine and probably pyroxene) and a ferric iron doublet (tentatively associated to nanophase ferric iron oxide). Two sextets resulting from nonstoichiometric magnetite are also present, except for a coating on the rock Mazatzal, where a hematite-like sextet is present. Greater proportions of ferric-bearing phases are associated with undisturbed soils and rock surfaces as compared to fresh rock surfaces exposed by grinding. The ubiquitous presence of olivine in soil suggests that physical rather than chemical weathering processes currently dominate at Gusev crat…

Voltammetric analysis of iron oxide pigments

2002

Eighteen earthy and four pure synthetic pigments containing alpha-Fe2O3 (hematite), alpha-FeOOH (goethite) and poorly crystalline Fe and Mn oxide species were analyzed by voltammetry of microparticles. Three natural samples were subjected to an interlaboratory test to evaluate the reproducibility of the voltammetric peak potentials and peak shapes. The results confirmed that linear-sweep voltammetry is able to distinguish between poorly crystalline, ferrihydrite-like oxides and well-crystalline hematite and goethite and to detect XRD-amorphous Mn(III,IV) oxides via the peak occurrence. Voltammetry is further able to distinguish between pigments containing well-crystalline goethite (accordin…

Mapping of corrosion products of highly altered archeological iron using voltammetry of microparticles

2013

The application of the voltammetry of microparticles to identify corrosion products on different localizations of highly altered archeological iron pieces is described. The use of graphite pencil methodology permits to mapping different corrosion products, namely, akaganeite, goethite, hematite, jarosite, magnetite, maghemite and siderite, in iron artifacts. Identification protocols are based on square wave voltammetric measurements performed at sample-modified paraffin-impregnated graphite electrodes immersed into aqueous HCl. This methodology is applied for mapping corrosion products on an Iberian Roman shield boss from the Torre la Sal archeological site (Oropesa, Spain) dated in the IVt…

Identification of Earth Pigments by Applying Hierarchical Cluster Analysis to Solid State Voltammetry. Application to Severely Damaged Frescoes

2007

Multivariate chemometric methods are applied for identifying earth pigments from square-wave voltammetric measurements performed at pigment-modified paraffin-impregnated graphite electrodes allowing for a separation between hematite-based earths, French ochres, Spanish ochres, siennas, umbers and green earths. This methodology is applied to the identification of the pigments in samples from the ceiling frescoes of Antonio Palomino (dated 1707) in the vaulted nave of the Sant Joan del Mercat church in Valencia (Spain). These frescoes suffered considerable damage by fire during the Spanish Civil War in 1936, resulting in severe chemical and chromatic alterations. Electrochemical data, support…

Characterisation of the magnetic iron phases in Clovis Class rocks in Gusev crater from the MER Spirit Mössbauer spectrometer

2007

Abstract Mossbauer backscattering spectra of eight Martian rocks, acquired by the MIMOS II spectrometer of Rover Spirit (MER-A) and containing goethite in addition to other iron minerals, have been selected for in-depth numerical analysis. Where feasible, different temperature windows for a given rock were considered. A novel calibration/folding procedure, exclusively based on the fitted positions of the eight prominent absorption lines in the transmission spectra of the reference target and not relying on the error signal of the MIMOS II spectrometer, has been developed. It is demonstrated that this procedure yields reliable and reasonably accurate values for the adjusted Mossbauer paramet…

Mineralverwitterung, tonmineralbildung und rubefizierung in Terrae calcis der slowakei Ein beitrag zum paläoklimatischen aussagewert von kalkstein-Ro…

1984

Mineral weathering, clay mineral formation and rubefication of Terrae calcis in Slovakia — A contribution to paleoclimatic evidence of limestone Rotlehm (terra rossa) in Central Europe Limestone Rotlehm (Terra rossa) is very often interpreted as a product of intensive mineral weathering and clay formation under subtropic (to tropic) climate. Especially the formation of hematite in soils as the main process of rubefication is generally believed to occur only in warm climates with a seasonal alternation of precipitation and drought. Fossil or relict Terrae rossae in Central Europe are therefore very often considered as witnesses of a corresponding paleoclimate. On the other side many authors …