Search results for "heterogeneous"

Photocatalytic Membrane Reactors: Case Studies and Perspectives

2009

Photocatalysis by polycrystalline semiconductor oxides is being successfully applied to the abatement of organic and inorganic pollutants both in gas and in liquid phase. In order to increase the efficiency of this method, the coupling of this technology with the membrane separation process has been the object of sound investigation. In this combination, the membrane may act in different ways: to confine the photocatalytic powder in the reacting suspension, to selectively separate the photoreaction products, or to be the support of photocatalyst. This article reports recent studies in which different types of membranes (such as distillation, dialysis, nanofiltration, pervaporation and osmos…

Photocatalytic membrane reactors: fundamentals, membrane materials and operational issues

2013

Abstract: This chapter reports the properties of semiconductor materials used in heterogeneous photocatalysis together with a comparison of heterogeneous photocatalytic systems and a brief description of the types of membranes that can be used. Some aspects of membrane operations, such as fouling, separation of a photocatalyst and effectiveness of photodegradation on permeate quality are discussed.

Selective oxidation of phenol and benzoic acid in water via home-prepared TiO2 photocatalysts: Distribution of hydroxylation products

2012

Abstract The hydroxylation of phenol (a substrate containing an electron donor group) and of benzoic acid (a substrate containing an electron withdrawing group) has been carried out by the photocatalytic method in aqueous suspensions containing commercial or home prepared TiO2 samples. The aim of the work was to study the distribution of hydroxylation products when different photocatalysts were used and to correlate the selectivity to some physico-chemical features of the powders. The samples were characterized by X-ray diffraction, thermogravimetry, determination of crystalline phase percentage, specific surface area and zero charge point. The photoreactivity results indicate that the prod…

Photocatalytic oxidation of nitrobenzene and phenylamine: Pathways and kinetics

2007

WOS: 000245150800018

Clean by Light Irradiation: Practical applications of supported TiO2

2010

Selective Heterogeneous Photocatalysis: Achievements and Challenges

2009

SESAMO: An integrated framework for gathering, managing and sharing environmental data

2016

ICT systems are widely adopted for environmental management, but existing solutions address limited tasks and compose a plethora of heterogeneous tools, which impose a great additional effort on the operators. This work presents SESAMO, a novel framework to provide the operators with a unique tool for gathering, managing and merging environmental and territorial data. SESAMO uses WSNs for providing pervasive monitoring of environmental phenomena and exploits a multi-tier infrastructure in order to integrate data coming from heterogeneous information sources.

From Signal Processing to Machine Learning

2018

This chapter reviews the main landmarks of signal processing in the 20th century from the perspective of algorithmic developments. It focuses on cross‐fertilization with the field of statistical (machine) learning in the last decades. In the 21st century, model and data assumptions as well as algorithmic constraints are no longer valid, and the field of machine‐learning signal processing has erupted, with many successful stories to tell. The chapter also focuses on digital signal processing (DSP), which deals with the analysis of digitized and discrete sampled signals. Machine learning is a branch of computer science and artificial intelligence that enables computers to learn from data. Mac…

A new class of heterogeneous Pd catalysts for synthetic organic chemistry

2011

A new series of leach-proof nanostructured Pd(0) catalysts able to catalyze a number of fundamental organic transformations including C–C bond formation has been developed. Reactions in general proceed with high yield and often at completion, while the catalysts can be reused in further reaction runs. This establishes a new class of relevant solid catalysts for synthetic organic chemistry trademarked SiliaCat Pd0 Hydrogel.

Thiazolium-based catalysts for the etherification reaction of benzylic alcohols under solvent-free condition

2015

Thiazolium and imidazolium hybrid materials were prepared by radical reactions between a mercaptopropyl-modified SBA-15 mesoporous silica and bis-vinylthiazolium or bis-vinylimidazolium dibromide salts. These hybrid materials were characterized by several techniques and were employed in the etherification reaction of 1-phenylethanol. Solvent-free conditions at 160C under different gas phases (oxygen, air, nitrogen and argon) were used. The thiazolium-based material displayed excellent performances. Further studies were carried out using unsupported thiazolium salts, with or without a methyl group at the C-2 position of the thiazolium moiety. These studies allowed us to propose a reaction me…