Search results for "hexamethylguanidinium"

showing 3 items of 3 documents

CCDC 112513: Experimental Crystal Structure Determination

1998

Related Article: H.Meier, M.Buss, M.Adam|1996|Liebigs Ann.||2131|doi:10.1002/jlac.199619961227

Space GroupCrystallographyCrystal SystemCrystal StructureHexamethylguanidinium (E)-3-oxo-23-bis(246-trimethylphenyl)-propenoic acid methyl esterCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 867308: Experimental Crystal Structure Determination

2016

Related Article: I. Tiritiris, W. Kantlehner|2015|Acta Crystallogr.,Sect.E:Cryst.Commun.|71|o1076|doi:10.1107/S2056989015024317

Space GroupCrystallographyCrystal SystemNNN'N'N''N''-Hexamethylguanidinium cyanate sesquihydrateCrystal StructureCell ParametersExperimental 3D Coordinates

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Crystal structure of N,N,N′,N′,N′′,N′′-hexamethylguanidinium cyanate 1.5-hydrate

2015

The title hydrated salt, C7H18N3+·OCN−.1.5H2O, was synthesized starting fromN,N,N′,N′,N′′,N′′-hexamethylguanidinium chloride by a twofold anion-exchange reaction. The asymmetric unit contains two cations, two cyanate anions and three water molecules. One cation shows orientational disorder and two sets of N-atom positions were found related by a 60° rotation, with an occupancy ratio of 0.852 (6):0.148 (6). The C—N bond lengths in both guanidinium ions range from 1.329 (2) to 1.358 (10) Å, indicating double-bond character, pointing towards charge delocalization within the NCN planes. Strong O—H...N hydrogen bonds between the crystal water molecules and the cyanate ions and strong O—H...O hyd…

crystal structureInorganic chemistryCrystal structureIonCrystalchemistry.chemical_compoundsaltGeneral Materials ScienceO—H⋯N hydrogen bondsCrystallographyHydrogen bondhexamethylguanidiniumO—H⋯O hydrogen bondsGeneral ChemistryCondensed Matter PhysicsCyanateHEXAData ReportsO—H...N hydrogen bondsBond lengthCrystallographychemistryQD901-999hexamethylguanidiniumcyanateHydrateO—H...O hydrogen bondsActa Crystallographica Section E: Crystallographic Communications

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