Search results for "humid"
showing 10 items of 334 documents
Calibration of an airborne HO<sub><i>x</i></sub> instrument using the All Pressure Altitude-b…
2020
Abstract. Laser-induced fluorescence (LIF) is a widely used technique for both laboratory-based and ambient atmospheric chemistry measurements. However, LIF instruments require calibrations in order to translate instrument response into concentrations of chemical species. Calibration of LIF instruments measuring OH and HO2 ( HOx ) typically involves the photolysis of water vapor by 184.9 nm light, thereby producing quantitative amounts of OH and HO2 . For ground-based HOx instruments, this method of calibration is done at one pressure (typically ambient pressure) at the instrument inlet. However, airborne HOx instruments can experience varying cell pressures, internal residence times, tempe…
Nanoporous characterization of modified humidity-sensitive MgO-Al 2 O 3 ceramics by positron annihilation lifetime spectroscopy method
2019
The work was supported by the Ukrainian Ministry of Education and Science. H. Klym thanks Prof. O. Shpotyuk for the fruitful discussion.
Heterogeneous Interactions between Gas-Phase Pyruvic Acid and Hydroxylated Silica Surfaces: A Combined Experimental and Theoretical Study
2019
The adsorption of gas-phase pyruvic acid (CH3COCOOH) on hydroxylated silica particles has been investigated at 296 K using transmission Fourier transform infrared (FTIR) spectroscopy and theoretical simulations. Under dry conditions (<1% relative humidity, RH), both the trans-cis (Tc) and trans-trans (Tt) pyruvic acid conformers are observed on the surface as well as the (hydrogen bonded) pyruvic acid dimer. The detailed surface interactions were further understood through ab initio molecular dynamics simulations. Under higher relative humidity conditions (above 10% RH), adsorbed water competes for surface adsorption sites. Adsorbed water is also observed to change the relative populations …
Theoretical study on the decomposition mechanism of bisphenol A polycarbonate induced by the combined effect of humidity and UV irradiation.
2020
Polycarbonate (PC) is a good material for covering and protecting cultural heritage sites because of its durability, mechanical properties, and transparency. When bisphenol A polycarbonate is subjected to weathering conditions this polymer shows several degradation processes depending on the irradiation wavelength, humidity and temperature. In particular, the combined effects of humidity and UV irradiation speed up the PC molecular weight reduction. In this work, the decomposition mechanisms associated to the hydrolysis process are scrutinized and the effects of UV irradiation on the hydrolysis process are evaluated throughout the Density Functional Theory (DFT) approach. It was found that …
Comparison of IAGOS in-situ water vapour measurements and ECMWF ERA-Interim Reanalysis data
2019
Abstract. Cirrus clouds and their potential formation regions, so-called ice-supersaturated regions (ISSRs) occur frequently in the tropopause region. It is assumed that ISSRs and cirrus clouds can change the tropopause structure by diabatic processes, driven by latent heating due to phase transition and interaction with radiation. For many research questions a three-dimensional picture including a sufficient temporal resolution of the water vapour fields in the tropopause region is required. This requirement is fulfilled nowadays by reanalysis products such as the European Centre for Medium-Range Weather Forecasts (ECMWF) ERA-Interim reanalysis. However, for a meaningful investigation of w…
Analysing the effect of land use and vegetation cover on soil infiltration in three contrasting environments in northeast Spain
2017
Este estudio presenta el análisis conjunto de la información obtenida a partir de 195 ensayos de infiltración en el campo, que fueron realizados mediante dispositivos de doble anillo. Los experimentos se realizaron en 20 situaciones contrastadas de usos del suelo, los cuales se encuentran distribuidos en tres contextos geográficos (costa NE de Cataluña, monte bajo del sector central del valle del Ebro y montaña media de la vertiente Sur del Pirineo central). El objetivo de esta investigación es determinar los factores más importantes que explican la variabilidad de la infiltración: uso del suelo, tipo de cubierta vegetal, características del suelo y del substrato rocoso, humedad del suelo y…
Identification of processes that control the stable isotope composition of rainwater in the humid tropical West-Central Africa.
2020
12 pages; International audience; This study interprets 11 years (2006 to 2016) and 6 months (March to August in 2017) of respectively monthly and daily isotopic (δD and δ18O) monitoring of rain at Douala (Cameroon), a humid tropical station in Western Africa. The main scope is to analyze the climate controls on precipitation isotopes at different timescales. Firstly, we examine the annual cycles of δ18O. Over the 11 years of survey, the annual cycle exhibits a W shape that is quite reproducible from year to year, with two minima in spring and autumn periods. Based on back trajectory calculations and remote sensing observations of water vapor isotopic composition, we show that the observed …
Vegetation and climate record from Abric Romaní (Capellades, northeast Iberia) during the Upper Pleistocene (MIS 5d−3)
2019
This study addresses the pollen record of Abric Romani archaeological site and the climate evolution of the last interglacial and glacial stadials in the Iberian Peninsula. The new pollen record spans the interval from 110,000 to 55,000 years ago. In general, the glacial/stadial vegetation is characterized by a steppe and herbaceous communities indicating dry and cold climatic conditions, whereas the vegetation optimum of past interglacials can be described as pine-oaks with mediterranean forest indicating milder and moister climatic conditions. During the first half of the MIS 5a and the MIS 5c, the region was warmer, which is characterized by temperate forests. However, the existence of A…
Paleoclimate and extensional tectonics of short-lived lacustrine environments. Lower Cretaceous of the Panormide Southern Tethyan carbonate platform …
2017
Abstract Subaerial erosion and continental sedimentation interbedded with shallow-water carbonates are unequivocal stratigraphic records to evaluate paleoenvironmental and paleoclimate evolution of emerged landmass. Stratigraphic analysis of the Cretaceous Monte Gallo section of the Mesozoic Panormide carbonate platform, in the northern side of the Palermo Mountains (NW Sicily) records a peculiar continental-derived clays that interrupted the shallow-water carbonate sedimentation. These clays rest, with lenticular geometries, above the tectonically-enhanced subaerial erosional unconformity of the Barremian-Lower Aptian Requienid limestones and are covered by the Upper Cretaceous Rudistid li…
Temporal variations in microclimate cooling induced by urban trees in Mainz, Germany
2016
Abstract Global warming is likely to increase the frequency and magnitude of heat waves. As the urban geometry and material amplifies warming, city dwellers will face an intensification of heat-induced health problems and mortality. Although increased vegetation cover is frequently used in urban planning to mitigate excessive heat, temporal variations, as well as the influence of synoptic weather conditions and surrounding urban geometry on the vegetation cooling effect, are still unclear. In this study, we monitored the transpiration-induced cooling from trees over two summers in five urban settings characterized by varying levels of greenness and urban geometry in the city of Mainz (Germa…