Search results for "hybrides"
showing 9 items of 9 documents
Hybrid ferrocene ligands (P, N) : synthesis, coordination to metals and applications in arylation coupling catalysis
2017
The research theme developed during this thesis concerns the development of new hybrid ferrocene hybrid (P, N) ligands with controlled conformation, robust and stable to air. These hybrid tetradent ligands comprise two types of coordinating functions with distinct steric and electronic properties. Their coordination chemistry with metals such as gold or palladium has been studied and some isolated Au (I) complexes have been used in the arylation coupling catalysis of aryl iodides.
Mechanical characterization of bio-based composite/metal laminates for an application in street furniture
2019
In this work, it is proposed to study the influence of three manufacturing parameters in the development of bio-basedcomposite/steel hybrids. These parameters arethe methodof assembly between composite and metal, the distribution of composite and steellayers throughthe thicknessof the hybrid,and the stacking sequence of the composite part of the hybrid. The study was conducted through impact tests at different energies and quasi-static three-point bending tests. For each of these parameters, the influenceon the mechanical properties of the hybrid is evaluated.The results show that these properties depend essentially on the relative distribution of steel and composite through the thickness.
Elaboration of functionalized nanoparticles : applications as MRI contrast agent
2010
Spinel structured iron oxide nanoparticles open the way of biomedical applications of nanomaterials.Superparamagnetic properties of ten nanometer size crystallites permit to use them in diagnosis such as Magnetic Resonance Imaging (MRI).The aim of this work was to synthesize colloidal suspension of magnetite or maghemite (called USPIO for Ultrasmall SuperParamagnetic Iron Oxide) stable in physiological conditions (pH = 7.4 and [NaCl] = 0.15M).By classical co-precipitation method, UPSIO were synthesized with a mean crystallite size of 8 nm, with a specific surface area of 110 m².g-1 and an aggregate size of 20 nm. To stabilize these nano-objects, two ways were investigated. Electrostatic age…
Iron oxides nanoparticles and titanate nanotubes dedicated to multimodal imaging and anticancer therapy
2013
The new implementations of nanoparticles in the medical field are one of the essential factors of the medical progress expected at the beginning of this XXIst century. Thus, the domain of the medical imaging is also affected by this technological evolution. This work consisted in developing theranostic probes with iron oxides nanoparticles (SPIO) and titanate nanotubes (TiONts) for multimodal imaging (magnetic/nuclear or magnetic/optical) and also possessing a therapeutic effect (hyperthermia/PDT or radiosensitization/PDT).The titanate nanotubes of this study have an average length of about 150 nm and were obtained by Kasuga's hydrothermal synthesis. These nanotubes present an outside diame…
Thermal and hydrothermal ageing of bio-based composite/metal hybrid materials. Application to the development of ultra-light and durable street furni…
2021
In the perspectives of the future city, the progressive use of autonomous vehicles seems to become unavoidable. The preparation of an adequate framework for the deployment of this future mobility represents an important issue. This requires revisiting the urban infrastructures of cities from the choice of material to the design, and to propose solutions based on mobile street furniture. Faced with this challenge, hybrid materials such fibre metal laminates (FML) present interesting characteristics. FML made of plant fibre composites are of particular interest to minimize their environmental impact. Thus, the objective of this thesis is to design and manufacture plant-fibre metal laminates a…
Polyamines and applications. A look at the first workshop in linear and cyclic polyamines chemistry
2008
Given their versatile coordination properties, cyclic and linear polyamines are the subject of numerous worksin many research groups. This great interest is mainly related to their use in diverse fields such as removalof metals from liquids, purification of gases, application in catalysis, in sensors, as well as in various probesfor medical applications. This paper summarizes recent results obtained by the French research groupswhich attended the first ìworkshop in linear and cyclic polyamines chemistryî.
Functionalised Imidazoporphyrins and their application in catalysis
2017
A broad series of functionalized imidazo[4,5-b]porphyrins was synthesized by the acid-catalyzed condensation of 2,3-dioxo-5,10,15,20-tetraarylchlorins with aromatic aldehydes. Both steric and electronic features of meso-aryl substituents influence on the product yield ranging from 18% to 90%.Single-crystal X-ray diffraction analysis of the structure of zinc(II) 5,10,15,20-tetramesityl-2-(4-pyridyl)-1H-imidazo[4,5-b]porphyrinate showed that this compound forms 1D coordination chains in the solid state.The post-synthetic modifications of imidazo[4,5-b]porphyrins were investigated by performing the Suzuki-Miyaura coupling reaction, preparing water-soluble imidazoporphyrins and linear/angular b…
Apprendre à manger. Sémiotique des objets de table pour enfants
2021
The subject of children at the table is related to that of conviviality on two levels. Firstly, at the level of the acquisition of social rules concerning the ways of being at the table, the codes of the meal, the recognition of appropriate behaviour in different contexts (at home, outside, formal, informal, etc.), in short, the "have to". Secondly, at the level of the acquisition of a general know-how, represented by all the somatic behaviours necessary for the consumption of the meal: learning to chew solid food, to drink from a glass, to use cutlery, to handle plates, bowls, soup plates, and so on. In this essay, we will analyse table objects designed for children (glasses, cutlery, plat…
Contribution to thermal behaviour study of lithium-ion battery for electric and hybrid electric vehicle
2014
The main objectives of this study are to provide the essential information on the thermal behaviour of the battery cells for automotive purpose especially for EVs and HEVs through experimental work in order to develop an effective 3D electro-thermal model for lithium ion battery cells and pack. The experimental study is focusing on the distribution of temperature at various points of the battery cell surface, impact of different constant discharge rates, and also the importance of cooling system on the battery temperature behaviour. This thesis highlights the battery cell temperature under abuse discharge condition and the impact of stacking the battery cells inside the battery pack. Impact…