Search results for "hydrogen production"

Hydrogen Production from Methanol-Water Solution and Pure Water Electrolysis Using Nanocomposite Perfluorinated Sulfocationic Membranes Modified by P…

2022

In this work, we report the preparation of Nafion membranes containing two different nanocomposite MF-4SC membranes, modified with polyaniline (PANI) by the casting method through two different polyaniline infiltration procedures. These membranes were evaluated as a polymer electrolyte membrane for water electrolysis. Operating conditions were optimized in terms of current density, stability, and methanol concentration. A study was made on the effects on the cell performance of various parameters, such as methanol concentration, water, and cell voltage. The energy required for pure water electrolysis was analyzed at different temperatures for the different membranes. Our experiments showed …

Electrodeposited nickel–zinc alloy nanostructured electrodes for alkaline electrolyzer

2022

Abstract Over the last decade, as a consequence of the global decarbonization process, the interest towards green hydrogen production has drastically increased. In particular a substantial research effort has focused on the efficient and affordable production of carbon-free hydrogen production processes. In this context, the development of more efficient electrolyzers with low-cost electrode/electrocatalyst materials can play a key role. This work, investigates the fabrication of electrodes of nickel-zinc alloys with nanowires morphology cathode for alkaline electrolyzers. Electrodes are obtained by the simple method of template electrosynthesis that is also inexpensive and easily scalable.…

Recent Developments in Heterogeneous Photoreactor Modelling

1991

A selection of recently proposed heterogeneous photoreactors is presented. In some cases efforts have been made for the formulation of models able to describe the photoreactor behaviour with regard to the absorption of radiation. Examples of proposals of both novel photoreactor and models are critically reviewed.

Catalytic performance of CoAlZn and NiAlZn mixed oxides in hydrogen production by bio-ethanol partial oxidation

2013

CoAlZn and NiAlZn mixed oxides were prepared by sol-gel method and tested in partial oxidation of bio-ethanol (POE). At lower temperatures, CoAlZn showed higher ethanol conversion and higher selectivity to H2 and CO than NiAlZn. At higher temperatures, ethanol conversion on both catalysts reached 100%, while selectivity (S) to H2 and CO became higher on NiAlZn. At 750 C, NiAlZn showed S(H2) of 95%, S(CO) of 90%, while for CoAlZn these values were 90% and 83% respectively. Both catalysts were resistant to coking, but the amount of carbon deposits was still lower on NiAlZn. During 50 h on-stream, ethanol conversion and selectivity to H2 and CO on NiAlZn remained unchanged demonstrating stable…

Highly textured boron/nitrogen co-doped TiO2 with honeycomb structure showing enhanced visible-light photoelectrocatalytic activity

2020

International audience; In this work, we report a novel photocatalyst based on boron and nitrogen co-doped TiO2 rutile (1 1 0) honeycomb structures. The photocatalyst has been prepared by simultaneously oxidizing and doping a Ti-foil substrate at 750 degrees C. The unit cell volume and the crystallite size of grown TiO2 films were measured by Rietveld refinement analysis. The co-doping by boron and nitrogen was achieved simultaneously with the oxidation of the titanium, resulting in a rutile (1 1 0) textured TiO2 film. X-ray photoelectron spectroscopy analysis revealed the presence of Ti-O-N and Ti-O-B-N bonds, and the presence of crystal defects in the lattice was detected and displayed by…

Effect of the TiO2 crystalline structure on the photocatalytic production of hydrogen

2010

Efficient H2 production by photocatalytic water splitting under UV or solar light over variously modified TiO2-based catalysts

2019

Abstract This paper focused for the first time on the comparison between three different approach to modify the chemico-physical properties of TiO2-based photocatalysts and their effect in the H2 production by photocatalytic water splitting both under UV and solar light irradiation, under the same experimental conditions. The application of pulsed laser irradiation to aqueous TiO2 suspensions (first approach) induced structural transformations both on the bulk and on the surface of TiO2, boosting the H2 production, under UV light irradiation, of almost three times (20.9 mmol/gcat·h) compared to bare TiO2 (7.7 mmol/gcat·h). The second strategy was based on a templating method to obtain TiO2 …

Insights into the catalytic production of hydrogen from propane in the presence of oxygen: Cooperative presence of vanadium and gold catalysts

2015

7 figures.-- © 2015. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/

Detoxification of Copper and Chromium via Dark Hydrogen Fermentation of Potato Waste by Clostridium butyricum Strain 92

2022

The accumulation of various types of waste containing both organic and inorganic metal-containing compounds is extremely hazardous for living organisms. The possibility of polymer degradation, biohydrogen synthesis, and metal detoxification via the dark fermentation of model potato waste was investigated. For this purpose, the strict anaerobic strain was isolated and identified as Clostridium butyricum. The high efficiency of dark hydrogen fermentation of potatoes with yield of hydrogen in 85.8 ± 15.3 L kg−1 VSpotato was observed. The copperand chromium salts solutions were added to the culture fluid to obtain the concentrations of 50, 100, and 200 mg L−1 Cu(II) and Cr(VI) in the active pha…

Thermophilic hydrogen production from cellulose with rumen fluid enrichment cultures: Effects of different heat treatments

2011

Elevated temperatures (52, 60 and 65 °C) were used to enrich hydrogen producers on cellulose from cow rumen fluid. Methanogens were inhibited with two different heat treatments. Hydrogen production was considerable at 60 °C with the highest H2 yield of 0.44 mol-H2 mol-hexose -1 (1.93 mol-H2 mol-hexose-degraded-1) as obtained without heat treatment and with acetate and ethanol as the main fermentation products. H2 production rates and yields were controlled by cellulose degradation that was at the highest 21%. The optimum temperature and pH for H2 production of the rumen fluid enrichment culture were 62 °C and 7.3, respectively. The enrichments at 52 and 60 °C contained mainly bacteria from …