Search results for "hyperfine structure"
showing 10 items of 423 documents
ESR, electrochemical and cyclodextrin-inclusion studies of triazolopyridyl pyridyl ketones and dipyridyl ketones derivatives.
2008
Abstract The electron spin resonance (ESR) spectra of free radicals obtained by electrolytic reduction of triazolopyridyl pyridyl ketones and dipyridyl ketones derivatives were measured in dimethylsulfoxide (DMSO). The hyperfine patterns indicate that the spin density delocalization is dependent of the rings presented in the molecule. The electrochemistry of these compounds was characterized using cyclic voltammetry, in DMSO as solvent. When one carbonyl is present in the molecule one step in the reduction mechanism was observed while two carbonyl are present two steps were detected. The first wave was assigned to the generation of the correspondent free radical species, and the second wave…
New approach to describe two coupled spins in a variable magnetic field
2021
We propose a method to describe the evolution of two spins coupled by hyperfine i nteraction in an external time- dependent magnetic field. We apply the approach to the case of hyperfine interaction with axial symmetry, which can be solved exactly in a constant, appropriately oriented magnetic field. In order to t reat t he n onstationary d ynamical p roblem, we modify the time-dependent Schrödinger equation through a change of representation that, by exploiting an instantaneous (adiabatic) basis makes the time-dependent Hamiltonian diagonal at any time instant. The solution of the transformed time-dependent Schrödinger FRVBUJPO in the form of chronologically ordered exponents with transpar…
The hyperfine structure in the rotational spectrum of water: Lamb-dip technique and quantum-chemical calculations
2009
Seven ortho rotational transitions have been recorded for the main isotopic species of water in the mil- limeter- and submillimeter-wave region using the Lamb-dip technique in order to resolve the hyperfine structure due to the hydrogens and to provide accurate hyperfine constants. The experimental determi- nation has been supplemented by high-level quantum-chemical calculations of the hyperfine parameters thereby focusing in particular on a systematic study of the basis-set convergence and on vibrational effects.
The rotational spectrum of trans-DCOOD: Lamb-dip measurements, THz spectroscopy and quantum-chemical calculations
2011
Abstract The rotational spectrum of the bi-deuterated isotopologue of trans-formic acid, trans-DCOOD, was recorded at sub-Doppler resolution in the millimeter- and sub-millimeter-wave region using the Lamb-dip technique. The hyperfine structure due to the deuterium nuclei could be resolved and accurate hyperfine constants were derived. The experimental determination of the deuterium quadrupole-coupling constants was supported by high-level quantum-chemical calculations at the coupled-cluster level using large atomic-orbital basis sets. The Lamb-dip measurements were also supplemented by THz Doppler-limited measurements in order to extend the predictive capability of the available spectrosco…
Rotational spectra of isotopic species of silyl fluoride. Part I: Lamb-dip measurements and quantum-chemical calculations
2010
The Lamb-dip technique has been employed for recording the rotational spectra of three isotopic species of silyl fluoride, namely (28)SiH3F, (29)SiH3F, and (30)SiH3F, in order to improve the knowledge of their spectro- scopic parameters as well as to try to resolve their hyperfine structure. High-level quantum-chemical computations using state-of-the-art coupled-cluster techniques together with core-polarized correla- tion-consistent basis sets have been employed to provide reliable reference values for the hyperfine parameters involved and have been used to guide the experimental investigation. Analysis of the exper- imental spectra allowed to improve the accuracy of the known spectroscopi…
Search for CP-violating nuclear magnetic quadrupole moment using the LuOH+ cation
2020
The time-reversal and spatial parity violating interaction of the nuclear magnetic quadrupole moment (MQM) of the 175Lu and 176Lu nuclei with electrons in the molecular cation LuOH+ is studied. The resulting effect is expressed in terms of fundamental parameters, such as quantum chromodynamics angle θ⎯⎯, quark electric dipole moment (EDM), and chromo-EDM. For this, we have estimated the magnetic quadrupole moments of 175Lu and 176Lu nuclei and calculated the molecular constant that characterizes the interaction of the MQM with electrons in the considered molecules. Additionally, we predict the hyperfine structure constants for the ground electronic state of LuOH+. In the molecular calculati…
Hyperfine mixing in electromagnetic decay of doubly heavy bc baryons
2010
We investigate the role of hyperfine mixing in the electromagnetic decay of ground state doubly heavy bc baryons. As in the case of a previous calculation on b -> c semileptonic decays of doubly heavy baryons, we find large corrections to the electromagnetic decay widths due to this mixing. Contrary to the weak case just mentioned, we find here that one cannot use electromagnetic width relations obtained in the infinite heavy quark mass limit to experimentally extract information on the admixtures in a model independent way.
Splittings of low-lying charmonium masses at the physical point
2019
We present high-precision results from lattice QCD for the mass splittings of the low-lying charmonium states. For the valence charm quark, the calculation uses Wilson-clover quarks in the Fermilab interpretation. The gauge-field ensembles are generated in the presence of up, down, and strange sea quarks, based on the improved staggered (asqtad) action, and gluon fields, based on the one-loop, tadpole-improved gauge action. We use five lattice spacings and two values of the light sea quark mass to extrapolate the results to the physical point. An enlarged set of interpolating operators is used for a variational analysis to improve the determination of the energies of the ground states in ea…
The effect of hyperfine mixing in electromagnetic and semileptonic decays of doubly heavy baryons
2010
We consider the role played by hyperfine mixing in electromagnetic and semileptonic decays of doubly heavy baryons, which give rise to large corrections to the decay widths in both cases.
Exclusive c → s, d Semileptonic Decays of Spin-1/2 and Spin-3/2 cb Baryons
2013
We present results for exclusive semileptonic decay widths of ground state spin-$1/2$ and spin-$3/2$ $cb$ baryons corresponding to a $c\to s, d$ transition at the quark level. The relevance of hyperfine mixing in spin-1/2 $cb$ baryons is shown. Our form factors are compatible with heavy quark spin symmetry constraints obtained in the infinite heavy quark mass limit.