Search results for "hétérogène"
showing 7 items of 7 documents
Dissimilar joining of copper to stainless steel and TA6V to stainless steel by high power beams : understanding and modeling of physicochemical pheno…
2010
The present study is dedicated to the comprehension of the mechanism of materials mixing during dissimilar welding by high power beam sources. We have been interested in joining of two couples of metallic materials which present different metallurgical problems: •copper- stainless steel (miscibility gap, important difference in physical properties);•TA6V- stainless steel (oxidation on air, formation of intermetallic phases which made the joint brittle).For the first couple of materials, continuous laser Nd:YAG welding and electron beam welding have been applied. The experimental study of morphology evolution, composition, microstructure and mechanical properties has allowed establishing the…
Handover management in heterogenous mobile and wireless networks
2015
Since 1990, networking and mobile technologies have made a phenomenal unprecedented progress. This progress has been experienced on multiple fronts in parallel; especially on the application level and the user's needs one. This rapid evolution of the technology imposed a need for the existence of heterogeneous environments where the coverage is ensured throughout the different available networks. The challenge with such architecture would be to provide the user with the ability to navigate through the different available networks in a transparent and seamless fashion. However, the navigation among different types of networks is commonly referred to as vertical Handover. The IEEE 802.21 stan…
Reactivity of arsenic compounds on trapping masses and role of the active phase
2019
The aim of the thesis is to study the reactivity of organic arsenic compounds on various recovery masses and to identify the role of the nature of the active phase and the reaction mechanisms involved. The active phase is composed of metals (Ni, Co, Mo, Cu, Zn, Fe, etc.), pure or in a mixture, in the reduced state or in the sulphide state. The selection of the metallic phases will be carried out by molecular modeling "ab initio", and the synthesis by impregnation of metallic salts on mesoporous aluminas). The reactivity of the solids will be studied in a static reactor on simplified model loads, with kinetic monitoring. The advanced characterization of the solids after synthesis and after r…
Superior Fischer-Tropsch performance of uniform cobalt nanoparticles deposited into mesoporous SiC
2020
Electrochemically-derived well-crystalline mesoporous silicon carbide (pSiC) was used as a host for cobalt nanoparticles to demonstrate superior catalytic performance during the CO hydrogenation according to Fischer-Tropsch. Colloidal Co nanoparticles (9 ± 0.4 nm) were prepared independently using colloidal recipes before incorporating them into pSiC and, for comparison purposes, into commercially available silica (Davisil) as well as foam-like MCF-17 supports. The Co/pSiC catalyst demonstrated the highest (per unit mass) catalytic activity of 117 µmol.g(CO)-1.g-1(Co).s-1 at 220 °C which was larger by about one order of magnitude as compared to both silica supported cobalt catalysts. Furthe…
Functionalised Imidazoporphyrins and their application in catalysis
2017
A broad series of functionalized imidazo[4,5-b]porphyrins was synthesized by the acid-catalyzed condensation of 2,3-dioxo-5,10,15,20-tetraarylchlorins with aromatic aldehydes. Both steric and electronic features of meso-aryl substituents influence on the product yield ranging from 18% to 90%.Single-crystal X-ray diffraction analysis of the structure of zinc(II) 5,10,15,20-tetramesityl-2-(4-pyridyl)-1H-imidazo[4,5-b]porphyrinate showed that this compound forms 1D coordination chains in the solid state.The post-synthetic modifications of imidazo[4,5-b]porphyrins were investigated by performing the Suzuki-Miyaura coupling reaction, preparing water-soluble imidazoporphyrins and linear/angular b…
Modélisation numérique avec apport de matière du soudo-brasage des assemblages hétérogènes acier/aluminium
2007
This study deals with the numerical simulation of heterogeneous brazing of steel / aluminium alloy sheets by CMT process. The difference between the linear expansion coefficients of these materials generates high deformations and residual stress. The addiction of brazing material is simulated. A validation the model is made in the simplest case of a sheet of aluminium alloy with a brazing bead. Comparisons are made between numerical and experimental results on out-of-plane displacements of steel / aluminium assembly.
Etude numérique et expérimentale de l'assemblage acier aluminium par soudo-brasage
2006
Dans cet article nous étudions le soudo-brasage de tôles d'acier et d'aluminium (par la technique CMT, assemblage à clin). Ces métaux ont des coefficients de dilatation thermique différents, ce qui provoque des déformations, d'où des contraintes mécaniques élevées. Des expériences sur des éprouvettes, une simulation numérique thermomécanique sont menées en parallèle afin de mieux comprendre ces aspects thermiques et mécaniques dans le but de minimiser la déformation de l'assemblage.