Search results for "iTED"
showing 10 items of 2408 documents
Strongly Red-Emissive Molecular Ruby [Cr(bpmp)2]3+ Surpasses [Ru(bpy)3]2+
2021
Gaining chemical control over the thermodynamics and kinetics of photoexcited states is paramount to an efficient and sustainable utilization of photoactive transition metal complexes in a plethora of technologies. In contrast to energies of charge transfer states described by spatially separated orbitals, the energies of spin-flip states cannot straightforwardly be predicted as Pauli repulsion and the nephelauxetic effect play key roles. Guided by multireference quantum chemical calculations, we report a novel highly luminescent spin-flip emitter with a quantum chemically predicted blue-shifted luminescence. The spin-flip emission band of the chromium complex [Cr(bpmp)2]3+ (bpmp = 2,6-bis(…
Genetic relationship between five psychiatric disorders estimated from genome-wide SNPs
2013
AM Vicente - Cross-Disorder Group of the Psychiatric Genomics Consortium Most psychiatric disorders are moderately to highly heritable. The degree to which genetic variation is unique to individual disorders or shared across disorders is unclear. To examine shared genetic etiology, we use genome-wide genotype data from the Psychiatric Genomics Consortium (PGC) for cases and controls in schizophrenia, bipolar disorder, major depressive disorder, autism spectrum disorders (ASD) and attention-deficit/hyperactivity disorder (ADHD). We apply univariate and bivariate methods for the estimation of genetic variation within and covariation between disorders. SNPs explained 17-29% of the variance in …
The Roosevelt Years and the Rise of the American Welfare State
2014
The global crisis of multidrug resistance: how to face healthcare associated infections without effective antibiotics?
2013
[No abstract available
Lyapunov dimension formula for the global attractor of the Lorenz system
2016
The exact Lyapunov dimension formula for the Lorenz system for a positive measure set of parameters, including classical values, was analytically obtained first by G.A. Leonov in 2002. Leonov used the construction technique of special Lyapunov-type functions, which was developed by him in 1991 year. Later it was shown that the consideration of larger class of Lyapunov-type functions permits proving the validity of this formula for all parameters, of the system, such that all the equilibria of the system are hyperbolically unstable. In the present work it is proved the validity of the formula for Lyapunov dimension for a wider variety of parameters values including all parameters, which sati…
On lower-bound estimates of the Lyapunov dimension and topological entropy for the Rossler systems
2019
In this paper, on the example of the Rössler systems, the application of the Pyragas time-delay feedback control technique for verification of Eden’s conjecture on the maximum of local Lyapunov dimension, and for the estimation of the topological entropy is demonstrated. To this end, numerical experiments on computation of finite-time local Lyapunov dimensions and finite-time topological entropy on a Rössler attractor and embedded unstable periodic orbits are performed. The problem of reliable numerical computation of the mentioned dimension-like characteristics along the trajectories over large time intervals is discussed. peerReviewed
Nonlinear higher-order polariton topological insulator
2020
We address the resonant response and bistability of the exciton-polariton corner states in a higher-order nonlinear topological insulator realized with kagome arrangement of microcavity pillars. Such states are resonantly excited and exist due to the balance between pump and losses, on the one hand, and between nonlinearity and dispersion in inhomogeneous potential landscape, on the other hand, for pump energy around eigen-energies of corresponding linear localized modes. Localization of the nonlinear corner states in a higher-order topological insulator can be efficiently controlled by tuning pump energy. We link the mechanism of corner state formation with symmetry of the truncated kagome…
The first large-scale shell-model calculation of the two-neutrino double beta decay of $^{76}$Ge to the excited states in $^{76}$Se
2022
Large-scale shell-model calculations were carried out for the half-lives and branching ratios of the $2\nu\beta\beta$ decay of $^{76}$Ge to the ground state and the lowest three excited states $2_1^+$, $0_2^+$ and $2_2^+$ in $^{76}$Se. In total, the wave functions of more than 10,000 intermediate $1^+$ states in $^{76}$As were calculated in a three-step procedure allowing an efficient use of the available computer resources. In the first step, 250 lowest states, below some 5 MeV of excitation energy, were calculated without truncations within a full major shell $0f_{5/2}-1p-0g_{9/2}$ for both protons and neutrons. The wave functions of the rest of the states, up to some 30 MeV, were compute…
Lifetime measurements of excited states in $^{162}$W and $^{164}$W and the evolution of collectivity in rare-earth nuclei
2017
International audience; Lifetimes of the first excited 2+ states in the extremely neutron-deficient $^{162}$W and $^{164}$W nuclei have been measured using the recoil distance Doppler shift technique. Experimental B(E2) data for the isotopic chains of hafnium, tungsten, and osmium, from the midshell region near the β-stability line towards the N=82 closed shell and the most neutron-deficient nuclides, are compared with predictions of nuclear deformations and 21+→0g.s.+ reduced transition strengths from different classes of state-of-the-art theoretical model calculations. The results reveal striking differences and deficiencies in the predictive power of current nuclear structure models.
Lifetime measurements in 166Re : Collective versus magnetic rotation
2016
Lifetimes of excited states in the neutron-deficient odd-odd nucleus 166Re have been measured for the first time using the recoil distance Doppler-shift method. The measured lifetime for the (8−) state; τ = 480 (80) ps, enabled an assessment of the multipolarities of the γ rays depopulating this state. Information on electromagnetic transition strengths were deduced for the γ -ray transitions from the (9−), (10−), and (11−) states, and in the case of the (10−) and (11−) states limits on the B(M1) and B(E2) strengths were estimated. The results are compared with total Routhian surface predictions and semiclassical calculations. Tilted-axis cranking calculations based on a relativistic mean-f…