Search results for "iTED"
showing 10 items of 2408 documents
Hard-X-ray-induced excited-spin-state trapping.
2007
Shine bright or live long: substituent effects in [Cu(N^N)(P^P)]+-based light-emitting electrochemical cells where N^N is a 6-substituted 2,2'-bipyri…
2016
We report [Cu(P^P)(N^N)][PF6] complexes with P^P = bis(2-(diphenylphosphino)phenyl)ether (POP) or 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene (xantphos) and N^N = 6-methyl-2,2′-bipyridine (Mebpy), 6-ethyl-2,2′-bipyridine (Etbpy), 6,6′-dimethyl-2,2′-bipyridine (Me2bpy) or 6-phenyl-2,2′-bipyridine (Phbpy). The crystal structures of [Cu(POP)(Phbpy)][PF6]·Et2O, [Cu(POP)(Etbpy)][PF6]·Et2O, [Cu(xantphos)(Me2bpy)][PF6], [Cu(xantphos)(Mebpy)][PF6]·CH2Cl2·0.4Et2O, [Cu(xantphos)(Etbpy)][PF6]·CH2Cl2·1.5H2O and [Cu(xantphos)(Phbpy)][PF6] are described; each copper(I) centre is distorted tetrahedral. In the crystallographically determined structures, the N^N domain in [Cu(xantphos)(Phbpy)]+ and [Cu(…
The global economic crisis as a critical Juncture? The crisis's impact on migration movements and policies in Europe and the US
2016
The current global economic crisis has resulted in the strongest recession in the Organisation for Economic Cooperation and Development (OECD) countries since the Great Depression in the early 1930s and the 1970s oil shocks. This special issue sets out to explore how the most recent economic crisis impacted immigration and immigration-related policy in the United States of America and in European countries that are part of the OECD. The crisis of the late 2000s was offset by the collapse of the subprime US housing market, destabilising the financial system and leading to a sovereign debt crisis. The shock was marked by a “sudden […] deterioration of most, or all, key macroeconomic indicator…
Developments for resonance ionization laser spectroscopy of the heaviest elements at SHIP
2016
Abstract The experimental determination of atomic levels and the first ionization potential of the heaviest elements ( Z ⩾ 100 ) is key to challenge theoretical predictions and to reveal changes in the atomic shell structure. These elements are only artificially produced in complete-fusion evaporation reactions at on-line facilities such as the GSI in Darmstadt at a rate of, at most, a few atoms per second. Hence, highly sensitive spectroscopic methods are required. Laser spectroscopy is one of the most powerful and valuable tools to investigate atomic properties. In combination with a buffer-gas filled stopping cell, the Radiation Detected Resonance Ionization Spectroscopy (RADRIS) techniq…
Application of WGM Resonances to the Measurement of the Temperature Increment of Ho and Ho-Yb Doped Optical Fibers Pumped at 1125 and 975 nm
2021
Optical fiber characterization using whispering gallery mode resonances of the fiber itself has been demonstrated to be a powerful technique. In this work, we exploit the thermal sensitivity of whispering gallery mode resonances to characterize the pump-induced temperature increment in holmium doped and holmium-ytterbium codoped optical fibers. The technique relies on the measurement of the resonances’ wavelength shift due to temperature variation as a function of the pump power. Holmium doped fibers were pumped to the second excited level 5I6 of the Ho3+ ion using a laser diode at 1125 nm and ytterbium-holmium codoped fibers to the 2F5/2 level of the Yb3+ ion by a laser diode at 975 nm. Ou…
Sulfur Dioxide Oxidation Catalyzed by Photosensitized Ytterbium Diphthalocyanine
2008
Oxidation of SO2 into SO3 was found effectively catalyzed by photosensitized ytterbium diphthalocyanine, YbPc2 (Pc = phthalocyanine ligand, C32H16N8) when performed in air-saturated dimethylformamide (DMF) solution at 20 °C. The process follows according to a multi-step complex mechanism involving chemical induction as its driving force. Excitation energy of the sandwich molecular system in YbPc2 is used to promote the reaction by creating a reactive intermediate form of the ytterbium complex hosting up to eight SO2 molecules. The conversion of SO2 proved complete.
Effect of thermocycling with or without 1 year of water storage on retentive strengths of luting cements for zirconia crowns
2015
Abstract Statement of problem Bond stability between zirconia crowns and luting cement and between cement and dentin is a main concern; however, only limited evidence is available as to its longevity. Purpose The purpose of this in vitro study was to measure the retentive strengths of 7 self-adhesive cements (RelyX Unicem Aplicap, RelyX Unicem Clicker, RelyX Unicem 2 Automix, iCEM, Maxcem Elite, Bifix SE, SpeedCem), 2 adhesive cements with self-etch primers (Panavia 21, SEcure), 1 glass ionomer cement (Ketac Cem), 1 resin-modified glass ionomer cement (Meron Plus), and 1 zinc phosphate cement for luting zirconia crowns (LAVA) to extracted teeth after thermocycling with or without 1 year of …
Transient collisionally excited X-ray laser in nickel-like zirconium pumped with the PHELIX laser facility
2004
A transient collisionally excited X-ray laser has been put into operation using the front end of the PHELIX laser system as a pump laser. Strong lasing at 22 nm has been observed in nickel-like zirconium.
Charles Darwin and the Origin of Life
2009
When Charles Darwin published The Origin of Species 150 years ago he consciously avoided discussing the origin of life. However, analysis of some other texts written by Darwin, and of the correspondence he exchanged with friends and colleagues demonstrates that he took for granted the possibility of a natural emergence of the first life forms. As shown by notes from the pages he excised from his private notebooks, as early as 1837 Darwin was convinced that “the intimate relation of Life with laws of chemical combination, & the universality of latter render spontaneous generation not improbable”. Like many of his contemporaries, Darwin rejected the idea that putrefaction of preexisting organ…
Experimental and numerical enhancement of Vibrational Resonance in a neural circuit
2012
International audience; A neural circuit exactly ruled by the FitzHugh-Nagumo equations is excited by a biharmonic signal of frequencies f and F with respective amplitudes A and B. The magnitude spectrum of the circuit response is estimated at the low frequency driving f and presents a resonant behaviour versus the amplitude B of the high frequency. For the first time, it is shown experimentally that this Vibrational Resonance effect is much more pronounced when the two frequencies are multiple. This novel enhancement is also confirmed by numerical predictions. Applications of this nonlinear effect to the detection of weak stimuli are finally discussed.