Search results for "iTED"

High resolution study of the six lowest doubly excited vibrational states of PH2D

2005

Abstract The five lowest doubly excited deformational vibrational bands ν 4  +  ν 6 , 2 ν 6 , ν 3  +  ν 4 , ν 3  +  ν 6 , and 2 ν 3 of PH 2 D have been recorded for the first time using a Bruker 120 HR interferometer with a resolution 0.0033 cm −1 and analysed. Some transitions belonging to a very weak band 2 ν 4 have been also assigned. From the fit 24 and 86, respectively, diagonal and resonance interaction parameters were obtained which reproduce 1089 upper energy levels obtained from more than 4600 assigned transitions with the rms deviation of 0.00059 cm −1 .

On the Study of the Very High Excited Vibrational Levels of the Pyramidal Molecules

2006

Analysis of highly excited 'hot' bands in the SO2 molecule: ν2 + 3ν3 - ν2 and 2ν1 + ν2 + ν3 - ν2

2010

International audience; We set up a variational procedure of assignments of transitions and we applied it to the analysis very weak 'hot' bands, v(2) + 3v(3) - v(2) and 2v(1) + v(2) + v(3) - v(2), of the SO2 molecule. As the first step of the study, the 'cold' bands, 3v(3) and 2v(1) + v(3), are re-analysed and transitions belonging to those bands are assigned up to the values of quantum numbers J(max.) = 60, K-a(max.) = 19, and J(max.) = 69, K-a(max.) = 20 for the bands 3v(3) and 2v(1) + v(3), respectively. After 'cleaning' the experimental spectrum from transitions belonging to the 3v(3) and 2v(1) + v(3) bands, a variational procedure was used that allowed us to assign 230 and 115 transiti…

Speed-accuracy trade-off and its consequences in a scramble competition context.

2014

Abstract: Animals foraging in groups commonly respond to the presence of others by increasing their foraging rate, an increase that could come at the expense of prey detection accuracy. Yet the existence and consequences of such so-called 'speed-accuracy trade-offs' in group-foraging animals remain unexplored. We used group-feeding zebra finches, Taeniopygia guttata, to determine how search speed affects food detection accuracy and how a potential speed-accuracy trade-off influences feeding success. We found significant between-individual differences in hopping speed as well as evidence that faster individuals were more likely to overlook food, demonstrating the existence of a trade-off bet…

Towards Iron(II) Complexes with Octahedral Geometry: Synthesis, Structure and Photophysical Properties

2020

The control of ligand-field splitting in iron (II) complexes is critical to slow down the metal-to-ligand charge transfer (MLCT)-excited states deactivation pathways. The gap between the metal-centered states is maximal when the coordination sphere of the complex approaches an ideal octahedral geometry. Two new iron(II) complexes (C1 and C2), prepared from pyridylNHC and pyridylquinoline type ligands, respectively, have a near-perfect octahedral coordination of the metal. The photophysics of the complexes have been further investigated by means of ultrafast spectroscopy and TD-DFT modeling. For C1, it is shown that&mdash

Presentations of constrained systems with unconstrained positions

2005

International audience; We give a polynomial-time construction of the set of sequences that satisfy a finite-memory constraint defined by a finite list of forbidden blocks, with a specified set of bit positions unconstrained. Such a construction can be used to build modulation/error-correction codes (ECC codes) like the ones defined by the Immink-Wijngaarden scheme in which certain bit positions are reserved for ECC parity. We give a lineartime construction of a finite-state presentation of a constrained system defined by a periodic list of forbidden blocks. These systems, called periodic-finite-type systems, were introduced by Moision and Siegel. Finally, we present a linear-time algorithm for con…

Generation of a 160-GHz transform-limited pedestal-free pulse train through multiwave mixing compression of a dual-frequency beat signal.

2002

International audience; We report the experimental generation of a 160-GHz picosecond pulse train at 1550 nm, using multiple four-wave mixing temporal compression of an initial dual-frequency beat signal in the anomalous-dispersion regime of a nonzero dispersion-shifted fiber. Complete intensity and phase characterizations of the pulse train were carried out by means of a frequency-resolved optical gating technique, showing that 1.27-ps transform-limited pedestal-free Gaussian pulses were generated.

On the possibility of observing bound soliton pairs in a "wave-breaking-free" mode-locked fiber laser

2007

To generate ultrashort pulses with higher energy in passively mode-locked fiber lasers, several groups have recently focused on the development of laser cavities operating in normal path-averaged dispersion, with a view to achieve wave-breaking-free operation. The mode-locking mechanism in fiber laser play a key role in providing scalability limitation: for instance, nonlinear polarization evolution can be overdriven. Furthermore, the differential gain of the doped fiber decreases along with the traveled distance. From all of these limitations, it follows that power scalability is always bounded for virtually any mode-locked laser cavity design. In general, the consequence is the emergence …

Stabilisation of modelocking in fibre ring laser through pulse bunching

2001

Bunching of equally spaced pulses is reported to be the most stable mode of operation in a passively modelocked fibre ring laser. The ring includes dispersion management, which results in the absence of strict pulse energy quantisation, giving pulse bunching a better immunity to environmental perturbation.

Wavelength conversion and temporal compression of a pulse train using a dispersion oscillating fiber

2014

International audience; We demonstrate the generation of a picosecond pulse train taking advantage of the cross gain occurring in a dispersion oscillating fibre. The resulting frequency-converted signal is detuned by more than 20 nm from the pump and can be temporally compressed by a factor 2 compared to the input sinusoidal pump wave.