Search results for "icp-m"
showing 10 items of 71 documents
Nuevos desarrollos de la espectroscopia para el análisis mineral de alimentos
2017
El trabajo recopilado en la siguiente Tesis Doctoral está basado en el desarrollo de nuevas metodologías para la determinación de elementos minerales en distintos alimentos y dietas, siguiendo los principios de la “Química Verde”: rapidez, bajo coste, simplicidad y respeto por el medio ambiente. Esta Tesis se ha realizado acogiéndose a la modalidad “compendio de publicaciones”, contemplada en el Reglamento de la Universidad de Valencia de 28/16/2016 (ACGUV 172/2016) y se ha dividido en dos secciones: la sección I, que incluye un resumen global de la temática, resumen de los principales resultados obtenidos, así como las conclusiones finales. A continuación, en la sección II se incluyen los …
Corundum Anorthosites-Kyshtymites from the South Urals, Russia: A Combined Mineralogical, Geochemical, and U-Pb Zircon Geochronological Study
2019
Kyshtymites are the unique corundum-blue sapphire-bearing variety of anorthosites of debatable geological origin found in the Ilmenogorsky-Vishnevogorsky complex (IVC) in the South Urals, Russia. Their mineral association includes corundum-sapphire, plagioclase (An61&ndash
Solid phase extraction materials as a key for improving the accuracy of silver nanoparticle characterization with single-particle inductively coupled…
2022
The accurate characterization of silver nanoparticles (Ag NPs) in environmental samples is crucial for understanding the potential impact of these materials on the environment and human health. Single-particle inductively coupled plasma mass spectrometry (spICP-MS) is one of the few techniques available for quantifying NPs at environmentally relevant concentrations. However, the spICP-MS detection of Ag NPs can be interfered with coexisting dissolved analyte causing high background signals, which mask NP signals leading to a significant bias in NP characterization. In this paper, a simple sample pre-treatment procedure for efficient removal of dissolved silver in natural waters is proposed …
Hiilen taustavaikutukset muovien lisäaineille induktiivisesti kytketyssä plasmassa
2017
Tässä tutkielmassa tarkasteltiin hiilen matriisivaikutuksia induktiivisesti kytkettyä plasmaa (ICP) hyödyntävissä analyysimenetelmissä. Kirjallisessa osassa on tarkasteltu erilaisia kiinteiden näytteiden esikäsittelymenetelmiä kiinnittäen huomiota jäännöshiilimääriin. Lisäksi läpi käydään ICP-tekniikoiden teoriaa, laitteistoa ja häiriöitä, painotuksen ollessa hiilen aiheuttamissa ongelmatekijöissä. Kokeellisessa osassa tutkittiin onko hiilellä merkittäviä vaikutuksia muovien hivenaineille (As, Cd, Cr, Pb, Sb, Sn, Zn, S) sellaisissa pitoisuuksissa, joita jäännöshiilipitoisuudelta voidaan odottaa kiinteiden näytteiden esikäsittelyn jälkeen. Jäljitellen sertifioituja muovimateriaaleja valmiste…
Bedrock and soil geochemistry influence the content of chemical elements in wild edible mushrooms (Morchella group) from South Italy (Sicily)
2019
Chemical elements in the samples of wild edible mushrooms of the <em>Morchella</em> group collected from different unpolluted Sicilian sites was analyzed by the ICP-MS (method) to detect the content of their minerals and determine whether soil geology and geochemistry can influence the chemical composition in fungi. Results showed that the mushroom samples mainly contained a high concentration of K and P and a wide variety of minor and trace elements (V, Mo, Pb, Ce, Cs, Zr), including heavy metals. Statistical analysis showed that the mushrooms differed in their content of minor and trace elements based on the geological/geographic site of origin. Comparison with other studies s…
Indirect chronology method employing rare earth elements to identify Sagunto Castle mortar construction periods
2017
A novel indirect chronology method has been developed to identify Sagunto Castle construction periods. The method is based on the use of inductively coupled plasma mass spectrometry (ICP-MS) to determine rare earth elements (REE) and other trace elements in mortars. Additionally, a no destructive geochemical analysis based on X-ray fluorescence (XRF) was employed for major elements determination. Collected chemical data were processed through Principal Component Analysis (PCA) to highlight any differences among the mortars belonging to different buildings and construction periods. The results show that PCA analysis permits to discriminate construction periods according to mortar sample REE …
Cēlmetālu piemaisījumu analīze un uzkrāšanās cēloņi tritiju ģenerējošā keramikā
2017
Cēlmetālu piemaisījumu analīze un uzkrāšanās cēloņi tritiju ģenerējošā keramikā. Valtenbergs O., zinātniskais vadītājs: profesors, Dr. chem. Vīksna A., zinātniskais konsultants: pētnieks, MSc. chem. Zariņš A. Maģistra darbs, 40 lappuses, 27 attēli, 6 tabulas, 31 literatūras avots, 4 pielikumi. Latviešu valodā. Literatūras apskatā ir izklāstīta galvenā informācija par kodoltermisko sintēzi un eksperimentālo reaktoru (International Thermonuclear Experimental Reactor – ITER), kā arī tā testa blanketa moduļiem, tritija ģenerējošo keramiku un pētījumam izmantotajām analīzes metodēm. Ar dažādām analīzes metodēm, eksperimentāli tika analizētas modificētās litija ortosilikāta (Li4SiO4) minilodītes …
Analytical method for metal distribution in the organic and inorganic fractions of sediment: a case-study on sedimento f Ganzirri marine coastal lago…
2008
Western mediterranean archaeology: chemical element levels in archaeological materials as a methodological tool
2014
Una línea de desarrollo de las investigaciones arqueométricas, objeto de nuestro estudio, que presenta un amplia gama de potenciales aplicaciones metodológicas, al día de hoy conocidas solo en parte, es el análisis de los elementos químicos metálicos y no metálicos, ya sean los elementos mayoritarios, los elementos trazas y, más recientemente, los conocidos como “tierras raras” (por su nombre en inglés, Rare Earth Elements - REEs), que se han revelado útiles en nuestro estudio para la solución de algunos problemas arqueológicos. La posibilidad de poder actuar de forma sistemática, ha ayudado, por un lado, a conocer y desarrollar el potencial de estos elementos y, por otro, ha servido de sop…
Caractérisation des céramiques à bioclastes de la Protohistoire dans l’ouest de la France.
2015
The study of the ceramics from the site of the Batterie Basse in the region of Manche, shows again that the presence of bioclasts in the clays of protohistoric ceramics is a very common phenomenon in Normandy unlike in Brittany, where in the current state of knowledge only one individual from the Iron Age has been described. These bioclasts, mostly fragments of bivalves, are non-plastic elements naturally present in the clays, either in the form of fossils, either in the form of contemporary shells, or are incorporated by the craftsmans after being pounded to modify the technical characteristics of the clays. The aim of this work is to awareness the archaeologists to this type of artefacts …