Search results for "imidazol-2-ylidene"

showing 10 items of 103 documents

Dibromido[N-(1-diethylamino-1-oxo-3-phenylpropan-2-yl)-N′-(pyridin-2-yl)imidazol-2-ylidene]palladium(II) dichloromethane monosolvate

2019

In the molecule of the title N,N′-disubstituted imidazol-2-ylidene palladium(II) complex, [PdBr2(C21H24N4O)]·CH2Cl2, the palladium(II) atom adopts a slightly distorted square-planar coordination (r.m.s. deviation = 0.0145 Å), and the five-membered chelate ring is almost planar [maximum displacement = 0.015 (8) Å]. The molecular conformation is enforced by intramolecular C—H...Br hydrogen bonds. In the crystal, complex molecules and dichloromethane molecules are linked into a three-dimensional network by C—H...O and C—H...Br hydrogen bonds.

crystal structureHydrogen bondchemistry.chemical_element02 engineering and technologyGeneral MedicineCrystal structure010402 general chemistry021001 nanoscience & nanotechnologyRing (chemistry)palladium01 natural sciencesMedicinal chemistryMethane0104 chemical scienceschemistry.chemical_compoundchemistrylcsh:QD901-999Chelationlcsh:Crystallography0210 nano-technologyMaximum displacementimidazol-2-ylidenePalladiumIUCrData
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CCDC 1955879: Experimental Crystal Structure Determination

2020

Related Article: Jens Oberkofler, Brech Aikman, Riccardo Bonsignore, Alexander Pöthig, James Platts, Angela Casini, Fritz E. Kühn|2020|Eur.J.Inorg.Chem.|2020|1040|doi:10.1002/ejic.201901043

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(33-dimethylbut-1-yn-1-yl)-[13-di-isopropylbenzimidazol-2-ylidene]-gold(i)Experimental 3D Coordinates
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CCDC 968510: Experimental Crystal Structure Determination

2013

Related Article: Filippo Monti, Florian Kessler, Manuel Delgado, Julien Frey, Federico Bazzanini, Gianluca Accorsi, Nicola Armaroli, Henk J. Bolink, Enrique Ortí, Rosario Scopelliti, Md. Khaja Nazeeruddin, and Etienne Baranoff|2013|Inorg.Chem.|52|10292|doi:10.1021/ic400600d

(11'-methylenebis(3-methyl-imidazol-2-ylidene))-bis(2-phenylpyridine)-iridium hexafluorophosphate dichloromethane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1436326: Experimental Crystal Structure Determination

2016

Related Article: Jacob Fernández-Gallardo, Benelita T. Elie, Mercedes Sanaú, María Contel|2016|Chem.Commun.|52|3155|doi:10.1039/C5CC09718E

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersdichloro-(13-dimesityl-23-dihydro-1H-imidazol-2-ylidene)-(mu-((diphenylphosphino)methyl)(diphenyl)phosphine)-(1-isopropyl-4-methylbenzene)-ruthenium-gold perchlorate dichloromethane solvateExperimental 3D Coordinates
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CCDC 719664: Experimental Crystal Structure Determination

2010

Related Article: J.L.Dutton, H.M.Tuononen, P.J.Ragogna|2009|Angew.Chem.,Int.Ed.|48|4409|doi:10.1002/anie.200901495

bis(13-Di-isopropyl-45-dimethylimidazol-2-ylidene)-tellurium(ii) bis(trifluoromethanesulfonate)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1952095: Experimental Crystal Structure Determination

2020

Related Article: Xueer Zhou, Petra Vasko, Jamie Hicks, M. Ángeles Fuentes, Andreas Heilmann, Eugene L. Kolychev, Simon Aldridge|2020|Dalton Trans.|49|9495|doi:10.1039/D0DT01960G

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-bromo)-bis(1-(2-(t-butylamido)ethyl)-3-mesitylimidazol-2-ylidene)-di-germanium tetrakis(tris(trifluoromethyl)methoxy)-aluminiumExperimental 3D Coordinates
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CCDC 1485045: Experimental Crystal Structure Determination

2016

Related Article: Elena A. Giner, Alicia Santiago, Mar Gómez-Gallego, Carmen Ramírez de Arellano, Rebecca C. Poulten, Michael K. Whittlesey, and Miguel A. Sierra|2015|Inorg.Chem.|54|5450|doi:10.1021/acs.inorgchem.5b00492

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterspentacarbonyl-(3-(13-dimesityl-13-dihydro-2H-imidazol-2-ylidene)-1-ethoxy-3-phenylprop-1-en-1-yl)-chromium hexafluorophosphate chloroform solvateExperimental 3D Coordinates
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CCDC 722582: Experimental Crystal Structure Determination

2010

Related Article: J.L.Dutton, H.M.Tuononen, P.J.Ragogna|2009|Angew.Chem.,Int.Ed.|48|4409|doi:10.1002/anie.200901495

Space GroupCrystallographyCrystal SystemCrystal Structuretetrakis(13-Di-isopropyl-45-dimethylimidazol-2-ylidene)-tellurium(ii) bis(trifluoromethanesulfonate) tetrahydrofuran solvateCell ParametersExperimental 3D Coordinates
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CCDC 1861476: Experimental Crystal Structure Determination

2018

Related Article: Chris Gendy, Akseli Mansikkamäki, Juuso Valjus, Joshua Heidebrecht, Paul Chuk-Yan Hui, Guy M. Bernard, Heikki M. Tuononen, Roderick E. Wasylishen, Vladimir K. Michaelis, Roland Roesler|2019|Angew.Chem.,Int.Ed.|58|154|doi:10.1002/anie.201809889

Space GroupCrystallographyCrystal SystemCrystal Structure(11'-(propane-13-diyl)bis(3-t-butyl-imidazol-2-ylidene))-(cycloocta-15-diene)-nickel(0)Cell ParametersExperimental 3D Coordinates
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CCDC 1873193: Experimental Crystal Structure Determination

2019

Related Article: Marco Monticelli, Marco Baron, Cristina Tubaro, Stéphane Bellemin-Laponnaz, Claudia Graiff, Gregorio Bottaro, Lidia Armelao, and Laura Orian|2019|ACS Omega|4|4192|doi:10.1021/acsomega.8b03668

Space GroupCrystallographyCrystal SystemCrystal Structurebis(3-methyl-1-phenyl-5-[3-(3-methylimidazol-2-ylidene-1-yl)propyl]-1H-123-triazol-3-ium)-palladium bis(hexafluorophosphate) acetonitrile solvateCell ParametersExperimental 3D Coordinates
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