Search results for "instability"
showing 10 items of 724 documents
The Instability of Ni{N(SiMe3 )2 }2 : A Fifty Year Old Transition Metal Silylamide Mystery.
2015
The characterization of the unstable Ni(II) bis(silylamide) Ni{N(SiMe3 )2 }2 (1), its THF complex Ni{N(SiMe3 )2 }2 (THF) (2), and the stable bis(pyridine) derivative trans-Ni{N(SiMe3 )2 }2 (py)2 (3), is described. Both 1 and 2 decompose at ca. 25 °C to a tetrameric Ni(I) species, [Ni{N(SiMe3 )2 }]4 (4), also obtainable from LiN(SiMe3 )2 and NiCl2 (DME). Experimental and computational data indicate that the instability of 1 is likely due to ease of reduction of Ni(II) to Ni(I) and the stabilization of 4 through dispersion forces.
Competition between the buckling-driven delamination and wrinkling in compressed thin coatings
2012
Abstract The competition between two common failure modes of a thin coating under in-plane compression, the surface wrinkling and the buckling-driven delamination, is studied to assess the critical strain when the mechanical instability may occur at given geometrical and material parameters. A buckling map is constructed based on results of a finite element analysis, which relates the critical applied strain for the onset of instability to the interface adhesion and elastic properties of materials. An approximate scaling relation is derived for the energy release rate of buckling-driven delamination of a coating deposited on a compliant substrate.
Extreme sensitivity of superconductivity to stoichiometry in Fe1+?Se
2009
The recently discovered iron arsenide superconductors appear to display a universal set of characteristic features, including proximity to a magnetically ordered state and robustness of the superconductivity in the presence of disorder. Here we show that superconductivity in Fe1+?Se, which can be considered the parent compound of the superconducting arsenide family, is destroyed by very small changes in stoichiometry. Further, we show that nonsuperconducting Fe1+?Se is not magnetically ordered down to 5 K. These results suggest that robust superconductivity and immediate instability against an ordered magnetic state should not be considered as intrinsic characteristics of iron-based superco…
Vortex instability and vortex-glass transition in Bi 2 Sr 2 CaCu 2 O 8 and YBa 2 Cu 3 O 7 thin films
2000
We investigated the current-voltage (I-V) curves of high-T c superconductors at very low and very high dissipation levels. In the limit of low driving currents the barriers for vortex movement become infinite in the vortex-glass state. Using long measurement bridges up to 0.5 m we were able to sample an electric field range from 1 V/m down to 10 -8 V/m in one experimental setup. The resulting I-V curves allowed us to verify an excellent glass scaling of the I-V curves, which revealed an increased dynamical exponent of the glass transition. We also found a considerable dependence of the vortex-glass scaling on the probed electric-field range. At very high dissipation levels the I-V curves of…
Origin of the fast magnetization relaxation at low temperatures in HTS with strong pinning
2010
The temperature T variation of the normalized magnetization relaxation rate S in high-temperature superconductors (HTS) with strong vortex pinning exhibits a maximum in the low-T range. This was reported for various HTS, and the origin of the faster relaxation at low T appearing in standard magnetization relaxation measurements was usually related to specific pinning properties of the investigated specimens. Since the observed behaviour seems to be characteristic to all HTS with enhanced pinning (generated by random and/or correlated disorder), we show that the S(T) maximum can be explained in terms of classic collective vortex creep. The influence of thermo-magnetic instabilities in the lo…
Force-free state in a superconducting single crystal and angle-dependent vortex helical instability
2017
Superconducting 2H-NbSe2 single crystals show intrinsic low pinning values. Therefore, they are ideal materials with which to explore fundamental properties of vortices. (V, I) characteristics are the experimental data we have used to investigate the dissipation mechanisms in a rectangular shape 2H-NbSe2 single crystal. Particularly, we have studied dissipation behavior with magnetic fields applied in the plane of the crystal and parallel to the injected currents, i.e. in the force-free state where the vortex helical instability governs the vortex dynamics. In this regime, the data follow the elliptic critical state model and the voltage dissipation shows an exponential dependence.Moreover,…
Irreversibility of the threshold field for dendritic flux avalanches in superconductors
2010
Hysteretic effects are seen in the upper and lower threshold fields for the appearance of dendritic flux instabilities, first explained in Yurchenko et al. [Phys. Rev. B 76 (2007) 092504], in NbN-films. We have measured the threshold fields at increasing and decreasing applied fields at different temperatures and proposed a mechanism explaining how the hysteresis arises by analyzing the field profiles inside the sample.
Instabilities in heavy-fermion systems
1992
Abstract We review (i) an itinerant antiferromagnetic phase transition below 4 K in Ni-rich Ce(Cu 1− x Ni x ) 2 Ge 2 systems, (ii) the coincidence at T = 0.63 K of both a structural lattice instability in “as-grown” (non-superconducting) CeCu 2 Si 2 single crystals and bulk superconductivity in annealed ones as well as (iii) antiferromagnetic and superconducting transitions at T N = 4.6 K and T c = 1 K, respectively, in the heavy-fermion compound UNi 2 Al 3 .
Reentrant stability of superconducting films and the vanishing of dendritic flux instability
2007
We propose a mechanism responsible for the abrupt vanishing of the dendritic flux instability found in many superconducting films when an increasing magnetic field is applied. The onset of flux avalanches and the subsequent reentrance of stability in NbN films were investigated using magneto-optical imaging, and the threshold fields were measured as functions of critical current density ${j}_{c}$. The results are explained with excellent quantitative agreement by a thermomagnetic model published recently [D. V. Denisov et al., Phys. Rev. B 73, 014512 (2006)], showing that the reentrant stability is a direct consequence of a monotonously decreasing ${j}_{c}$ versus field.
Instability of the topological surface state in Bi2Se3 upon deposition of gold
2017
Momentum-resolved photoemission spectroscopy indicates the instability of the Dirac surface state upon deposition of gold on the (0001) surface of the topological insulator Bi2Se3. Based on the str ...