Search results for "inversion"

Focal nodular hyperplasias in normal and fatty liver: a quantitative evaluation with SH U 508A and pulse inversion ultrasound

2003

Atypical liver hemangiomas: contrast enhancement patterns with SH U 508A and pulse inversion ultrasound

2003

A new proof of the support theorem and the range characterization for the Radon transform

1983

The aim of this note is to give a new and elementary proof of the support theorem for the Radon transform, which is based only on the projection theorem and the Paley-Wiener theorem for the Fourier transform. The idea is to solve a certain system of linear equations in order to determine the coefficients of a homogeneous polynomial (interpolation problem). By the same method, we get a short proof of the range characterization for Radon transforms of functions supported in a ball.

Iterative integral equation methods for structural coarse-graining

2021

In this paper, new Newton and Gauss-Newton methods for iterative coarse-graining based on integral equation theory are evaluated and extended. In these methods, the potential update is calculated from the current and target radial distribution function, similar to iterative Boltzmann inversion, but gives a potential update of quality comparable with inverse Monte Carlo. This works well for the coarse-graining of molecules to single beads, which we demonstrate for water. We also extend the methods to systems that include coarse-grained bonded interactions and examine their convergence behavior. Finally, using the Gauss-Newton method with constraints, we derive a model for single bead methano…

Palladium-catalysed direct cross-coupling of secondary alkyllithium reagents

2014

Palladium-catalysed cross-coupling of secondary C(sp(3)) organometallic reagents has been a long-standing challenge in organic synthesis, due to the problems associated with undesired isomerisation or the formation of reduction products. Based on our recently developed catalytic C-C bond formation with organolithium reagents, herein we present a Pd-catalysed cross-coupling of secondary alkyllithium reagents with aryl and alkenyl bromides. The reaction proceeds at room temperature and on short timescales with high selectivity and yields. This methodology is also applicable to hindered aryl bromides, which are a major challenge in the field of metal catalysed cross-coupling reactions.

Chiral Inversion of Thiolate-Protected Gold Nanoclusters via Core Reconstruction without Breaking an Au-S Bond

2019

On the basis of density functional theory computations of the well-known chiral Au38(SR)24 nanocluster and its Pd- and Ag-doped derivatives, we propose here a mechanism for chiral inversion that does not require the breaking of a metal-sulfur bond at the metal-ligand interface but features a collective rotation of the gold core. The calculated energy barriers for this mechanism for Au38 and Pd-doped Au38 are in the range of 1-1.5 eV, significantly lower than barriers involving the breakage of Au-S bonds (2.5 eV). For Ag-doped Au38, barriers for both mechanisms are similar (1.3-1.5 eV). Inversion barriers for a larger chiral Au144(SR)60 are much higher (2.5-2.8 eV). Our computed barriers are…

Comparison of different acquisition patterns for 2D tomographic resistivity surveys

2015

A systematic comparison is presented between some 2D resistivity models and their images by the inversion of synthetic datasets relating to three different arrays, suitable for multichannel data acquisitions (dipole-dipole (DD), Wenner-Schlumberger (WS) and multiple gradient (MG)). The goal is to study how the measurement errors affects the resolution of the tomographic models and the ability to retrieve correct information on buried targets. We considered different data acquisition patterns, gradually increasing the complexity of the combinations of potential spacing and dipolar distance. To this end we increased the number of current dipoles to obtain approximately the same amount of meas…

Mapping of landfills using time-domain spectral induced polarization data: the Eskelund case study

2012

This study uses time-domain induced polarization data for the delineation and characterization of the former landfill site at Eskelund, Denmark. With optimized acquisition parameters combined with a new inversion algorithm, we use the full content of the decay curve and retrieve spectral information from time-domain IP data. Thirteen IP/DC profiles were collected in the area, supplemented by el-log drilling for accurate correlation between the geophysics and the lithology. The data were inverted using a laterally constrained 1D inversion considering the full decay curves to retrieve the four Cole-Cole parameters. For all profiles, the results reveal a highly chargeable unit that shows a ver…

Spillovers de la Inversion Extranjera Directa y sus efectos en las empresas colombianas

2018

El desarrollo de esta tesis gira entorno a investigar acerca de las contribuciones de la IED y sus impactos en las empresas colombianas, sobre todo, en aquellas que vienen teniendo una importante presencia con sus ventas en los mercados internacionales. Se trata de valorar a nivel cuantitativo y cualitativo el papel de los spillovers o de externalidades causadas por los flujos de inversión directa que recibe el país, sobre algunas de las actividades importantes que permiten impulsar la competitividad de las empresas colombianas con alta vocación exportadora y con presencia internacional. En especial, la posibilidad de tener acceso a nuevas tecnologías, el incentivo a buscar la eficiencia en…

A new chromosomal rearrangement improves the adaptation of wine yeasts to sulfite

2019

Sulfite‐generating compounds are widely used during winemaking as preservatives because of its antimicrobial and antioxidant properties. Thus, wine yeast strains have developed different genetic strategies to increase its sulfite resistance. The most efficient sulfite detoxification mechanism in Saccharomyces cerevisiae uses a plasma membrane protein called Ssu1 to efflux sulfite. In wine yeast strains, two chromosomal translocations (VIIItXVI and XVtXVI) involving the SSU1 promoter region have been shown to upregulate SSU1 expression and, as a result, increase sulfite tolerance. In this study, we have identified a novel chromosomal rearrangement that triggers wine yeast sulfite adaptation.…