Search results for "ionic liquid"

Study of aromatic nucleophilic substitution with amines on nitrothiophenes in RTILs: are the different effects on the behavior of para-like and orto-…

2006

The kinetics of the nucleophilic aromatic substitution of some 2-L-5-nitrothiophenes (para-like isomers) with three different amines (pyrrolidine, piperidine, and morpholine) were studied in three roomtemperature ionic liquids ([bmim][BF4], [bmim][PF6], and [bm2im][BF4], where bmim ) 1-butyl-3- methylimidazolium and bm2im ) 1-butyl-2,3-dimethylimidazolium). To calculate thermodynamic parameters, a useful instrument to gain information concerning reagent-solvent interactions, the reaction was carried out over the temperature range 293-313 K. The reaction occurs faster in ionic liquids than in conventional solvents (methanol, benzene), a dependence of rate constants on amine concentration sim…

Ionic liquids: a highway with many lanes

Supported ionic liquids. New recyclable materials for L-proline-catalyzed aldol reaction

The effect of the cation p-surface area on the 3D organization and catalytic ability of imidazolium-based ionic liquids

2011

The dichotomic nature of ionic liquids (ILs, simple solvents or supramolecular fluids) induced us to carry out a structural investigation of some mono-and dicationic ionic liquids using 1D and 2D NMR, resonance light scattering, and UV/Vis spectroscopy. Ionic liquids with different cation π-surface areas were used, namely [bmim][NTf2], [Bzmim][NTf 2], [Bzbim][NTf2], [p-Xyl-(bim)2][NTf 2]2, and [m-Xyl-(bim)2][NTf2] 2 [bmim = 1-butyl-3-methylimidazolium, Bzmim = 1-benzyl-3- methylimidazolium, Bzbim = 1-benzyl-3-butylimidazolium, NTf2 = bis(trifluoromethansulfonyl)imide]. In order to verify to what extent the structural investigation, coupled with the determination of solvent parameters, could…

A joint of experimental investigations about the structural organization of two geminal ionic liquids

Ionic Liquid Gels: Tunable and Multifaceted Materials

Materials based on ionic liquids retain properties of solvent components, like low vapor pressure, high thermal stability and structure tunability. The latter allows changing properties of materials by making small variations in the cation or anion structure, opening the way to a plethora of different applications. In this context, ionic liquid gels can represent a challenge especially if they are obtained from gelation of ionic liquid binary mixtures or of organic salts in ionic liquids. In the framework of our interest in studying ionic liquids properties and applications, in the last few years, we have addressed our attention to the obtainment of ionic liquid gels.1 We have deeply invest…

Polycarbonate depolymerization promoted by Task-Specific Ionic Liquids and Ultrasound

Cholinium-based ionic liquids as catalysts for the glycolysis of post-consumer PET waste

How the Combination of Bio-based Polymers and Ionic Liquids in Gel Phases Works for the Desulfurization of Fuels

Determination of basic strenght of aliphatic amines through ion pair formation in some ionic liquid solutions

2010

To have an evaluation of the basic strength of aliphatic amines in ionic liquid solution, the stability constants relevant to the formation of amine/p-nitrophenol ion pairs were determined in different ionic liquids at 298 K. In particular, aliphatic (pyrrolidinium) and aromatic (imidazolium) ionic liquids were used. Imidazolium ions, bmim(+) and bm(2)im(+), having different hydrogen bond donor abilities were taken into account. Anions were chosen ([BF(4)(-)], [PF(6)(-)], and [NTf(2)(-)]; where NTf(2) = bis(trifluoromethansulfonyl)imide) showing different shape, size, and coordination ability. Several primary, secondary (cyclic or not), and tertiary amines were used to study the effect of a…