Search results for "ionic"
showing 10 items of 2016 documents
Experimental Confirmation of a Topological Isomer of the Ubiquitous Au25(SR)18 Cluster in the Gas Phase
2021
High-resolution electrospray ionization ion mobility mass spectrometry has revealed a gas-phase isomer of the ubiquitous, extremely well-studied Au25(SR)18 cluster both in anionic and cationic form. The relative abundance of the isomeric structures can be controlled by in-source activation. The measured collision cross section of the new isomer agrees extremely well with a recent theoretical prediction (Matus, M. F.; et al. Chem. Commun. 2020, 56, 8087) corresponding to a Au25(SR)18– isomer that is energetically close and topologically connected to the known ground-state structure via a simple rotation of the gold core without breaking any Au–S bonds. The results imply that the structural d…
Monovalent cation conductance in Xenopus laevis oocytes expressing hCAT-3
2005
hCAT-3 (human cationic amino acid transporter type three) was investigated with both the two-electrode voltage clamp method and tracer experiments. Oocytes expressing hCAT-3 displayed less negative membrane potentials and larger voltage-dependent currents than native or water-injected oocytes did. Ion substitution experiments in hCAT-3-expressing oocytes revealed a large conductance for Na + and K + . In the presence of l-Arg, voltage-dependent inward and outward currents were observed. At symmetrical (inside/outside) concentrations of l-Arg, the conductance of the transporter increased monoexponentially with the l-Arg concentrations; the calculated Vmax and KM values amounted to 8.3 AS and…
A Study of Mechanical Properties of Polymer Composite Membranes with Various Ionic Liquids at Elevated Temperatures
2019
This work was supported by Latvian Council of Science (Cooperation project No.666/2014.4).
Wo3 and ionic liquids: A synergic pair for pollutant gas sensing and desulfurization
2020
This review deals with the notable results obtained by the synergy between ionic liquids (ILs) and WO3 in the field of pollutant gas sensing and sulfur removal pretreatment of fuels. Starting from the known characteristics of tungsten trioxide as catalytic material, many authors have proposed the use of ionic liquids in order to both direct WO3 production towards controllable nanostructures (nanorods, nanospheres, etc.) and to modify the metal oxide structure (incorporating ILs) in order to increase the gas adsorption ability and, thus, the catalytic efficiency. Moreover, ionic liquids are able to highly disperse WO3 in composites, thus enhancing the contact surface and the catalytic abilit…
Dissolution and hydrolysis of fibre sludge using hydroxyalkylimidazolium hydrogensulphate ionic liquids
2014
The dissolution and hydrolysis of wet fibre sludge in ionic liquids (ILs) with different reaction conditions are performed in this study. Novel types of hydroxyalkylimidazolium hydrogensulphate ILs, [glymim]HSO4, [hemim]HSO4 and [hpmim]HSO4, are especially designed and aimed to combine the dissolution and hydrolysis of wet fibre sludge in a one-step pretreatment. The results were obtained based on the analysis of total reducing sugars (TRS) with the DNS method. The dissolution and hydrolysis of fresh wild horse chestnut fruit (Aesculus hippocastanum) with the same ILs were also carried out as a comparison reference. Since fibre sludge is cellulose based and horse chestnut fruit is starch ba…
The electric properties of ionic solutions: a molecular dynamics (preliminary) study
2011
Protonazione del p-nitrofenato di sodio in liquidi ionici: una "sonda" per la determinazione della forza acida
LIQUIDI IONICI E CARBON DOTS UNITI NEI GEL IBRIDI!
2020
La ricerca di materiali sempre più efficienti abbraccia svariati campi della società attuale e l’unione di due componenti con peculiarità complementari può generare materiali altamente innovativi. I gel formati da carbon nanodots e liquidi ionici non soltanto preservano le caratteristiche dei singoli componenti, ma ne migliorano le prestazioni, generando così un materiale ibrido performante e facilmente modulabile in base alle applicazioni richieste.
Complessi liquido ionico-cobalto: un’interazione termocromica
2019
Le ben note proprietà chimico-fisiche dei liquidi ionici (ILs), unite alla versatilità strutturale, sono alla base delle loro numerose e differenti applicazioni. In questo lavoro, si presenta un’interazione termocromica reversibile, sia in soluzione che in un film polimerico, tra un IL portante sul catione un residuo gluconammidico e il sale di cobalto Co(NTf2)2. I gruppi ossidrilici sul catione e l’anione bromuro dell’IL coordinano il Co al variare della temperatura applicata. A temperatura ambiente il complesso OH-Co risulta ottaedrico (rosa) mentre, intorno ai 60 °C, la geometria diviene tetraedrica con lo ione bromuro che coordina il Co (blu). Lo studio VT UV-vis (Figura 1) ha permesso …
On Apache Log4j2 Exploitation in Aeronautical, Maritime, and Aerospace Communication
2022
Apache Log4j2 is a prevalent logging library for Java-based applications. In December 2021, several critical and high-impact software vulnerabilities, including CVE-2021-44228, were publicly disclosed, enabling remote code execution (RCE) and denial of service (DoS) attacks. To date, these vulnerabilities are considered critical and the consequences of their disclosure far-reaching. The vulnerabilities potentially affect a wide range of internet of things (IoT) devices, embedded devices, critical infrastructure (CI), and cyber-physical systems (CPSs). In this paper, we study the effects and feasibility of exploiting these vulnerabilities in mission-critical aviation and maritime environment…