Search results for "ionic"

Complexes of (CH3)2AuIII: synthesis, PMR and IR spectra

1975

Abstract The syntheses and reactivity of dimethylgold(III) complexes with multidentate ligands as TRIPHOS (i.e., 1,1,1-tris(diphenylphosphinomethyl)ethane) and TREN (i.e. 2,2′,2″-triaminotriethylamine) have been examined. I.r. spectra for the compounds in the solid state, conductivity and PMR data for solutions, lead to the assignment of an ionic formula [CH 3 ) 2 Au TRIPHOS] + [(CH 3 ) 2 AuCl 2 ] − where the gold(III) atoms are presumably four-coordinate. The complex (CH 3 ) 2 AuCl TREN in DMSO solution undergoes a reductive elimination reaction, as found for analogous dimethylgold(III) derivatives.

TASK SPECIFIC IONIC LIQUIDS: CATALIZZATORI ECOCOMPATIBILI PER LA DEPOLIMERIZZAZIONE DELLE PLASTICHE

Fluorimetric determination of 1-naphthol and mixtures of carbaryl and 1-naphthol in micellar media

1990

The interaction of 1-naphthol with different types of anionic, cationic and non-ionic surfactants has been studied spectrofluorimetrically in order to obtain a sensitivity enhancement in the determination of this compound. At neutral pH, cetyl trimethyl ammonium bromide (CTAB) provides a 2-fold sensitivity enhancement of 1-naphthol and exhibits a weak interaction with carbaryl. In strong alkaline medium carbaryl is hydrolyzed to 1-naphthol and in the presence of CTAB micells, a 5-fold sensitivity enhancement and a limit of detection of 0.2 μg·ml−1 with a 101±3% percentage of recovery is obtained. These facts permit the development of an accurate method for the fluorimetric analysis of 1-nap…

Ionic liquid-based single-drop microextraction followed by liquid chromatography-ultraviolet spectrophotometry detection to determine typical UV filt…

2009

Abstract A user-friendly and inexpensive ionic liquid-based single-drop microextraction (IL-SDME) procedure has been developed to preconcentrate trace amounts of six typical UV filters extensively used in cosmetic products (i.e., 2-hydroxy-4-methoxybenzophenone, isoamyl 4-methoxycinnamate, 3-(4′-methylbenzylidene)camphor, 2-ethylhexyl 2-cyano-3,3-diphenylacrylate, 2-ethylhexyl 4-dimethylaminobenzoate and 2-ethylhexyl 4-methoxycinnamate) from surface water samples prior to analysis by liquid chromatography-ultraviolet spectrophotometry detection (LC-UV). A two-stage multivariate optimization approach was developed by means of a Plackett–Burman design for screening and selecting the significa…

Determination of UV filters in both soluble and particulate fractions of seawaters by dispersive liquid–liquid microextraction followed by gas chroma…

2014

An analytical method to determine the total content (i.e., not only in the soluble fraction but also in the particulate one) of eight commonly used UV filters in seawater samples is presented for the first time. Dispersive liquid-liquid microextraction (DLLME) is used as microextraction technique to pre-concentrate the target analytes before their determination by gas chromatography-mass spectrometry (GC-MS). In order to release the UV filters from the suspended particles an ultrasound treatment is performed before DLLME. The ultrasound treatment time was studied in order to achieve a quantitative lixiviation of the target analytes. The type and volume of both disperser and extraction solve…

On-line bidirectional electrostacking of chromium(III) and chromium(VI) for flame atomic absorption spectrometry determination

2000

Abstract An on-line bidirectional electrostacking-flow injection-flame atomic absorption spectrometry method has been developed for the simultaneous separation, pre-concentration and determination of Cr(III) and Cr(VI). The electrostacking-flow injection unit was established, the pH and components of the support buffer and sample medium were investigated. Results indicated that the ionic mobility, electric field strength and sample area cross-section are the main influence factors on the electrostacking. The calibration range for both, Cr(III) and Cr(VI), was from 20 to 400 μg l −1 . The limit of detection was 7 μg l −1 for three-times the standard deviation of blank values using a electros…

Interaction of diazepam with surfactants. Spectrophotometric and spectrofluorometric study

1986

Abstract The interaction of diazepam with non-ionic, anionic and cationic surfactants has been studied spectrophotometrically and fluorometrically. It has been verified that the absorption spectrum of diazepam is not modified in micellar medium. However, a dramatic five-fold increase in fluorescence sensitivity is observed in the presence of sodium lauryl sulphate (SDS). The experimental conditions, temperature, pH and surfactant concentration have been optimized to improve the fluorometric determination of diazepam and a detection limit of 0,04 ppmhas been obtained.

Sensitive determination of free benzophenone-3 in human urine samples based on an ionic liquid as extractant phase in single-drop microextraction pri…

2007

Abstract Benzophenone-3 (BZ3), one of the compounds most commonly used as UV filter in cosmetic products, can be absorbed through the skin into the human body, since it can be found at trace levels in urine from users of cosmetic products that contain BZ3. Moreover, different undesirable effects have been attributed to this compound. Thus, sensitive analytical methods to monitor urinary excretion of this compound should be developed. This paper presents a selective and sensitive methodology for BZ3 determination at ultratrace levels in human urine samples. The methodology is based on a novel microextraction technique, known as single-drop microextraction (SDME). An ionic liquid (IL) has bee…

Chromium speciation using activated alumina microcolumns and sequential injection analysis-flame atomic absorption spectrometry

2001

Abstract A new procedure has been developed for chromium speciation in water by sequential injection analysis and flame atomic absorption spectrometry. The method involves the online retention of Cr(VI) anionic species and Cr(III) cationic species on alumina microcolumns, prepared by packing activated alumina in polytetrafluoroethylene tubes, followed by selective elution of Cr(VI) with 2 mol l −1 NH 4 OH and of Cr(III) with 0.2 mol l −1 HNO 3 . Studies were carried out on the effect of retention and elution conditions for both Cr species. The limit of detection values, established as the concentration corresponding to three times the standard deviation of blank measurements divided by the …

In-tube solid-phase microextraction and liquid chromatography using a monolithic column for the selective determination of residual ethylenediamine i…

2009

The selective determination of the diamine ethylenediamine (EDA) in the presence of a higher amount of residual dimethylamine in cationic polymers has been developed. The strategy uses both a solution derivatization with a selective agent of primary amines such as o-phthaldialdehyde-N-acetyl-L-cysteine (OPA-NAC) and an in-tube solid-phase microextraction (IT-SPME) coupled to liquid chromatography (LC). A 70 cm long, 0.32 mm internal diameter, and 3 microm thick commercially available capillary column coated with 95% polydimethylsiloxane and 5% polydiphenylsiloxane was employed to replace the injection loop of a Rheodyne injection valve. A volume of 1 mL of derivatized sample was passed thro…