Search results for "ionit"
showing 10 items of 142 documents
In-Operando Lithium-Ion Transport Tracking in an All-Solid-State Battery.
2022
An all-solid-state battery is a secondary battery that is charged and discharged by the transport of lithium ions between positive and negative electrodes. To fully realize the significant benefits of this battery technology, for example, higher energy densities, faster charging times, and safer operation, it is essential to understand how lithium ions are transported and distributed in the battery during operation. However, as the third lightest element, methods for quantitatively analyzing lithium during operation of an all-solid-state device are limited such that real-time tracking of lithium transport has not yet been demonstrated. Here, the authors report that the transport of lithium …
Anion-driven encapsulation of cationic guests inside pyridine[4]arene dimers
2019
Pyridine[4]arenes have previously been considered as anion binding hosts due to the electron-poor nature of the pyridine ring. Herein, we demonstrate the encapsulation of Me4N+ cations inside a dimeric hydrogen-bonded pyridine[4]arene capsule, which contradicts with earlier assumptions. The complexation of a cationic guest inside the pyridine[4]arene dimer has been detected and studied by multiple gas-phase techniques, ESI-QTOF-MS, IRMPD, and DT-IMMS experiments, as well as DFT calculations. The comparison of classical resorcinarenes with pyridinearenes by MS and NMR experiments reveals clear differences in their host–guest chemistry and implies that cation encapsulation in pyridine[4]arene…
Dithionite bleaching of thermomechanical pulp: factors having effects on bleaching efficiency
2000
The efficiency of dithionite bleaching of Norway spruce (Picea abies) thermomechanical pulp was studied by applying various multivariate data analysis techniques to analytical data (temperature, pH, ion chromatographic and energy-dispersive X-ray fluorescence data). In addition, modeling the residual sulfur content of bleached pulp by means of diffuse reflectance UV-vis spectral data from laboratory-scale bleaching experiments was attempted. The results indicated that this lignin-preserving bleaching process could be evaluated by means of the analytical data using either PCR or PLS models. These models also indicated that wavelengths below 400 nm should not be used in measuring the pulp bri…
Ferricytochrome c encapsulated in silica nanoparticles: structural stability and functional properties.
2004
Using a modified sol-gel technique, we have succeeded in encapsulating ferric cytochrome c in silica nanoparticles obtained from hydrolysis and polycondensation of tetramethylorthosilicate. Particles dimensions have been determined with dynamic light scattering; this technique yields an hydrodynamic radius of about 100 nm, each nanoparticle containing about 10(2)-10(3) proteins. If stored in the cold at low ionic strength, nanoparticles are stable for more than one week, even if a slow radius increase with time is observed. CD measurements show that encapsulated proteins exhibit substantially increased stability against guanidinium hydrochloride induced denaturation. Reduction kinetics of e…
Global and local interactions in football : the changing field of professional football stadiums in Finland and Hungary in the 2000s
2018
This article aims to increase understanding of the global-local contexts in football by exploring the changing field of professional football stadiums in Finland and Hungary in the 2000s. More specifically, the cases of two clubs, HJK (Finland) and Ferencvárosi TC (Hungary) are studied. We employ concepts of sport and globalization. The research data consist of semi-structured expert interviews with Finnish and Hungarian football practitioners, media and club documents, and data from observation. The results suggest that interactions of global and local forces are reflected in the development and operation of stadiums. On the one hand, international and national governing bodies have streng…
A multicommuted flow system with solenoid micro-pumps for paraquat determination in natural waters.
2007
A flow system designed with solenoid micro-pumps is proposed for the determination of paraquat in natural waters. The procedure involves the reaction of paraquat with dehydroascorbic acid followed by spectrophotometric measurements. The proposed procedure minimizes the main drawbacks related to the standard chromatographic procedure and to flow analysis and manual methods with spectrophotometric detection based on the reaction with sodium dithionite, i.e. high solvent consumption and waste generation and low sampling rate for chromatography and high instability of the reagent in the spectrophotometric procedures. A home-made 10-cm optical-path flow cell was employed for improving sensitivit…
A crystalline radical cation derived from Thiele’s hydrocarbon with redox range beyond 1 V
2021
Thiele’s hydrocarbon occupies a central role as an open-shell platform for new organic materials, however little is known about its redox behaviour. While recent synthetic approaches involving symmetrical carbene substitution of the CPh2 termini yield isolable neutral/dicationic analogues, the intervening radical cations are much more difficult to isolate, due to narrow compatible redox ranges (typically 1 V), permitting its isolation in crystalline form. Further single-electron oxidation affords borenium dication 12+, thereby establishing an organoboron redox system fully characterized in all three redox states. We perceive that this strategy can be extended to other transient organic rad…
Isolation and partial characterization of a cytochrome-o complex from chromatophores of the photosynthetic bacterium Rhodospirillum rubrum FR1.
1989
A cytochrome-o complex was isolated from chromatophores of photoheterotrophically grown Rhodospirillum rubrum FR1. The enzyme was extracted with the non-denaturating detergent taurodeoxycholate and subsequently purified by sucrose-density-gradient centrifugation and gel-permeation HPLC. The complex contains two types of cytochromes, one of them cytochrome o, and two copper atoms. It catalyzes the reduction of molecular oxygen, when N,N,N',N'-tetramethyl-p-phenylenediamine or ubiquinol 10 are offered as electron donors. The oxidase activity is inhibited by cyanide, carbon monoxide and 2-heptyl-2-hydroxyquinoline N-oxide. The molecular mass of the protein is 136 +/- 15 kDa. The subunit analys…
Neutron cross section measurements at n_TOF for ADS related estudies
2005
A neutron Time-of-Flight facility (n_TOF) is available at CERN since 2001. The innovative features of the neutron beam, in particular the high instantaneous flux, the wide energy range, the high resolution and the low background, make this facility unique for measurements of neutron induced reactions relevant to the field of Emerging Nuclear Technologies, as well as to Nuclear Astrophysics and Fundamental Nuclear Physics. The scientific motivations that have led to the construction of this new facility are here presented. The main characteristics of the n_TOF neutron beam are described, together with the features of the experimental apparata used for cross-section measurements. The main res…
Measurement of ionization, charge exchange and ion confinement times in charge breeder ECR ion sources with short pulse 1+ injection of metal ions
2022
Abstract The Consecutive Transients (CT) method is used for estimating the characteristic times of ionization, charge exchange and confinement within the plasma of a Charge Breeder Electron Cyclotron Resonance Ion Source (CB-ECRIS). The method reveals differences in the characteristic times between different source configurations, with K9+ charge breeding efficiencies of 8.9 % and 20.4 %, and allows qualitative explanation of the improved breeding efficiency. The increase in K9+ efficiency is accompanied by a decrease in ionization time for low charge states, a decrease of charge exchange time for high charge states, and an overall decrease of the ion confinement time, which increases non-l…