Search results for "isomers"

showing 4 items of 64 documents

Melting point, molecular symmetry and aggregation of tetrachlorobenzene isomers: the role of halogen bonding

2018

Tetrachlorobenzenes represent one of the best known, but not yet fully understood, group of isomers of the structure–melting point relationship. The differences in melting temperatures of these structurally related compounds were rationalized in terms of the hierarchy and nature of formed noncovalent interactions, and the molecular aggregation that is influenced by molecular symmetry. The highest melting point is associated with the highly symmetric 1,2,4,5-tetrachlorobenzene isomer. The structures of less symmetrical 1,2,3,4-tetrachlorobenzene and 1,2,3,5-tetrachlorobenzene, determined at 270 and 90 K, show a distinct pattern of halogen bonds, characterized by the different numbers and typ…

melting pointEnthalpy02 engineering and technology010402 general chemistry01 natural sciencesGroup (periodic table)Materials ChemistryMolecular symmetryNon-covalent interactionschemistry.chemical_classificationHalogen bondstructure–property relationsIntermolecular forceMetals and Alloys021001 nanoscience & nanotechnologytetra­chloro­benzene isomersAtomic and Molecular Physics and Optics0104 chemical sciencesElectronic Optical and Magnetic Materialsmolecular symmetryCrystallographychemistryhalogen bondingHalogenMelting point0210 nano-technologyActa Crystallographica Section B Structural Science, Crystal Engineering and Materials
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Response to comment on Properties and inter­actions – melting point of tri­bromo­benzene isomers

2022

molecular symmetrycohesion forcesmelting pointisomersActa Crystallographica Section B-Structural Science Crystal Engineering and Materials
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Recent experiments at the JYFLTRAP Penning trap

2020

AbstractThe JYFLTRAP double Penning trap mass spectrometer at the Ion Guide Isotope Separator On-Line (IGISOL) facility offers excellent possibilities for high-precision mass measurements of radioactive ions. Around 400 atomic masses, including around 50 isomeric states, have been measured since JYFLTRAP became operational. JYFLTRAP has also been used as a high-resolution mass separator for decay spectroscopy experiments as well as an ion counter for fission yield studies. In this contribution, an overview of recent activities at the JYFLTRAP Penning trap is given, with a focus on nuclei discussed in the PLATAN2019 meeting.

nuclear binding energymassaspektrometriaNuclear and High Energy PhysicstutkimuslaitteetFission product yieldMass spectrometry7. Clean energy01 natural sciencesIonNuclear physicsPhysics in General0103 physical sciencesPhysical and Theoretical Chemistry010306 general physicsSpectroscopyPhysicsIsotope010308 nuclear & particles physicsatomic masspenning trapCondensed Matter PhysicsPenning trapAtomic and Molecular Physics and OpticsAtomic massNuclear binding energyisomersydinfysiikkaHyperfine Interactions
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Studying Gamow-Teller transitions and the assignment of isomeric and ground states at $N=50$

2022

Direct mass measurements of neutron-deficient nuclides around the N=50 shell closure below $^{100}$Sn were performed at the FRS Ion Catcher (FRS-IC) at GSI, Germany. The nuclei were produced by projectile fragmentation of $^{124}$Xe, separated in the fragment separator FRS and delivered to the FRS-IC. The masses of 14 ground states and two isomers were measured with relative mass uncertainties down to 1×10−7 using the multiple-reflection time-of-flight mass spectrometer of the FRS-IC, including the first direct mass measurements of $^{98}$Cd and $^{97}$Rh. A new QEC=5437±67 keV was obtained for $^{98}$Cd, resulting in a summed Gamow-Teller (GT) strength for the five observed transitions (0+…

nuclear isomersNuclear and High Energy PhysicsMultiple-reflection time-of-flight massNuclear shell structuremultiple-reflection time-of-flight mass[PHYS.NEXP] Physics [physics]/Nuclear Experiment [nucl-ex]N = 50 isotonesFOS: Physical sciencesGamow-Teller transition?s strength114 Physical sciencesSpectrometerexotic nucleiGamow-Teller transition's strengthnuclear shell structureNuclear isomersspectrometerN=50 isotonesNuclear Experiment (nucl-ex)ydinfysiikkaNuclear ExperimentExotic nuclei
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