Search results for "iva"

Synthesis and solid state structure for a series of poly(1-pyrrolylmethyl)benzene derivatives. Control of the interplaying π–π and C–H⋯π interactions?

2006

The syntheses of new hexa- and 1,2,4,5-tetra-1-pyrrolylmethyl-benzene (1 and 2, respectively) compounds and their crystal structures, along with those for the related disubstituted o-, m- and p-di-1-pyrrolylmethyl-benzene (3–5) derivatives are reported. The arrangements of molecules in the 1-D structure for 2–5 are controlled by the interplay of two different weak interactions: π–π and C–H⋯π (Ph) interactions. The absence of such interactions in the packing of 1 seems to be related to the arrangement of the pyrrolylmethyl arms with respect to the benzene core, which prevents the π cloud of the aromatic ring to be part of any intermolecular interaction. In addition, C–H⋯π (pyrrolyl) interact…

Reactions in the presence of irradiated semiconductors: Are they simply photocatalytic?

2018

A generally accepted classification distinguishes semiconductor photocatalysis in type A and type B. The first class comprehends reactions where the primary redox products (radical anions and cations) further evolve giving rise to the final reduced and oxidized species. Type B reactions occur when the primary redox products undergo intermolecular bond formation to addition products. Recently, some photocatalytic reactions have been reported wherein the photocatalytically produced compounds are not the final products. In fact, they react in the solution bulk or catalytically on the surface of the semiconductor with other species thus producing the target compounds. These reactions, hereby re…

Analysis of salivary detection of P16INK4A and RASSF1A promoter gene methylation and its association with oral squamous cell carcinoma in a Colombian…

2019

Background Epigenetic factors play a fundamental role in the etiopathogenesis of oral squamous cell carcinoma (OSCC). This study evaluated if salivary detection of P16INK4A/RASSF1A gene promoter methylation might be linked to the clinical/histological features of OSCC in a Colombian population. Material and Methods Methylation-specific polymerase chain reaction (MSP-PCR) was used to detect the methylation frequency of P16INK4A/RASSF1A genes in DNA obtained from whole saliva collected of 40 healthy controls (HC) and 43 OSCC patients. Determination of the clinical performance of MSP-PCR assay was based on standard algorithms derived from two-way contingency table analysis. The association of …

Volcanic structures investigation through SAR and seismic interferometric methods: The 2011-2013 Campi Flegrei unrest episode

2019

Observations from satellites provide high-resolution images of ground deformation allowing to infer deformation sources by developing advanced modeling of magma ascent and intrusion processes. Nevertheless, such models can be strongly biased without a precise model of the internal structure of the volcano. In this study, we jointly exploited two interferometric techniques to interpret the 2011–2013 unrest at Campi Flegrei caldera (CFc). The first is the Interferometric Synthetic Aperture Radar (InSAR) technique, which provides highly-resolved spatial and temporal images of ground deformation. The second is the Ambient Noise Tomography (ANT), which images subsurface structures, providing the…

Exposure to mercury among 9-year-old Spanish children: Associated factors and trend throughout childhood

2019

Mercury is considered a neurotoxicant and human exposure occurs mainly from the consumption of marine species. We aimed to describe total mercury concentrations (THg) and associated factors in 9-year old children, as well as to explore the trend in THg from 4 to 9 years of age. The study population consisted of 9-year-old children participating in the INMA (Environment and Childhood) birth cohort study in Valencia, Spain (n = 405, 2013–2014). THg in hair samples was measured by atomic absorption spectrometry at the age of 4 and 9 years. Sociodemographic and dietary data was obtained through questionnaires. Multiple linear regression was used to explore the association between THg and covari…

Unionid shells (Hyriopsis cumingii) record manganese cycling at the sediment-water interface in a shallow eutrophic lake in China (Lake Taihu)

2017

Abstract Aquatic eutrophication is becoming a serious environmental problem throughout the world. The utility of bivalves as bio-filters to improve water quality and reduce algal blooms has been widely acknowledged, but the potential usefulness of bivalve shells as retrospective monitors of eutrophication-induced environmental change has received little attention. Here, we present the first multi-year, high-resolution Mn/Ca shell records of the freshwater mussel, Hyriopsis cumingii (Lea, 1852) from a shallow eutrophic lake (Lake Taihu, China). Mn/Ca shell time-series of the two studied shells exhibit a high degree of synchrony after being placed in a precise temporal context by means of gro…

2016

Gianluca Tramontana was supported by the GEOCARBON EU FP7 project (GA 283080). Dario Papale, Martin Jung and Markus Reichstein acknowledge funding from the EU FP7 project GEOCARBON (grant agreement no. 283080) and the EU H2020 BACI project (grant agreement no. 640176). Gustau Camps-Valls wants to acknowledge the support by an ERC Consolidator Grant with grant agreement 647423 (SEDAL). Kazuhito Ichii was supported by Environment Research and Technology Development Funds (2-1401) from the Ministry of the Environment of Japan and the JAXA Global Change Observation Mission (GCOM) project (no. 115). Christopher R. Schwalm was supported by National Aeronautics and Space Administration (NASA) gran…

Sr/Ca and Mg/Ca ratios of ontogenetically old, long-lived bivalve shells (Arctica islandica) and their function as paleotemperature proxies

2011

International audience; The Sr/Ca and Mg/Ca ratios of many biogenic skeletons provide useful paleotemperature estimates. As yet however, it has remained largely impossible to obtain such information from bivalve shells. In the present study, metal-to-calcium values in the hinge plate (aragonite, outer shell layer) of four ontogenetically old (85 to 374 year-old) specimens of the long-lived bivalve, Arctica islandica, were measured on a LA-ICP-MS. The shells were collected alive in 1868, 1986 and 2003 from three different localities around Iceland. With increasing ontogenetic age and decreasing growth rate, a distinct trend toward increasing Sr/Ca (max. 5.17 mmol/mol) and Mg/Ca values (max. …

A Participatory Agrobiodiversity Conservation Approach in the Oases: Community Actions for the Promotion of Sustainable Development in Fragile Areas

2021

Rural development policies today include significant directions towards ecological transition and sustainability. Biodiversity plays a fundamental role, especially in fragile environments. The North African oases, for example, are socio-ecological structures with delicate balances in terms of natural resources, where the activation of participatory conservation approaches appears today to be very useful, aiming at long-lasting results. This type of approach was applied in the oasis of El Hamma, in Tunisia. The socio-ecological analysis was carried out through semi-structured interviews with different stakeholders of the oasis. The results were used to activate focus groups and to identify, …

Soil erosion processes in European vineyards: A qualitative comparison of rainfall simulation measurements in Germany, Spain and France

2016

Small portable rainfall simulators are considered a useful tool to analyze soil erosion processes in cultivated lands. European research groups in Spain (Valencia, Málaga, Lleida, Madrid and La Rioja), France (Reims) and Germany (Trier) have used different rainfall simulators (varying in drop size distribution and fall velocities, kinetic energy, plot forms and sizes, and field of application) to study soil loss, surface flow, runoff and infiltration coefficients in different experimental plots (Valencia, Montes de Málaga, Penedès, Campo Real and La Rioja in Spain, Champagne in France and Mosel-Ruwer valley in Germany). The measurements and experiments developed by these research teams give…