Search results for "kompleksi"
showing 10 items of 201 documents
Riemann surfaces and Teichmüller theory
2017
Riemannin pinnat ja Teichmüller-teoriaa. Tämän työn päämääränä on määritellä Riemannin pintojen Teichmüller-avaruudet sekä tutkia niiden geometrisia ominaisuuksia. Ensin työssä kehitetään peiteavaruuksien ja toimintojen teoriaa, jota sovelletaan Möbius-kuvauksista koostuviin ryhmiin. Tämän jälkeen kvasikonformaalikuvaukset määritellään Riemannin pinnoille ja niiden yhteyttä yhdesti yhtenäisten Riemannin avaruuksien kvasikonformikuvauksiin tutkitaan. Näitä tietoja sekä yhdesti yhtenäisten Riemannin pintojen uniformisaatiolausetta hyödyntämällä todistetaan yleisten Riemannin pintojen uniformisaatiolause. Tämä tulos liittää pinnat Möbius-kuvauksien toimintoihin yhdesti yhtenäisillä Riemannin p…
The Effects of Database Complexity on SQL Query Formulation
2020
In Structured Query Language (SQL) education, students often execute queries against a simple exercise database. Recently, databases that are more realistic have been utilized to the effect that students find exercises more interesting and useful, as these databases more accurately mimic databases students are likely to encounter in their future work environments. However, using even the most engaging database can be counterproductive to learning, if a student is not able to formulate correct queries due to the complexity of the database schema. Scientific evidence on the effects of database complexity on student’s query formulation is limited, and with queries from 744 students against thr…
Komplekso skaitļu apguves iespējas vidusskolā
2020
Diplomdarbs ir veltīts komplekso skaitļu apguves iespējai vidusskolā. Darba mērķis ir, izmantojot iespējas mācīt tēmu “Kompleksie skaitļi” vidusskolā, izstrādāt mācību programmas paraugu. Saistībā ar to darba uzdevums ir izpētīt, kādas iespējas mācīt tēmu “Kompleksie skaitļi” vidusskolā ir tagad un būs pēc projekta “Skola 2030” ieviešanas Latvijas skolās, izstrādāt tēmas teorētisko materiālu, stundas plānu, pārbaudes darbu piemērus un to aprobēt vidusskolā. Darba rezultātā ir izveidots mācību stundu saturs un plāns par tematu “Komplekso skaitļu algebriskā forma”, “Komplekso skaitļu trigonometriskā forma” ar sekmīgi aprobētiem pārbaudes darbiem, kurus var izmantot dotās tēmas apgūšanai fakul…
Series of Near-IR-Absorbing Transition Metal Complexes with Redox Active Ligands
2020
New soluble and intensely near-IR-absorbing transition metal (Ti, Zr, V, Ni) complexes were synthesized using a redox non-innocent N,N&rsquo
Synthesis of a labile sulfur-centred ligand, [S(H)C(PPh2S)2]−: structural diversity in lithium(i), zinc(ii) and nickel(ii) complexes
2016
A high-yield synthesis of [Li{S(H)C(PPh2S)2}]2 [Li2·(3)2] was developed and this reagent was used in metathesis with ZnCl2 and NiCl2 to produce homoleptic complexes 4 and 5b in 85 and 93% yields, respectively. The solid-state structure of the octahedral complex [Zn{S(H)C(PPh2S)2}2] (4) reveals notable inequivalence between the Zn-S(C) and Zn-S(P) contacts (2.274(1) Å vs. 2.842(1) and 2.884(1) Å, respectively). Two structural isomers of the homoleptic complex [Ni{S(H)C(PPh2S)2}2] were isolated after prolonged crystallization processes. The octahedral green Ni(ii) isomer 5a exhibits the two monoprotonated ligands bonded in a tridentate (S,S',S'') mode to the Ni(ii) centre with three distinctl…
Steric vs. electronic stereocontrol in syndio- or iso-selective ROP of functional chiral β-lactones mediated by achiral yttrium-bisphenolate complexes
2018
International audience; Origins of stereoselectivity in ROP of racemic chiral cyclic esters promoted by achiral yttrium complexes, resulting in the formation of highly heterotactic polylactide, and highly syndiotactic or, more uniquely, highly isotactic poly(3-hydroxybutyrate)s, are discussed. A close interplay between the nature of the cyclic ester, most particularly of the exocyclic functional chain installed on the chiral center of β-lactones, and the ortho-substituents installed on the phenolate rings of the ligand, results in various determining secondary interactions of steric and also electronic nature.
Shedding Light on the Interactions of Hydrocarbon Ester Substituents upon Formation of Dimeric Titanium(IV) Triscatecholates in DMSO Solution
2020
Abstract The dissociation of hierarchically formed dimeric triple lithium bridged triscatecholate titanium(IV) helicates with hydrocarbyl esters as side groups is systematically investigated in DMSO. Primary alkyl, alkenyl, alkynyl as well as benzyl esters are studied in order to minimize steric effects close to the helicate core. The 1H NMR dimerization constants for the monomer–dimer equilibrium show some solvent dependent influence of the side chains on the dimer stability. In the dimer, the ability of the hydrocarbyl ester groups to aggregate minimizes their contacts with the solvent molecules. Due to this, most solvophobic alkyl groups show the highest dimerization tendency followed by…
The Instability of Ni{N(SiMe3 )2 }2 : A Fifty Year Old Transition Metal Silylamide Mystery.
2015
The characterization of the unstable Ni(II) bis(silylamide) Ni{N(SiMe3 )2 }2 (1), its THF complex Ni{N(SiMe3 )2 }2 (THF) (2), and the stable bis(pyridine) derivative trans-Ni{N(SiMe3 )2 }2 (py)2 (3), is described. Both 1 and 2 decompose at ca. 25 °C to a tetrameric Ni(I) species, [Ni{N(SiMe3 )2 }]4 (4), also obtainable from LiN(SiMe3 )2 and NiCl2 (DME). Experimental and computational data indicate that the instability of 1 is likely due to ease of reduction of Ni(II) to Ni(I) and the stabilization of 4 through dispersion forces.
Oxovanadium(V) complexes with tripodal bisphenolate and monophenolate ligands: Syntheses, structures and catalytic activities
2019
Abstract The reactions between [VO(acac)2] (acac– = acetylacetonate) and the tripodal amino bisphenols 6,6′-(((2-morpholinoethyl)azanediyl)bis(methylene))bis(2,4-di-tert-butylphenol) (H2L1) and 6,6′-(((thiophen-2-ylmethyl)azanediyl)bis(methylene))bis(2,4-di-tert-butylphenol) (H2L2) as well as the tetradentate amino phenol 2,2′-((3,5-di-tert-butyl-2-hydroxybenzyl)azanediyl)bis(ethan-1-ol) (H3L3) afford the complexes [VO(L1)(OMe)] (1), [VO(L2)(acac)] (2) and [VO(L3)] (3), correspondingly. Complexes 1 and 3 can also be prepared using VOSO4·xH2O or [VO(OPr)3] as vanadium precursors. When [VO(acac)2] or VOSO4·xH2O is used, mononuclear oxovanadium(V) complexes are formed upon oxidation of the met…
Synthesis, X-ray Structure, Antimicrobial and Anticancer Activity of a Novel [Ag(ethyl-3-quinolate)2(citrate)] Complex
2022
A novel Ag(I) citrate complex with ethyl-3-quinolate (Et3qu) was synthesized. Its structure was confirmed using X-ray single crystal to be [Ag(Et3qu)2(citrate)]. It crystallized in the Triclinic crystal system and P-1 space group with unit cell parameters of a = 8.6475(2) Å, b = 11.4426(3) Å, c = 15.2256(3) Å, α = 73.636(2)°, β = 79.692(2)° and γ = 86.832(2)°, while the unit cell volume was 1422.19(6) Å3. In the unit cell, there are two [Ag(Et3qu)2(citrate)] molecules and one unit as the asymmetric formula. The molecular structure comprised one Ag(I) coordinated with two Et3qu molecules via two almost equidistant Ag-N bonds and one citrate ion acting as a mono-negative monodentate ligand vi…