Search results for "lactone"

showing 10 items of 335 documents

Two new sesquiterpene lactones from Montanoa tomentosa ssp. microcephala

2001

Sesquiterpene lactones Antiproliferative activitySettore BIO/14 - Farmacologia
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Evaluation of the in vitro and in vivo antineoplastic effects of Parthenolide on MDA-MB231 breast cancer cells

2012

Triple-negative breast cancer refers to an aggressive subtype of breast cancer in which the tumor cells lack receptors for estrogen, progesterone and the HER2 protein on their surfaces. This type of breast cancer does not respond to treatments such as hormone therapy, like tamoxifen and aromatase inhibitors, or drugs that target HER2, like Herceptin. It is important, therefore, the identification of new selective drugs for the treatment of these tumors. Parthenolide (PN), a sesquiterpene lactone extracted from the medical plant Tanacetum parthenium, exerts anticancer activity on several tumor cell lines in culture, acting through diverse molecular mechanisms. Our previous studies have shown…

Settore BIO/10 - BiochimicaBreast cancer cells sesquiterpene lactones parthenolide DMAPT
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GALACTOSE-DECORATED POLYMERIC CARRIERS FOR HEPATOCYTE-SELECTIVE DRUG TARGETING

2015

In this paper, the current available strategies to realize galactose-decorated nanostructured polymeric systems are summarized. These carriers are designed in order to obtain targeted drug delivery to hepatocytes via galactose (GAL) moieties, i.e., for the treatment of viral hepatitis or liver cancer that are the greater causes of global disability and mortality. Usually, the main followed strategy to obtain galactosylated polymeric carriers is to use galactosylated copolymers. The chemical modifications of preformed polymers with sugar-containing reagents is followed for obtaining lactosaminated human albumin, galactosylated phospholipid-polyaminoacid and polylactide (PLA)- polyaminoacid c…

Settore CHIM/09 - Farmaceutico Tecnologico ApplicativoAsialoglycoprotein receptor (ASGP-R) carboxymethyl chitosan (CMC) galactose (GAL) hepatocytes lactosaminated albumin liver targeting poly(ε-caprolactone) (PCL) polyamidoamine (PAMAM) dendrimers polycarbonates polylactide (PLA) xyloglucan αβ-poly(N-2-hydroxyethyl)-DLaspartamide (PHEA).
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Improvement of actinorhodin production yield in Streptomyces coelicolor by immobilized-cell cultivations by using PCL- and PLA-based films

2016

Actinomycetes are Gram-positive bacteria producing most of naturally occurring antibiotics (Donadio et al., 2010). At industrial level, antibiotics are produced by submerged fermentations where the actinomycete filamentous morphology negatively affects bioproductivity (van Dissel et al., 2014). Microporous membranes for bacterial cell-immobilization were already proven increasing bioproductivity in Streptomyces coelicolor, that is a model actinomycete producing the blue pigmented actinorhodin (ACT) antibiotic (Scaffaro et al., 2016). To develop an immobilized-cell bioreactor system, different kinds of polycaprolactone (PCL) and polylactic acid (PLA) films were produced by an electrospinning…

Settore ING-IND/22 - Scienza E Tecnologia Dei MaterialiStreptomyces coelicolor immobilizationbioproduction improvementpolycaprolactone and polylactic acid filmSettore BIO/19 - Microbiologia Generale
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Actinorhodin production intensification by nanofibrous membranes in Streptomyces coelicolor cultures

2016

In this work, electrospun polycaprolactone (PCL) and polylactic acid (PLA) membranes, subjected or not to O2-plasma treatment, werwe used as support for cell-immobilization in S. coelicolor immobilized-cells created a compact biofilm on both kinds of membranes.

Settore ING-IND/22 - Scienza E Tecnologia Dei Materialiimmobilization of Streptomyces coelicoloractinorhodin productionpolycaprolactone and polylactic acid membranesSettore BIO/19 - Microbiologia Generale
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Ring opening polymerization of cyclic esters with metal free catalysts

2012

Settore ING-IND/27 - Chimica Industriale E TecnologicaRing opening polymerization epsilon-caprolactone enzymes cyclodextrins
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Triple-target stimuli-responsive anti-COVID-19 face mask with physiological virus-inactivating agents

2021

Conventional face masks to prevent SARS-CoV-2 transmission are mostly based on a passive filtration principle. Ideally, anti-COVID-19 masks should protect the carrier not only by size exclusion of virus aerosol particles, but also be able to capture and destroy or inactivate the virus. Here we present the proof-of-concept of a filter mat for such a mask, which actively attracts aerosol droplets and kills the virus. The electrospun mats are made of polycaprolactone (PCL) a hydrophilic, functionalizable and biodegradable polyester, into which inorganic polyphosphate (polyP) a physiological biocompatible, biodegradable and antivirally active polymer (chain length, ∼40 Pi units) has been integr…

Size-exclusion chromatographyBiomedical EngineeringNanoparticle02 engineering and technologyDivalent03 medical and health scienceschemistry.chemical_compoundPolyphosphatesHumansGeneral Materials ScienceIon channel030304 developmental biologychemistry.chemical_classification0303 health sciencesLiposomeCoacervateSARS-CoV-2PolyphosphateMasksCOVID-19021001 nanoscience & nanotechnology3. Good healthChemistrychemistryPolycaprolactoneBiophysicsNanoparticles0210 nano-technology
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Effect of the dissolution time into an acid hydrolytic solvent to tailor electrospun nanofibrous polycaprolactone scaffolds

2017

[EN] The hydrolysis of the polycaprolactone (PCL) as a function of the dissolution time in a formic/acetic acid mixture was considered as a method for tailoring the morphology of nanofibrous PCL scaffolds. Hence the aim of this research was to establish a correlation between the dissolution time of the polymer in the acid solvent with the physicochemical properties of the electrospun nanofibrous scaffolds and their further service life behaviour. The physico-chemical properties of the scaffolds were assessed in terms of fibre morphology molar mass and thermal behaviour. A reduction of the molar mass and the lamellar thickness as well as an increase of the crystallinity degree were observed …

Solucions polimèriquesMaterials sciencePolymers and PlasticsEnginyeriaGeneral Physics and Astronomy02 engineering and technology010402 general chemistry01 natural sciencesScaffoldHydrolysischemistry.chemical_compoundCrystallinityCIENCIA DE LOS MATERIALES E INGENIERIA METALURGICAMaterials ChemistryLamellar structureComposite materialDissolutionchemistry.chemical_classificationPolycaprolactone (PCL)Molar massElectrospinningHydrolysisTermoplàsticsOrganic ChemistryQuímicaPolymer021001 nanoscience & nanotechnologyElectrospinning0104 chemical scienceschemistryIn vitro validationMAQUINAS Y MOTORES TERMICOSPolycaprolactone0210 nano-technologyEuropean Polymer Journal
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CCDC 251467: Experimental Crystal Structure Determination

2004

Related Article: J.R.Hanson, P.B.Hitchcock, I.Pibiri, F.Piozzi|2003|J.Chem.Res.||147|doi:10.3184/030823403103173291

Space GroupCrystallography6beta-HydroxyrosenonolactoneCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 251468: Experimental Crystal Structure Determination

2004

Related Article: J.R.Hanson, P.B.Hitchcock, I.Pibiri, F.Piozzi|2003|J.Chem.Res.||147|doi:10.3184/030823403103173291

Space GroupCrystallographyCrystal SystemCrystal Structure12alpha-HydroxyrosenonolactoneCell ParametersExperimental 3D Coordinates
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