Search results for "layer"
showing 10 items of 2667 documents
Thermal behavior of absorbing and scattering glass media containing molecular water impurity
2005
The effect of the presence of molecular water impurity of various concentrations in absorbing and scattering glass media on the temperature field in a layer subjected to thermal infrared radiation is investigated. The analysed medium is treated as a multicomponent medium consisting of glass matrix and water impurity. The effect of radiation on the medium is expressed by heat sources in each component due to absorption of radiation. It is shown that the presence of water impurity in the glass medium should be accounted for in order to predict the temperature distribution during radiation action. The effect of scattering of radiation by water molecules on thermal and diffusive processes in th…
Third-harmonic generation in the skin layer of a hot dense plasma
2003
The third-harmonic generation of a pump wave, resulting from the electron-ion collision frequency dependence on the electric field in the skin layer of a hot dense plasma is investigated. The relation of the current third harmonic with the high-frequency field in the skin layer is established for arbitrary ratios of the electron-ion collision frequency to the field frequency. For arbitrary ratios of these two frequencies, the field structure inside the skin layer is determined, and the field of the wave irradiated by the plasma at tripled frequency, too, is calculated. It has permitted us to find the explicit dependencies of the third-harmonic generation efficiency on the plasma and pump fi…
Formulation and validation of a reduced order model of 2D materials exhibiting a two-phase microstructure as applied to graphene oxide
2018
Abstract Novel 2D materials, e.g., graphene oxide (GO), are attractive building blocks in the design of advanced materials due to their reactive chemistry, which can enhance interfacial interactions while providing good in-plane mechanical properties. Recent studies have hypothesized that the randomly distributed two-phase microstructure of GO, which arises due to its oxidized chemistry, leads to differences in nano- vs meso‑scale mechanical responses. However, this effect has not been carefully studied using molecular dynamics due to computational limitations. Herein, a continuum mechanics model, formulated based on density functional based tight binding (DFTB) constitutive results for GO …
Wear Analysis During Friction Stir Processing of A359+20%SiC MMC
2009
Metal Matrix Composites (MMC) are very interesting materials for applications in the automotive and aerospace fields, since they combine the lightness of Aluminium with the strength of the ceramic reinforcement. These materials are very difficult to join and conventional welding techniques are not applicable, whereas solid-state welding techniques, like Friction Stir Welding (FSW), could be a solution. However very hard tool materials will need to be chosen in order to overcome the problem of heavy abrasive tool wear. In this work the wear behaviour of coated and uncoated steel tools has been investigated in the Friction Stir Processing of extruded bars in A359 + 20%SiC. AISI 1040 steel was…
Influence of charge transfer doping on the morphologies of C60islands on hydrogenated diamond C(100)-(2×1)
2012
The adsorption and island formation of C${}_{60}$ fullerenes on the hydrogenated C(100)-($2\ifmmode\times\else\texttimes\fi{}1$):H diamond surface is studied using high-resolution noncontact atomic force microscopy in ultrahigh vacuum. At room temperature, C${}_{60}$ fullerene molecules assemble into monolayer islands, exhibiting a hexagonally close-packed internal structure. Dewetting is observed when raising the substrate temperature above approximately 505 K, resulting in two-layer high islands. In contrast to the monolayer islands, these double-layer islands form extended wetting layers. This peculiar behavior is explained by an increased molecule-substrate binding energy in the case of…
Fullerene imposed high open-circuit voltage in efficient perovskite based solar cells
2016
Five different commercially available fullerenes are evaluated as hole blocking/electron transporting materials in p–i–n methylammonium lead iodide perovskite solar cells using a vacuum deposited perovskite absorber layer. A significant enhancement of the solar cell performance can be obtained by selecting a suitable fullerene derivative. Open-circuit voltages as high as 1.11 volts are obtained leading to a power conversion efficiency of 14.6%.
Second-layer induced island morphologies in thin-film growth of fullerenes.
2011
Deposition of fullerenes on the CaF(2)(111) surface yields peculiar island morphologies with close similarities to previous findings for (100) surfaces of other ionic crystals. By means of noncontact atomic force microscopy we find a smooth transition from compact, triangular islands to branched hexagonal islands upon lowering the temperature. While triangular islands are two monolayers high, hexagonal islands have a base of one monolayer and exhibit a complicated structure with a second-layer outer rim and trenches oriented towards the interior. By developing a kinetic growth model we unravel the microscopic mechanisms of the structure formation.
Atmosphere-induced change of microhardness and plasticity of C60 single crystals and polycrystalline films
1998
Abstract The effect of air exposure and visible light illumination on the microhardness, plasticity and dislocation mobility in the C60 single crystals was investigated. Microhardness values for defined structural states of the fullerene (pristine, oxygen-intercalated, photo-oxidized) are reported. It has been shown that oxygen intercalation in the fullerene lattice during air-aging in the dark results in the suppression of dislocation mobility. However, only a slight increase in the hardness of oxygenated samples was observed. A remarkable increase in the hardness and decrease in the plasticity of the C60 crystals under illumination-assisted air exposure was noted. Photochemical transforma…
Modelling of a recirculating photocatalytic microreactor implementing mesoporous N-TiO2 modified with graphene
2020
Abstract The use of microreactors in (photo)catalytic processes offers new possibilities for studying and optimizing many mass and photon transfer limited reactions. In this study, we propose a scalable computational fluid dynamics (CFD) model for the prediction of photocatalytic degradation of a model pollutant (4-nitrophenol) using immobilized N-doped TiO2 grown over reduced graphene oxide (N-TiO2/rGO) in a photocatalytic microreactor working in continuous flow-recirculation mode. The mode of operation used in this study allows the reduction of mass transfer limitations inherent to heterogeneous photocatalytic reactions taking place on immobilized catalysts. A CFD model was developed for …
Structural Relationships between Floating and Deposited Monolayers of Docosanoic Acid
1991
Floating docosanoic acid (behenic acid) monolayers in the SmI and SmH phase were deposited with the Langmuir-Blodgett technique onto thin polymethylmethacrylate (PMMA) and Formvar substrates and investigated by electron diffraction. The molecular packing of the monolayers on the substrates vary from those on the water surface and are different for different substrates. On PMMA four phases (H, SmB, SmI, SmL) have been identified, depending on the deposition conditions. While SmB and SmI are known for docosanoic acid on the water surface, H and SmL have only been unequivocally observed in other substances or on other subphases. The monolayer structure on Formvar was identical under all deposi…